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Optical spectroscopy with broadband femtosecond laser pulses often involves simultaneous excitation of multiple molecular species with close resonance frequencies. Interpreting the collective optical response from molecular mixtures…

光学 · 物理学 2016-04-13 Martin Bitter , Valery Milner

We consider deflection of rotating symmetric molecules by inhomogeneous optical and static electric fields, compare results with the case of linear molecules, and find new singularities in the distribution of the scattering angle.…

化学物理 · 物理学 2015-05-28 Erez Gershnabel , Ilya Sh. Averbukh

Raman-based technologies have enabled many ground-breaking scientific discoveries related to surface science, single molecule chemistry and biology. For example, researchers have identified surface bound molecules by their Raman vibrational…

光学 · 物理学 2020-03-12 Xiaoqin Shen , Hyungwoo Choi , Dongyu Chen , Wei Zhao , Andrea M. Armani

Raman scattering, an inelastic scattering mechanism, provides information about molecular excitation energies and can be used to identify chemical compounds. Albeit being a powerful analysis tool, especially for label-free biomedical…

光学 · 物理学 2018-10-12 Sebastian Karpf , Matthias Eibl , Wolfgang Wieser , Thomas Klein , Robert Huber

We propose a method for increasing the Raman scattering from an ensemble of molecules by up to four orders of magnitude. Our method requires an additional coherent source of IR radiation with the half-frequency of the Stokes shift. This…

量子物理 · 物理学 2019-04-24 V. Yu. Shishkov , E. S. Andrianov , A. A. Pukhov , A. P. Vinogradov , A. A. Lisyansky

Molecular optomechanics stems from the description of Raman scattering in the presence of an optical resonator using a cavity optomechanics formalism. We extend the molecular optomechanics formalism to the case of hybrid…

Polyatomic molecules equipped with optical cycling centers (OCCs), enabling continuous photon scattering during optical excitation, are exciting candidates for advancing quantum information science. However, as these molecules grow in size…

Several powerful techniques exist to detect topologically protected surface states of weakly-interacting electronic systems. In contrast, surface modes of strongly interacting systems which do not carry electric charge are much harder to…

强关联电子 · 物理学 2016-08-24 Brent Perreault , Johannes Knolle , Natalia B. Perkins , F. J. Burnell

Investigation of organic molecular films by a method Raman of a spectroscopy is carried out. It is shown, that values of frequencies of lines in a spectrum of the lattice oscillations of the molecular films are depressed in comparison with…

光学 · 物理学 2007-05-23 M. A. Korshunov

We demonstrate state detection based on coherent Raman repumping and a two-color Raman state transfer. The Raman coupling during detection selectively eliminates unwanted dark states in the fluorescence cycle without compromising the…

量子物理 · 物理学 2011-05-05 Boon Leng Chuah , Nick C. Lewty , Murray D. Barrett

We use an optical centrifuge to excite coherent rotational wave packets in N$_2$O, CS$_2$ and OCS molecules with rotational quantum numbers reaching up to J=465, 690 and 1186, respectively. Time-resolved rotational spectroscopy at such…

化学物理 · 物理学 2017-10-25 A. A. Milner , A. Korobenko , J. W. Hepburn , V. Milner

The interplay between the oxidation state and the optical properties of molecules plays a key role for applications in displays, sensors or molecular-based memories. The fundamental mechanisms occurring at the level of a single-molecule…

介观与纳米尺度物理 · 物理学 2018-08-15 Benjamin Doppagne , Michael C. Chong , Hervé Bulou , Alex Boeglin , Fabrice Scheurer , Guillaume Schull

We describe a robust and reliable fluorescence detector for single atoms that is fully integrated into an atom chip. The detector allows spectrally and spatially selective detection of atoms, reaching a single atom detection efficiency of…

We propose a scheme for direct laser deceleration of molecules based on a vibrational transition-mediated bichromatic force (VBCF). By precisely engineering mid-infrared optical fields, we establish coherent absorption-stimulated emission…

原子物理 · 物理学 2026-05-20 Meng-Yi Yu , Ya-Nan Lv , Cun-Feng Cheng , Shui-Ming Hu

Photonic molecules - particular systems composed of coupled optical resonators - emulate the behavior of complex physical systems exhibiting discrete energy levels. In this work, we present a novel photonic molecule composed of two strongly…

光学 · 物理学 2023-12-06 Sara Kacmoli , Deborah L. Sivco , Claire F. Gmachl

The random motion of molecules in living cells has consistently been reported to deviate from standard Brownian motion, a behavior coined as ``anomalous diffusion''. Fluorescence Correlation Spectroscopy (FCS) is a powerful method to…

Under the local plasmonic excitation, the Raman images of a single molecule can now reach sub-nanometer resolution. We report here a theoretical description of the interaction between a molecule and a highly confined plasmonic field. It is…

介观与纳米尺度物理 · 物理学 2015-08-06 Sai Duan , Guangjun Tian , Yongfei Ji , Jiushu Shao , Zhenchao Dong , Yi Luo

Identifying chemical compounds is essential in several areas of science and engineering. Laser-based techniques are promising for autonomous compound detection because the optical response of materials encodes enough electronic and…

机器学习 · 计算机科学 2023-03-17 Thulasi Bikku , Rubén A. Fritz , Yamil J. Colón , Felipe Herrera

The detection of fluorescence with submolecular resolution enables the exploration of spatially varying photon yields and vibronic properties at the single-molecule level. By placing individual polycyclic aromatic hydrocarbon molecules into…

介观与纳米尺度物理 · 物理学 2018-08-01 Jörg Kröger , Benjamin Doppagne , Fabrice Scheurer , Guillaume Schull

The inability to efficiently tune the optical properties of waveguiding structures has been one of the major hurdles for the future scalability of integrated photonic systems. In silicon photonics, although dynamic tuning has been achieved…

光学 · 物理学 2017-10-10 You-Chia Chang , Samantha P. Roberts , Brian Stern , Michal Lipson