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We discuss the effect of the local field polarization in metallic nanostructures where large field enhancements can be induced by excitation of localized surface plasmons. To demonstrate the importance of these effects, we study a few model…

化学物理 · 物理学 2007-05-23 E. C. Le Ru , P. G. Etchegoin

We have investigated the effects of tuning the localized surface plasmon resonances (LSPRs) of silver nanoparticles on the fluorescence intensity, lifetime, and Raman signal from nearby fluorophores. The presence of a metallic structure can…

其他凝聚态物理 · 物理学 2009-11-13 N. I. Cade , T. Ritman-Meer , D. Richards

The hotspots, which are typically found in nanogaps between metal structures, are critical for the enhancement of the electromagnetic field. Surface-enhanced Raman scattering (SERS), a technique known for its exceptional sensitivity and…

光学 · 物理学 2025-01-22 Mahsa Haddadi Moghaddam , Sobhagyam Sharma , Daehwan Park , Dai Sik Kim

A periodic arrangement of chains of gold discs shows pronounced plasmonic grating resonances. These have a clear impact on the Surface Enhanced Raman Scattering (SERS)-signal from 4-methylbenzenethiol molecules which form self-assembled…

It is an established understanding that the electromagnetic contribution (the plasmon-mediated enhancement of the laser and scattered local electromagnetic fields) is the main actor in Surface Enhanced Raman Scattering (SERS), with the…

Surface-enhanced Raman spectroscopy (SERS) is enabled by local surface plasmon resonances (LSPRs) in metallic nanogaps. When SERS is excited by direct illumination of the nanogap, the background heating of lattice and electrons can prevent…

介观与纳米尺度物理 · 物理学 2023-08-23 Shusen Liao , Yunxuan Zhu , Qian Ye , Stephen Sanders , Jiawei Yang , Alessandro Alabastri , Douglas Natelson

New type of plasmonic nanoparticles - silver octopods that can be synthesized with a variety of shapes - have been demonstrated to show versatile optical response using the discrete dipole approximation. The octopods show a complex behavior…

介观与纳米尺度物理 · 物理学 2015-05-13 Ivan I. Naumov , Zhiyong Li , Alexander M. Bratkovsky

We present a hybrid surface-enhanced Raman spectroscopy (SERS) platform based on dielectric silicon metasurfaces integrated with functionalized graphene for the selective detection of biomolecules such as prolactin and SARS-CoV-2…

We theoretically investigate the enhancement of surface enhanced Raman spectroscopy (SERS) using hyperbolic stratified nanostructures and compare to metal nanoresonators. The photon Green function of each nanostructure within its…

Plasmonic materials have got wide attention as a potential candidate for light driven catalysis of chemical conversions by harnessing solar energy to reduce the environmental issues generated by fossil fuels-based bulk chemical industries.…

光学 · 物理学 2024-08-27 Mahadi Hasan , Mahamadu Tiah Mahama

We investigate theoretically the optical properties associated to plasmon resonances of metal nanowires with cross section given by low-order Chebyshev nanoparticles (like rounded-tip nanostars or nanoflowers). The impact of the nanoflower…

光学 · 物理学 2009-10-23 V. Giannini , R. Rodriguez-Oliveros , J. A. Sanchez-Gil

We present the experimental realization of ordered arrays of hyper-doped silicon nanodisks, which exhibit a localized surface plasmon resonance. The plasmon is widely tunable in a spectral window between 2 and 5 $\mu$m by adjusting the free…

We present a microscopic model for surface-enhanced Raman scattering (SERS) from molecules adsorbed on small noble-metal nanoparticles. In the absence of direct overlap of molecular orbitals and electronic states in the metal, the main…

介观与纳米尺度物理 · 物理学 2009-11-11 Vitaliy N. Pustovit , Tigran V. Shahbazyan

We propose the theory of the plasmon excited in ultra-narrow plasmonic gap formed by a metal cylinder on a metal surface, that generates a huge resonant local electromagnetic field in optical frequencies. Resonance conditions are found. The…

光学 · 物理学 2021-11-11 Andrey K. Sarychev , Andrey V. Ivanov , Grégory Barbillon

Single-molecule surface enhanced Raman scattering (SM-SERS) is one of the vital applications of plasmonic nanoparticles. The SM-SERS sensitivity critically depends on plasmonic hot-spots created at the vicinity of such nanoparticles. In…

Graphene covered metal nanoparticles constitute a novel type of hybrid materials, which provide a unique platform to study plasmonic effects, surface-enhanced Raman scattering (SERS), and metal-graphene interactions at the nanoscale. Such a…

Electromagnetic theory predicts that the optimal value of the localized plasmon resonance (LPR) wavelength for the maximal SERS enhancement factor (EF) is half the sum of the laser and Raman wavelengths. For small Raman shifts, the…

We explored the surface enhanced Raman scattering (SERS) activity of the InN nanostructures, possessing surface electron accumulation (SEA), using the Rhodamine 6G (R6G) molecules. SERS enhancement is observed for the InN nanostructures…

材料科学 · 物理学 2018-08-14 Kishore K. Madapu , Sandip Dhara

A plasmonic nanostructure-based substrate, serving as a surface-enhanced Raman scattering (SERS) substrate, enhances the Raman scattering of molecules. By employing an electron beam lithography followed by our recently developed…

The spectral relationships between surface enhanced resonant Raman scattering (SERRS) and plasmon resonance observed in far field scattering cross are investigated using single silver nanoparticle dimers with focusing on the lowest energy…

光学 · 物理学 2023-04-07 Tamitake Itoh , Yuko S. Yamamoto
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