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The luminescence of fifteen representative Eu$^{2+}$-doped phosphors used for white-LED and scintillation applications is studied through a Constrained Density Functional Theory. Transition energies and Stokes shift are deduced from…

材料科学 · 物理学 2017-09-20 Yongchao Jia , Anna Miglio , Samuel Poncé , Masayoshi Mikami , Xavier Gonze

Narrow-band red-emitting phosphors are a critical component in phosphor-converted light-emitting diodes for highly efficient illumination-grade lighting. In this work, we report the discovery of a quantitative descriptor for narrow-band…

材料科学 · 物理学 2017-06-29 Zhenbin Wang , Iek-Heng Chu , Fei Zhou , Shyue Ping Ong

White light-emitting diodes are gaining popularity and are set to become the most common light source in the U.S. by 2025. However, their performance is still limited by the lack of an efficient red-emitting component with a narrow band…

材料科学 · 物理学 2023-07-10 Julien Bouquiaux , Samuel Poncé , Yongchao Jia , Anna Miglio , Masayoshi Mikami , Xavier Gonze

Understanding the physical mechanisms behind thermal effects in phosphors is crucial for white light-emitting diodes (WLEDs) applications, as thermal quenching of their photoluminescence might render them useless. The two chemically close…

材料科学 · 物理学 2015-08-26 Samuel Ponce , Yongchao Jia , Matteo Giantomassi , Masayoshi Mikami , Xavier Gonze

A presented analytical formulation of (optical)phonon-mediated and momentum-resonant Franck-Condon emission of photoexcited electrons from polar semiconductors is shown to be very consistent with (i) the observed emission properties of a…

材料科学 · 物理学 2025-06-17 W. Andreas Schroeder , L. A. Angeloni , I-J. Shan , L. B. Jones

The recently discovered Sr[Li$_2$Al$_2$O$_2$N$_2$]:Eu$^{2+}$ red phosphor, candidate for the next generation of eco-efficient white light-emitting diodes, exhibits excellent emission spectral position and exceptionally small linewidth. It…

材料科学 · 物理学 2021-09-10 Julien Bouquiaux , Samuel Poncé , Yongchao Jia , Anna Miglio , Masayochi Mikami , Xavier Gonze

Two-dimensional metal-halide perovskites are highly versatile for light-driven applications due to their exceptional variety in material composition, which can be exploited for tunability of mechanical and optoelectronic properties. The…

In a comprehensive study, we investigate the electronic scattering effects in EuFe$_{2}$(As$_{1-x}$P$_{x}$)$_{2}$ by using Fourier-transform infrared spectroscopy. In spite of the fact that Eu$^{2+}$ local moments order around $T_\text{Eu}…

The formation energies and electronic structure of europium doped zinc oxide has been determined using DFT and many-body $GW$ methods. In the absence of intrisic defects we find that the europium-$f$ states are located in the ZnO band gap…

材料科学 · 物理学 2016-03-23 M. Lorke , T. Frauenheim , A. L. da Rosa

Currently,lanthanide ions doped luminescence materials applying as optical thermometers have arose much concern. Basing on the different responses of two emissions to temperature, the fluorescence intensity ratio (FIR) technique can be…

材料科学 · 物理学 2023-02-22 Yude Niu , Yuzhen Wang , Kaiming Zhu , Wanggui Ye , Zhe Feng , Hui Liu , Xin Yi , Yihuan Wang , Xuanyi Yuan

Optical spectra (absorption, emission, excitation, decay) and dielectric relaxation were measured for divalent europium (and partially for ytterbium) in lanthanum fluoride crystals. Absorption of Eu$^{2+}$ contains not only asymmetric…

材料科学 · 物理学 2015-11-03 E A Radzhabov , R Yu Shendrik

The magnetic order of the localized Eu$^{2+}$ spins in optimally-doped Eu(Fe$_{1-x}$Ir$_{x}$)$_{2}$As$_{2}$ ($\mathit{x}$ = 0.12) with superconducting transition temperature $\mathit{T_{SC}}$ = 22 K was investigated by single-crystal…

超导电性 · 物理学 2015-02-20 W. T. Jin , Wei Li , Y. Su , S. Nandi , Y. Xiao , W. H. Jiao , M. Meven , A. P. Sazonov , E. Feng , Yan Chen , C. S. Ting , G. H. Cao , Th. Brückel

Luminescence in Eu$^{2+}$ activated materials corresponds to a transition from an excited state where the lowest Eu 5$d$ level is filled with one electron (often called the (Eu$^{2+}$)$^*$ state) to the ground state with half-filled 4$f$…

材料科学 · 物理学 2014-08-12 A. Chaudhry , R. Boutchko , S. Chourou , G. Zhang , N. Grønbech-Jensen , A. Canning

A review of electronic properties of insulating-, boron- and phosphorus-doped diamond is given. The main goal is, to show data in a wider context, to reveal trends and limitations with respect to carrier mobilities, conductivities, p- and…

材料科学 · 物理学 2020-05-11 Christoph E. Nebel

The temperature dependence of the complex optical properties of the layered phosphide material EuCd$_2$P$_2$ have been measured over a wide frequency range above and below $T_{\rm N} \simeq 11.5$ K for light polarized in the $a-b$ planes.…

强关联电子 · 物理学 2023-03-23 C. C. Homes , Z. -C. Wang , K. Fruhling , F. Tafti

White light emitting diodes (LEDs) have become the most widely used lighting devices due to their high luminous efficiency, environmental friendliness, long lifespan, and energy-saving advantages. Currently, the production of white light…

光学 · 物理学 2025-08-20 Rouziaji Alimu , Jiang Yu , Wang Maohua , Aierken Sidike

The Fermi surfaces (FS's) and band dispersions of EuRh2As2 have been investigated using angle-resolved photoemission spectroscopy. The results in the high-temperature paramagnetic state are in good agreement with the full potential…

We establish the phase diagram of Eu$_{1-x}$La$_x$Fe$_2$As$_2$ system as a function of doping level x and the pressure by measuring the resistivity and magnetic susceptibility. The pressure can suppress the spin density wave (SDW) and…

The interplay between superconductivity and Eu$^{2+}$ magnetic ordering in Eu(Fe$_{1-x}$Ir$_{x}$)$_{2}$As$_{2}$ is studied by means of electrical transport and magnetic measurements. For the critically doped sample…

超导电性 · 物理学 2013-06-11 U. B. Paramanik , Debarchan Das , R. Prasad , Z. Hossain

The phase diagrams of EuFe$_{2-x}$Co$_x$As$_2$ $(0 \leq x \leq 0.4)$ and EuFe$_2$As$_{2-y}$P$_y$ $(0 \leq y \leq 0.43)$ are investigated by Eu$^{2+}$ electron spin resonance (ESR) in single crystals. From the temperature dependence of the…

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