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Following the idea that hydrogen-rich compounds might be high-T$_c$ superconductors at high pressures, and the very recent breakthrough in predicting and synthesizing hydrogen sulfide with record-high T$_c$ = 203 K, ab initio evolutionary…

超导电性 · 物理学 2017-04-19 M. M. Davari Esfahani , A. R. Oganov , H. Niu , J. Zhang

Low-temperature (down to $\sim$ 50 mK) thermal conductivity measurements with the heat flow direction along the inter-plane tetragonal $c$-axis, $\kappa_c$, were used to study the superconducting state of heavy fermion CeIrIn$_5$.…

超导电性 · 物理学 2022-04-14 H. Shakeripour , M. A. Tanatar , C. Petrovic , Louis Taillefer , Louis Taillefer

First-order phase transitions are characterized by a discontinuous first derivative of the Gibbs free energy, so that volumes and entropies are discontinuous. Such transitions are common in the crystalline state, but extremely rare in…

材料科学 · 物理学 2017-09-29 Laura Henry , Mohamed Mezouar , Gaston Garbarino , David Sifré , Gunnar Weck , Frederic Datchi

It has been reported that graphite hosts room temperature superconductivity. Here we provide new results that confirm these claims on different samples of highly oriented pyrolytic graphite (HOPG) and commercial flexible graphite gaskets…

We report on the discovery of superconductivity in the previously unknown compound Ta$_4$Rh$_2$C$_{1-\delta}$. Ta$_4$Rh$_2$C$_{1-\delta}$ crystallizes in the $\eta$-carbide structure type, in the cubic space group $Fd\bar{3}m$ (No.227) with…

We study the electronic and lattice dynamical properties of compressed solid germane in the pressure range up to 200 GPa with density functional theory. A stable metallic structure, Aba2, with a base-centered orthorhombic symmetry was found…

超导电性 · 物理学 2008-05-01 Chao Zhang , Yanling Li , Xiaojia Chen , Ruiqin Zhang , Haiqing Lin

New stable thorium decahydride $Fm\bar{3}m$-$ThH_{10}$, a record high-temperature superconductor with $T_C$ up to 241 K ($-32^{\circ}C$), critical field $H_C$ up to 71T and superconducting gap ${\Delta_0}$ = 52 meV at 80-100 GPa was…

Recent experimental developments in hydrogen-rich materials in high pressures have put this class of materials above others in the race toward room temperature superconductivity. As it is the basis of all the materials in this class, the…

超导电性 · 物理学 2022-02-03 Mehmet Dogan , Sehoon Oh , Marvin L. Cohen

We identify a new family of boron-rich compounds consisting of interconnected B$_{12}$ icosahedra, and electropositive guest atoms ($X$) in interstitial sites. These structures were found through first-principles crystal structure…

超导电性 · 物理学 2026-05-15 Simone Di Cataldo , Antonio Sanna , Lilia Boeri

All solid phases of bismuth under pressure, but one, have been experimentally found to superconduct. From Bi-I to Bi-V, avoiding Bi-IV, they become superconductors and perhaps Bi-IV may also become superconductive. To investigate the…

High-entropy alloy (HEA) superconductors have attracted significant attention due to their exceptional low-temperature mechanical and superconducting properties. We report the synthesis and thorough characterization of an equiatomic HEA…

超导电性 · 物理学 2024-04-29 S. Jangid , P. K. Meena , R. K. Kushwaha , S. Srivastava , P. Manna , P. Mishra , S. Sharma , R. P. Singh

We report experimental discovery of tantalum polyhydride superconductor. It was synthesized at high pressure and high temperature conditions using diamond anvil cell combined with in-situ high pressure laser heating techniques. The…

We have investigated the pressure-induced phase transition and superconducting properties of niobium disulfide (NbS$_2$) based on the density functional theory. The structures of NbS$_2$ at pressures from 0 to 200 GPa were predicted using…

超导电性 · 物理学 2014-10-31 Zhong-Li Liu , Ling-Cang Cai , Xiu-Lu Zhang

H$_3$S is believed to the most possible high-temperature superconducting ($T_{\text{c}}$) phase of hydrogen sulfide at $\sim$200 GPa. It's isotope substitution of hydrogen (H) by deuterium (D), however, shows an anomalous $T_{\text{c}}$…

超导电性 · 物理学 2016-07-11 Ying Yuan , Yexin Feng , Lifeng Bian , Dong-Bo Zhang , Xin-Zheng Li

The superconducting current has been observed in mesa-heterostructures Nb/Au/Sr2IrO4/YBa2Cu3Ox with Sr2IrO4 interlayer thickness d=5 and 7 nm and in-plane sizes L=10-50 mcm. A strontium iridate, Sr2IrO4, is known as a canted…

We have studied the half-Heusler compound TbPdBi through resistivity, magnetization, Hall effect and heat capacity measurements. A semimetal behavior is observed in its normal state transport properties, which is characterized by a large…

超导电性 · 物理学 2018-08-01 H. Xiao , T. Hu , W. Liu , Y. L. Zhu , P. G. Li , G. Mu , J. Su , K. Li , Z. Q. Mao

We map the high-pressure phase diagram of nitrogen hydrate up to 16 GPa at room temperature by combining neutron diffraction, Raman spectroscopy, and crystal structure prediction. We reveal a rich sequence of structural transformations,…

Transport and magnetic studies of PbTaSe$_2$ under pressure suggest existence of two superconducting phases with the low temperature phase boundary at $\sim 0.25$ GPa that is defined by a very sharp, first order, phase transition. The first…

Superconductivity in the recently proposed ground-state structures of atomic metallic hydrogen is investigated over the pressure range 500 GPa to 3.5 TPa. Near molecular dissociation, the electron--phonon coupling $\lambda$ and renormalized…

超导电性 · 物理学 2015-05-28 Jeffrey M. McMahon , David M. Ceperley

Here we report the discovery of superconductivity in multiple phases of the compressed GeSb2Te4 (GST) phase change memory alloy, which has attracted considerable attention for the last decade due to its unusual physical properties with many…