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We report the superconductivity of a new quaternary compound ThMo$_2$Si$_2$C, synthesized with the arc-melting technique. The compound crystallizes in a tetragonal CeCr$_2$Si$_2$C-type structure with cell parameters of $a$ = 4.2296 \r{A}and…

In this work, global search for crystal structures of ternary Mg-Sc-H hydrides (Mg$_x$Sc$_y$H$_z$) under high pressure ($100 \le P \le 200$ GPa) were performed using the evolutionary algorithm and first-principles calculations. Based on…

Pressure as a clean and efficient tool can bring about unexpected extraordinary physical and chemical properties of matters. The recent discoveries of superconductivity at nearly room temperature in hydrides highlight the power of pressure…

超导电性 · 物理学 2022-08-22 Di Peng , Ren-Shu Wang , Li-Na Zong , Xiao-Jia Chen

Search for stable high-pressure compounds in the Ti--H system reveals the existence of titanium hydrides with new stoichiometries, including Ibam-Ti$_2$H$_5$, I4/m-Ti$_5$H$_{13}$, I$\bar{4}$-Ti$_5$H$_{14}$, Fddd-TiH$_4$,…

The recent discovery of room temperature superconductivity (283 K) in carbonaceous sulfur hydride (C-S-H) has attracted lots of interests in ternary hydrogen rich materials. In this report, ternary hydride P-S-H has been synthesized through…

材料科学 · 物理学 2022-06-15 Tingting Ye , Hong Zeng , Peng Cheng , Deyuan Yao , Xiaomei Pan , Xiao Zhang , Junfeng Ding

Various transition metal trichalcogenides (TMTC) show the charge-density-wave and superconductivity, which provide an ideal platform to study the correlation between these two orderings and the mechanism of superconductivity. Currently,…

超导电性 · 物理学 2021-11-04 Binbin Yue , Wei Zhong , Wen Deng , Ting Wen , Yonggang Wang , Yunyu Yin , Pengfei Shan , Xiaohui Yu , Fang Hong

Solid CS$_{2}$ is superficially similar to CO$_{2}$, with the same $Cmca$ molecular crystal structure at low pressures, which has suggested similar phases also at high pressures. We carried out an extensive first principles evolutionary…

材料科学 · 物理学 2015-06-23 S. Shahab Naghavi , Yanier Crespo , Roman Martonak , Erio Tosatti

Crystal structure searching and ab initio calculations have been used here to explore low-energy structures of boron carbides under high pressure. Under pressures of 85-110 GPa, a metastable B6C with R-3m symmetry is found to be…

材料科学 · 物理学 2018-01-01 Kang Xia , Mengdong Ma , Cong Liu , Hao Gao , Qun Chen , Julong He , Jian Sun , Hui-Tian Wang , Yongjun Tian , Dingyu Xing

Binary metal sulfides are potential material family for exploring high Tc superconductors under high pressure. In this work, we study the crystal structures, electronic structures and superconducting properties of the Lu-S system in the…

超导电性 · 物理学 2023-12-25 Juefei Wu , Bangshuai Zhu , Chi Ding , Dexi Shao , Cuiying Pei , Qi Wang , Jian Sun , Yanpeng Qi

The ab initio calculations suggest that the superconducting state in CaH6 under the pressure at 150 GPa has the highest critical temperature among the examined hydrogen-rich compounds. For this reason, the relevant thermodynamic parameters…

超导电性 · 物理学 2013-09-17 R. Szczesniak , A. P. Durajski

We propose to increase the superconducting transition temperature Tc of strongly correlated materials by designing heterostructures which exhibit a high pairing energy as a result of magnetic fluctuations. More precisely, applying an…

超导电性 · 物理学 2015-05-20 Karyn Le Hur , Chung-Hou Chung , I. Paul

The compression of SH$_2$ and its subsequent decomposition to SH$_3$, presumably in a cubic Im$\overline{3}$m structure, has lead to the discovery of conventional superconductivity with the highest measured and confirmed $T_c$ to date, 203…

材料科学 · 物理学 2019-02-20 Maximilian Amsler

We report the path from the charge density wave (CDW)-bearing superconductor CuIr2Te4 to the metal insulator transition (MIT)-bearing compound CuIr2S4 by chemical alloying with the gradual substitution of S for Te. The evolution of…

We report on the pressure dependence of superconducting transition temperature Tc and upper critical field Bc2(0) through electrical transport of the Ti4Co2O superconductor (eg.,the superconducting transition temperature Tc = 2.5 K and the…

Motivated by advances in hydrogen-rich superconductors in the past decades, we conducted variable-composition structural searches in Mo-H binary system at high pressure. A new composition-pressure phase diagram of thermodynamically stable…

超导电性 · 物理学 2024-01-31 Aiqin Yang , Xiangru Tao , Yundi Quan , Peng Zhang

Hydrogen-rich superhydrides are promising high-Tc superconductors, with superconductivity experimentally observed near room temperature, as shown in recently discovered lanthanide superhydrides at very high pressures, e.g. LaH10 at 170 GPa…

Very recently carbon-rich NaC6 with sodalite-like structure has been predicted to show superconducting transition temperature above 100 K at relatively low applied (compared to high-Tc hydrides) hydrostatic pressures. We have investigated…

超导电性 · 物理学 2021-09-08 Nazmun Sadat Khan , B. Rahman Rano , Ishtiaque M. Syed , R. S. Islam , S. H. Naqib

Unconventional superconductivity in bilayer graphene has been reported for twist angles $\theta$ near the first magic angle and charged electrostatically with holes near half filling of the lower flat bands. A maximum superconducting…

超导电性 · 物理学 2019-08-06 Dale R. Harshman , Anthony T. Fiory

The search for high-temperature superconductors in hydrides under high pressure has always been a research hotspot. Hydrogen-based superconductors offer an avenue to achieve the long-sought goal of superconductivity at room temperature. We…

超导电性 · 物理学 2023-05-22 Ming Xu , Defang Duan , Wendi Zhao , Decheng An , Hao Song , Tian Cui

The small atomic mass of boron indicates strong electron-phonon coupling, so it may have a brilliant performance in superconductivity. Recently, a new 2D boride sheet with ordered metal vacancies and surface terminals (Mo4/3B2-x) was…

超导电性 · 物理学 2023-11-14 Xiaoran Shi , Junfeng Gao , Shi Qiu , Yuan Chang , Luneng Zhao , Zhen-Guo Fu , Jijun Zhao , Ping Zhang