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Gaining fundamental understanding of crystal nucleation processes in metal alloys is crucial for the development and design of high-performance materials with targeted properties. Yet, crystallization is a complex non-equilibrium process…

材料科学 · 物理学 2022-12-09 Grisell Díaz Leines , Angelos Michaelides , Jutta Rogal

Dynamical density functional simulations reveal structural aspects of crystal nucleation in undercooled liquids: the first appearing solid is amorphous, which promotes the nucleation of bcc crystals, but suppresses the appearance of the fcc…

材料科学 · 物理学 2015-05-30 Gyula I. Tóth , Tamás Pusztai , György Tegze , Gergely Tóth , László Gránásy

Despite numerous efforts from numerical approaches to complement experimental measurements, several fundamental challenges have still hindered one's ability to truly provide an atomistic picture of the nucleation process in nanocrystals.…

Crystallization often proceeds through successive stages that lead to a gradual increase in organization. Using molecular simulation, we determine the nucleation pathway for solid solutions of copper and gold. We identify a new nucleation…

材料科学 · 物理学 2021-04-13 Caroline Desgranges , Jerome Delhommelle

Crystallization of the amorphous phases into metastable crystals plays a fundamental role in the formation of new matter, from geological to biological processes in nature to synthesis and development of new materials in the laboratory.…

材料科学 · 物理学 2023-10-03 Muratahan Aykol , Amil Merchant , Simon Batzner , Jennifer N. Wei , Ekin Dogus Cubuk

Nucleation is the onset of a first-order phase transition by which a metastable phase transforms into a more stable one. Such a phase transition occurs when an initial system initially in equilibrium is destabilized by the change of an…

材料科学 · 物理学 2010-01-27 Emmanuel Clouet

Nucleation and growth of solids from solutions impacts many natural processes and are fundamental to applications in materials engineering and medicine. For a crystalline solid, the nucleus is a nanoscale cluster of ordered atoms, which…

介观与纳米尺度物理 · 物理学 2016-05-17 Duane Loh , Soumyo Sen , Michael Bosman , Shu Fen Tan , Jun Zhong , Christian A. Nijhuis , Petr Kral , Paul Matsudaira , Utkur Mirsaidov

We investigate the early part of the crystal nucleation process in the hard sphere fluid using data produced by computer simulation. We find that hexagonal order manifests continuously in the overcompressed liquid, beginning approximately…

软凝聚态物质 · 物理学 2016-06-29 Joshua T. Berryman , Muhammad Anwar , Sven Dorosz , Tanja Schilling

Recent advances in classical density functional theory are combined with stochastic process theory and rare event techniques to formulate a theoretical description of nucleation, including crystallization, that can predict nonclassical…

化学物理 · 物理学 2019-04-09 James F. Lutsko

Understanding the mechanisms underlying crystal formation is crucial. For most systems, crystallization typically goes through a nucleation process that involves dynamics that happen at short time and length scales. Due to this, molecular…

统计力学 · 物理学 2025-11-04 Steven W. Hall , Porhouy Minh , Sapna Sarupria

Colloidal systems offer the ideal conditions to study the nucleation process, both from an experimental viewpoint, due to their relative large size and long time-scales, and from a modeling point of view, due to the tunability of their…

软凝聚态物质 · 物理学 2016-11-23 John Russo , Hajime Tanaka

Topological order characterizes a class of quantum and classical many-body liquid states that escape the conventional classification by spontaneous symmetry breaking. Many properties of the topological-ordered states still await a clear…

统计力学 · 物理学 2025-11-05 Kouki Kimata , Harukuni Ikeda , Masafumi Udagawa

Homogeneous nucleation processes are important for understanding solidification and the resulting microstructure of materials. Simulating this process requires accurately describing the interactions between atoms, hich is further…

材料科学 · 物理学 2024-10-11 Johannes Sandberg , Thomas Voigtmann , Emilie Devijver , Noel Jakse

Herein, fundamentals of topology and symmetry breaking are used to understand crystallization and geometrical frustration in topologically close-packed structures. This frames solidification from a new perspective that is unique from…

材料科学 · 物理学 2019-06-13 Carline S. Gorham , David E. Laughlin

Control of the crystallization process at the microscopic level makes it possible to generate the nanocrystalline samples with the desired structural and morphological properties, that is of great importance for modern industry. In the…

材料科学 · 物理学 2019-03-25 Bulat N. Galimzyanov , Dinar T. Yarullin , Anatolii V. Mokshin

Topological phases of matter are often understood and predicted with the help of crystal symmetries, although they don't rely on them to exist. In this chapter we review how topological phases have been recently shown to emerge in amorphous…

无序系统与神经网络 · 物理学 2022-08-23 Adolfo G. Grushin

A widely spread method of crystal preparation is to precipitate it from a supersaturated solution. In such a process, control of solution concentration is of paramount importance. Nucleation process, polymorph selection, and crystal habits…

软凝聚态物质 · 物理学 2019-07-10 Tarak Karmakar , Pablo M. Piaggi , Michele Parrinello

Automated analyses of the outcome of a simulation have been an important part of atomistic modeling since the early days, addressing the need of linking the behavior of individual atoms and the collective properties that are usually the…

化学物理 · 物理学 2019-05-22 Michele Ceriotti

Ice nucleation is a process of great relevance in physics, chemistry, technology and environmental sciences, much theoretical and experimental efforts have been devoted to its understanding, but still it remains a topic of intense research.…

软凝聚态物质 · 物理学 2019-06-26 Haiyang Niu , Yi Isaac Yang , Michele Parrinello

Spontaneous onset of a low temperature topologically ordered phase in a 2-dimensional (2D) lattice model of uniaxial liquid crystal (LC) was debated extensively pointing to a suspected underlying mechanism affecting the RG flow near the…

软凝聚态物质 · 物理学 2021-06-29 B. Kamala Latha , Surajit Dhara , V. S. S. Sastry