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Lithium metal penetrations through the liquid-electrolyte-wetted porous separator and solid electrolytes are a major safety concern of next-generation rechargeable metal batteries. The penetrations were frequently discovered to occur…

应用物理 · 物理学 2020-08-13 Youngju Lee , Bingyuan Ma , Peng Bai

Higher energy density and longer lifetime are the requirements for next-generation lithium-ion batteries. A promising anode material is silicon, which offers high specific capacity, but its significant volume change during lithiation and…

Aqueous rechargeable batteries are promising energy storage devices for the high safety, environmental friendliness, and easy assembly. However, their cycle stability and low temperature performance are limited by the narrow electrochemical…

化学物理 · 物理学 2022-06-17 Yuewang Yang , Sijing Liu , Zhaowen Bai , Baoling Huang

Some rate of oxidation and reduction side-reactions will inevitably coexist in most rechargeable batteries, contributing to reversible and irreversible self-discharge. While parasitic reduction traps electrons, parasitic oxidation donates…

化学物理 · 物理学 2026-02-17 Marco-Tulio F. Rodrigues

The penetrations of lithium-ion batteries in transport, energy and communication systems are increasing rapidly. A meticulous model applicable for precise in-situ monitoring and convenient online controlling is in sought to bridge the gap…

系统与控制 · 电气工程与系统科学 2022-03-22 Yuxuan Gu , Jianxiao Wang , Yuanbo Chen , Zhongwei Deng , Hongye Guo , Kedi Zheng , Qixin Chen

Aqueous batteries play an increasingly important role for the development of sustainable and safety-prioritised energy storage solutions. Compared to conventional lithium-ion batteries, the cell chemistry in aqueous batteries share many…

材料科学 · 物理学 2024-06-04 Alicia van Hees , Zhan-Yun Zhang , Aishwarya Sudhama , Chao Zhang

Sodium-ion batteries exhibit significant promise as a viable alternative to current lithium-ion technologies owing to their sustainability, low cost per energy density, reliability, and safety. Despite recent advancements in cathode…

Fast-charging of lithium-ion batteries is essential for electric vehicle adoption, but aggressive charging can accelerate its degradation and create safety risks. This study investigates a control framework that coordinates charging current…

系统与控制 · 电气工程与系统科学 2026-05-26 Frederic Fabry , Alessio Lodge , Robinson Medina , Feye Hoekstra , Steven Wilkins , Madalin Frunzete

This article considers a model formulation and an adaptive observer design for the simultaneous estimation of the state of charge and crossover flux in disproportionation redox flow batteries. This novel nonaqueous battery chemistry allows…

最优化与控制 · 数学 2020-06-05 Pedro Ascencio , Kirk Smith , Charles W. Monroe , David Howey

Despite the widespread applications of machine learning force fields (MLFF) in solids and small molecules, there is a notable gap in applying MLFF to simulate liquid electrolyte, a critical component of the current commercial lithium-ion…

This study presents a comprehensive Multiphysics model for zinc-ion batteries (ZIBs), incorporating electrochemical aspects. The model integrates the mass transport of Zn2+ ions, charge transfer, and solid diffusion to predict performance…

材料科学 · 物理学 2025-05-06 Roya Rajabi , Shichen Sun , Booker Wu , Jamil Khan , Kevin Huang

Battery electrode surfaces are generally coated with electronically insulating solid films of thickness 1-50 nm. Both electrons and Li+ can move at the electrode-surface film interface in response to the voltage, which adds complexity to…

材料科学 · 物理学 2015-07-10 Kevin Leung , Andrew Leenheer

Solid mixed conductors with significant ionic as well as electronic conduction play a pivotal role for mass transfer and storage as required in battery electrodes. Single-phase materials with simultaneously high electronic and ionic…

介观与纳米尺度物理 · 物理学 2017-09-11 M. Kühne , F. Paolucci , J. Popovic , P. M. Ostrovsky , J. Maier , J. H. Smet

Rechargeable lithium metal batteries have been widely investigated recently, driven by the global trend for the electrification of transportation. Understanding the dynamics of lithium metal electrodeposition is crucial to design safe and…

材料科学 · 物理学 2022-07-15 Shoutong Jin , Linming Zhou , Yongjun Wu , Shang Zhu , Qilong Zhang , Hui Yang , Yuhui Huang , Zijian Hong

Conversion cathode materials are gaining interest for secondary batteries due to their high theoretical energy and power density. However, practical application as a secondary battery material is currently limited by practical issues such…

Na, K and Ca-ion battery electrode materials with appropriate electrochemical properties are desirable candidates for replacing lithium-ion batteries (LIBs) because of their natural richness and low cost. Recently, MoO2 has been reported as…

计算物理 · 物理学 2019-03-27 Yongchao Rao , Song Yu , Xiao Gu , Xiangmei Duan

We study numerically localised short circuits in Li||Bi liquid metal batteries. In the prototype of a classical, three liquid-layer system, we assume a perceptible local deformation of the Li-salt interface. We find that there always exists…

流体动力学 · 物理学 2021-08-27 Sabrina Bénard , Norbert Weber , Gerrit Maik Horstmann , Steffen Landgraf , Tom Weier

Hybrid materials, which combine inorganic and molecular components, often exhibit structural flexibility that enables unusual functional responses. Among them, Prussian blue analogues (PBAs) are a promising class for post-lithium battery…

材料科学 · 物理学 2025-09-08 J. Cattermull , B. Jagger , S. J. Cassidy , S. Dhir , P. K. Allan , M. Pasta , A. L. Goodwin

The biggest challenge for the commercialization of layered structured nickel rich lithium transition metal oxide cathode is the capacity and voltage fading. Resolving this problem over the years follows an incremental progress. In this…

材料科学 · 物理学 2017-10-18 Pengfei Yan , Jianming Zheng , Jian Liu , Biqiong Wang , Xueliang Sun , Chongmin Wang , Ji-Guang Zhang

The solid-state electrolyte is critical for achieving next-generation high energy density and high-safety batteries. Solid polymer electrolytes (SPEs) possess great potential for commercial application owing to their compatibility with the…

材料科学 · 物理学 2023-07-04 Xiong Xiong Liu , Shengfa Feng , Pengcheng Yuan , Yaping Wang , Long Pan , ZhengMing Sun
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