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Halide perovskite semiconductors respond to electric fields in a way that varies across time and length scales. We discuss the microscopic processes that give rise to the macroscopic polarization of these materials, ranging from the optical…

材料科学 · 物理学 2018-12-04 Jacob N. Wilson , Jarvist M. Frost , Suzanne K. Wallace , Aron Walsh

Using cross-correlation current noise spectroscopy, we have investigated carrier dynamics in methylammonium lead triiodide solar cells. This method provides a space selectivity for devices with planar multi-layered structure, effectively…

应用物理 · 物理学 2020-07-15 Kevin Davenport , Fei Zhang , Mark Hayward , Logan Draper , Kai Zhu , Andrey Rogachev

Perovskites have proven to be a promising candidate for highly-efficient solar cells, light-emitting diodes, and X-ray detectors, overcoming limitations of inorganic semiconductors. However, they are notoriously unstable. The main reason…

应用物理 · 物理学 2020-02-19 Moritz H. Futscher , Mahesh K. Gangishetty , Daniel N. Congreve , Bruno Ehrler

Capacitance measurements as a function of voltage, frequency and temperature are useful tools to identify fundamental parameters that affect solar cell operation. Techniques such as capacitance-voltage (CV), Mott-Schottky analysis and…

应用物理 · 物理学 2021-12-23 Sandheep Ravishankar , Zhifa Liu , Uwe Rau , Thomas Kirchartz

Open circuit voltage decay measurements are performed on methylammonium lead iodide (CH3NH3PbI3) perovskite solar cells to investigate the charge carrier recombination dynamics. The measurements are compared to the two reference…

材料科学 · 物理学 2014-07-07 A. Baumann , K. Tvingstedt , M. C. Heiber , S. Väth , C. Momblona , H. J. Bolink , V. Dyakonov

Organic-inorganic hybrid perovskites (OIHPs) have attracted extensive research interest as a promising candidate for efficient and inexpensive solar cells. Transmission electron microscopy characterizations that can benefit the fundamental…

The anomalous hysteresis is reported in photo current density-voltage (J-V) curves of perovskite solar cells. The origins responsible for hysteresis are primarily attributed to ferroelectricity, trapping/de-trapping, and ions migration.…

材料科学 · 物理学 2015-08-25 Zeguo Tang , Takashi Minemoto

Intrinsic and extrinsic ion migration is a very large threat to the operational stability of perovskite solar cells and is difficult to completely eliminate due to the low activation energy of ion migration and the existence of internal…

应用物理 · 物理学 2020-08-06 Jiangjian Shi , Yiming Li , Yusheng Li , Huijue Wu , Yanhong Luo , Dongmei Li , Qingbo Meng

Impedance spectroscopy (IS) is a relatively straightforward experimental technique that is commonly used to obtain information about the physical and chemical characteristics of photovoltaic devices. However, the non-standard physical…

Halide perovskite solar cells based on CH3NH3PbI3 and related materials have emerged as the most exciting development in the next generation photovoltaic technologies, yet the microscopic phenomena involving photo-carriers, ionic defects,…

材料科学 · 物理学 2017-10-17 Jiangyu Li , Boyuan Huang , Ehsan Nasr Esfahani , Linlin Wei , Jianjun Yao , Jinjin Zhao , Wei Chen

An effective method, performed adding external electric field (EEF) on CH3NH3PbI3-xClx (OPIC) perovskite layer during the annealing process, is proposed to improve the performance of the solar cell. By harmonizing EEF direction with the…

材料科学 · 物理学 2015-07-10 Xiu Gong , Heng Ma , Yu-Rong Jiang , Meng Li , Zhao-Kui Wang , Tetsuo Soga

Increasing evidence suggests that the presence of mobile ions in perovskite solar cells can cause a current-voltage curve hysteresis. Steady state and transient current-voltage characteristics of a planar metal halide CH$_3$NH$_3$PbI$_3$…

应用物理 · 物理学 2018-04-24 N. E. Courtier , J. M. Foster , S. E. J. O'Kane , A. B. Walker , G. Richardson

Strong-field physics is currently experiencing a shift towards the use of mid-IR driving wavelengths. This is because they permit conducting experiments unambiguously in the quasi-static regime and enable exploiting the effects related to…

Perovskite solar cells (PSCs) have emerged as a promising photovoltaic technology, already achieving efficiencies surpassing 25%. However, effects such as hysteresis are commonly observed due to the interplay of ionic and electronic…

While transient photoluminescence measurements are a very popular tool to monitor the charge-carrier dynamics in the field of halide perovskite photovoltaics, interpretation of data obtained on multilayer samples is highly challenging due…

材料科学 · 物理学 2021-02-18 Lisa Krückemeier , Benedikt Krogmeier , Zhifa Liu , Uwe Rau , Thomas Kirchartz

Next-generation low-cost semiconductors such as halide perovskites exhibit optoelectronic properties dominated by nanoscale variations in their structure, composition and photophysics. While microscopy provides a proxy for ultimate device…

Understanding and quantifying the main loss factors affecting the power conversion efficiency of perovskite solar cells are urgently needed. In this work, based on semiconductor physics, the expressions of bulk and surface recombination…

介观与纳米尺度物理 · 物理学 2021-03-23 Ting Xu , Zi-Shuai Wang , Xuan-Hua Li , Wei E. I. Sha

Ionic migration in organo-halide perovskites plays an important role in operation of perovskite based solar cells and light emitting diodes. Despite the ionic migration being a reversible process, it often leads to worsening of perovskite…

The significant surge in energy use and escalating environmental concerns have sparked worldwide interest towards the study and implementation of solar cell technology. Perovskite solar cells (PSCs) have garnered remarkable attention as an…

材料科学 · 物理学 2025-06-23 Md Yekra Rahman , Sharif Mohammad Mominuzzaman

Ion migration in perovskite solar cells is usually analyzed and understood in terms of charge neutrality condition. However, several recent reports indicate possibility of ionic imbalance in the active layer due to external ion migration…

材料科学 · 物理学 2023-01-27 Dhyana Sivadas , Abhimanyu Singareddy , Chittiboina vinod , Pradeep Nair