相关论文: Temperature-Modulated Photomechanical Actuation of…
Azo-dye-doped liquid crystal elastomers (LCEs) are known to show a strong photomechanical response. We report on experiments that suggest that photothermal heating is the underlying mechanism in surface-constrained geometry. In particular,…
Recent studies of azo-dye doped liquid crystal elastomers show a strong photomechanical response. We report on models that predict experimental results that suggest photothermal heating is the dominant mechanism in a planar constrained…
Photoactive nematic elastomers are soft rubbery solids that undergo deformation when illuminated. They are made by incorporating photoactive molecules like azobenzene into nematic liquid crystal elastomers. Since its initial demonstration…
The emergent photoactive materials through photochemistry make it possible to directly convert photon energy to mechanical work. There is much recent work in developing appropriate materials and a promising new system is semi-crystalline…
Azo-containing liquid crystal elatomers are photomechanical materials which can be actuated by illumination. The photomechanical response is a result of the photoisomerization of the azo moiety, which produces bulk stresses in the material.…
The macroscopic shape of liquid crystalline elastomers strongly depends on the order parameter of the mesogenic groups. This order can be manipulated if photoisomerisable groups, e.g. containing N=N bonds, are introduced into the material.…
We describe the complex time-dependence of the build up of force exerted by a clamped photo-elastomer under illumination. Nonlinear (non-Beer) absorption leads to a bleaching wave of a significant cis isomer dye concentration deeply…
A range of monodomain nematic liquid crystal elastomers containing differing proportions of photo-isomerisable mesogenic moieties, which turn from a rod-like to a kinked shape upon ultraviolet (UV) irradiation, was studied. Depending on the…
Deformations of amorphous polymer networks prepared with significant concentrations of liquid crystalline mesogens have been recently reported to undergo mechanotropic phase transitions. Here, we report that these mechanotropic phase…
Photomechanical actuation is demonstrated in two coupled liquid crystal elastomer photomechanical optical devices (PODs) acting in series. The response function of an individual POD is characterized and used to predict the temporal response…
Liquid crystal elastomers are rubbers with liquid crystal order. They contract along their nematic director when heated or illuminated. The shape changes are large and occur in a relatively narrow temperature interval, or at low…
Owing to the possibility of controlling its specific mechanical behaviors up taken by irradiated by light at particular wavelengths, the photoisomerization hydrogels have a broad range of potential applications. A theory connecting the…
Photomechanical liquid crystal elastomers (LCEs) are responsive polymers that can convert light directly into mechanical deformation. This unique feature makes these materials an attractive candidate for soft actuators capable of remote and…
Liquid crystal elastomers (LCEs) containing light-sensitive molecules exhibit large reversible deformation when subjected to illumination. Here, we investigate the role of optical penetration depth on this photomechanical response. We…
Understanding the intricate relation between illumination and temperature in metallic nano-particles is crucial for elucidating the role of illumination in various physical processes which rely on plasmonic enhancement but are also…
We elucidate the polymer dynamics of a liquid crystal elastomer based on the time-dependent response of the pendent liquid crystal mesogens. The molecular tilt and switching time of mesogens are analyzed as a function of temperature and…
Actuation remains a signifcant challenge in soft robotics. Actuation by light has important advantages: objects can be actuated from a distance, distinct frequencies can be used to actuate and control distinct modes with minimal…
Optothermal interaction of active colloidal matter can facilitate environmental cues which can influence the dynamics of active soft matter systems. The optically induced thermal effect can be harnessed to study non-equilibrium…
Materials exhibiting a large caloric effect could lead to the development of new generation of heat-management technologies that will have better energy efficiency and be potentially more environmentally friendly. The focus of caloric…
Stimuli-responsive liquid crystal elastomers (LCEs) with a strong coupling of orientational molecular order and rubber-like elasticity, show a great potential as working elements in soft robotics, sensing, transport and propulsion systems.…