相关论文: A Practical Guide to the Partition Function of Ato…
Partition functions and dissociation equilibrium constants are presented for 291 diatomic molecules for temperatures in the range from near absolute zero to 10000 K, thus providing data for many diatomic molecules of astrophysical interest…
The key problem of statistical physics standing over one hundred years is how to exactly calculate the partition function (or free energy) of many-body interaction systems, which severely hinders application of the theory for realistic…
Using a central limit theorem for arrays of interacting quantum systems, we give analytical expressions for the density of states and the partition function at finite temperature of such a system, which are valid in the limit of infinite…
Aims. In this work we rigorously show the shortcomings of various simplifications that are used to calculate the total internal partition function. These shortcomings can lead to errors of up to 40 percent or more in the estimated partition…
New formulas are given for the grand partition function of paraboson systems of order p with n orbitals and parafermion systems of order p with m orbitals. These formulas allow the computation of statistical and thermodynamic functions for…
Long-range quantum systems, in which the interactions decay as $1/r^{\alpha}$, are of increasing interest due to the variety of experimental set-ups in which they naturally appear. Motivated by this, we study fundamental properties of…
The partition function for a system of non-interacting $N-$particles can be found by summing over all the states of the system. The classical partition function for an ideal gas differs from Bosonic or Fermionic partition function in the…
The fission process is a fascinating phenomenon in which the atomic nucleus, a compact self-bound mesoscopic system, undergoes a spontaneous or induced quantum transition into two or more fragments. A predictive, accurate and precise…
We investigate the dissociation and ionization equilibria of deuterium fluid over a wide range of temperatures and densities. The partition functions for molecular and atomic species are evaluated, in a statistical-mechanically consistent…
Atomic nuclei are quantum many-body systems of protons and neutrons held together by strong nuclear forces. Under the proper conditions, nuclei can break into two (sometimes three) fragments which will subsequently decay by emitting…
We calculate the partition function for "composite particles". For any finite number of states d, and in the following two cases: 1)all states have the same energy, 2)the energy is linearly distributed over the states, we transform the…
High temperature expansion of the partition function for a particle on a segment of a line is found to show an example of the quantum system that thermodynamical functions do not approach the thermodynamical functions of its classical…
In this study, internal energy (U), electric field (E) and particle number (N) which specify the system quantities i.e. thermodynamical quantities for the proteins. In the frame of thermodynamical formalism, the relation between the heat…
The recently proposed Partition Theory (PT) [J.Phys.Chem.A 111, 2229 (2007)] is illustrated on a simple one-dimensional model of a heteronuclear diatomic molecule. It is shown that a sharp definition for the charge of molecular fragments…
A charged particle traversing a plasma loses its energy to both plasma electrons and ions. We compute the energy partition, the fractions $E_e/E_0$ and $E_\smI/E_0$ of the initial energy $E_0$ of this `impurity particle' that are deposited…
The partition function of two-dimensional solitons in a heat bath of mesons is worked out to one-loop. For temperatures large compared to the meson mass, the free energy is dominated by the meson-soliton bound states and the zero modes, a…
Ionization is a problematic quantity in that it does not have a well-defined thermodynamic definition, yet it is a key parameter within plasma modelling. One still therefore aims to find a consistent and unambiguous definition for the…
The partition function with ring diagrams at finite temperature is exactly caluclated by using contour integrals in the complex energy plane. It contains a pole part with temperature and momentum dependent mass and a phase shift part…
Electron-electron correlation forms the basis of difficulties encountered in many-body problems. Accurate treatment of the correlation problem is likely to unravel some nice physical properties of matter embedded in this correlation. In an…
The variational argument is presented to establish the attainability of homogeneity of degree one in the number of particles for any functional $F[n, f]$ that depends on both the state variable $f$ and the particle count $n$. Euler's…