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We investigate theoretically the ability of an optical centrifuge - a laser pulse whose linear polarization is rotating at an accelerated rate, to control molecular rotation in the regime when the rigid-rotor approximation breaks down due…

量子物理 · 物理学 2025-12-11 J. M. García-Garrido , V. Milner , C. P. Koch , R. González-Férez

Since its invention in 1999, optical centrifuge has become a powerful tool for controlling molecular rotation and studying molecular dynamics and molecular properties at extreme levels of rotational excitation. The technique has been…

仪器与探测器 · 物理学 2020-05-20 Ian MacPhail-Bartley , Walter W. Wasserman , Alexander A. Milner , V. Milner

The control of ultrafast molecular rotational motion has benefited from the development of innovative techniques in strong-field laser physics. Here, we theoretically demonstrate a novel type of coherent control by inducing rotation of an…

化学物理 · 物理学 2018-08-27 Alec Owens , Andrey Yachmenev , Jochen Küpper

We demonstrate experimentally a method of varying the degree of directionality in laser-induced molecular rotation. To control the ratio between the number of clockwise and counter-clockwise rotating molecules (with respect to a fixed…

化学物理 · 物理学 2021-05-05 Alexander A. Milner , Valery Milner

Laser control of molecular rotation is an area of active research. A number of recent studies has aimed at expanding the reach of rotational control to extreme, previously inaccessible rotational states, as well as controlling the…

量子物理 · 物理学 2015-01-13 V. Milner , J. W. Hepburn

We computationally demonstrate a new method for coherently controlling the rotation-axis direction in asymmetric top molecules with an optical centrifuge. Appropriately chosen electric-field strengths and the centrifuge's acceleration rate…

化学物理 · 物理学 2021-06-16 Emil J. Zak , Andrey Yachmenev , Jochen Küpper

We introduce a new scheme for controlling the sense of molecular rotation. By varying the polarization and the delay between two ultrashort laser pulses, we induce unidirectional molecular rotation, thereby forcing the molecules to rotate…

量子物理 · 物理学 2015-05-13 Sharly Fleischer , Yuri Khodorkovsky , Yehiam Prior , Ilya Sh. Averbukh

We present an analysis of two experimental approaches to controlling the directionality of molecular rotation with ultrashort laser pulses. The two methods are based on the molecular interaction with either a pair of pulses (a "double kick"…

光学 · 物理学 2015-06-11 C. Bloomquist , S. Zhdanovich , A. A. Milner , V. Milner

We consider optical properties of a gas of molecules that are brought to fast unidirectional spinning by a pulsed laser field. It is shown that a circularly polarized probe light passing through the medium inverts its polarization…

光学 · 物理学 2015-06-17 Uri Steinitz , Yehiam Prior , Ilya Sh. Averbukh

We propose and computationally study a method for simultaneously orienting the angular momentum of asymmetric top molecules along: 1) a laboratory-fixed direction; 2) the molecular intermediate moment of inertia axis; 3) the laser field…

量子物理 · 物理学 2022-11-21 Emil J. Zak

Extremely fast rotating molecules carrying significantly more energy in their rotation than in any other degree of freedom are known as "super rotors". It has been speculated that super rotors may exhibit a number of unique properties.…

光学 · 物理学 2013-06-11 Aleksey Korobenko , Alexander A. Milner , Valery Milner

An optical centrifuge is a laser pulse which enables controlled rotational excitation of molecules. Centrifuged molecules rotating with well-defined angular frequencies are ideal candidates to probe many-body quantum systems at the…

化学物理 · 物理学 2025-10-10 K. Wang , A. Hardikar , A. A. Milner , V. Milner

We report on the first experimental demonstration of enantioselective rotational control of chiral molecules with a laser field. In our experiments, two enantiomers of propylene oxide are brought to accelerated unidirectional rotation by…

Strong laser-induced magnetization of oxygen gas at room temperature and atmospheric pressure is achieved experimentally on the sub-nanosecond time scale. The method is based on controlling the electronic spin of paramagnetic molecules by…

量子物理 · 物理学 2017-06-21 A. A. Milner , A. Korobenko , V. Milner

Following excitation by a strong ultra-short laser pulse, molecules develop coordinated rotational motion, exhibiting transient alignment along the direction of the laser electric field, followed by periodic full and fractional revivals…

量子物理 · 物理学 2007-05-23 Sharly Fleischer , Ilya. Sh. Averbukh , Yehiam Prior

We introduce a new optical tool - a "two-dimensional optical centrifuge", capable of aligning molecules in extreme rotational states. Unlike the conventional centrifuge, which confines the molecules in the plane of their rotation, its…

化学物理 · 物理学 2016-05-18 A. A. Milner , A. Korobenko , V. Milner

We outline the design and characterization of a laser pulse shaper, which creates an ``ultraslow optical centrifuge'' - a linearly polarized field whose polarization vector rotates with arbitrarily low angular acceleration. By directly…

化学物理 · 物理学 2026-03-12 Kevin Wang , Ian MacPhail-Bartley , Cameron E. Peters , Valery Milner

We investigate the prospects of creating broad rotational wave packets by means of molecular interaction with long sequences of intense femtosecond pulses. Using state-resolved rotational Raman spectroscopy of oxygen, subject to a sequence…

量子物理 · 物理学 2016-01-27 M. Bitter , V. Milner

We demonstrate a new spectroscopic method for studying electronic transitions in molecules with extremely broad range of angular momentum. We employ an optical centrifuge to create narrow rotational wave packets in the ground electronic…

化学物理 · 物理学 2017-09-13 Aleksey Korobenko , Alexander A. Milner , John W. Hepburn , Valery Milner

Laser cooling of molecules employing broadband optical pumping involves a timescale separation between laser excitation and spontaneous emission. Here, we optimize the optical pumping step using shaped laser pulses. We derive two…

量子物理 · 物理学 2013-12-24 Daniel M. Reich , Christiane P. Koch
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