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Liquid films of nanometric thickness are prone to spinodal dewetting driven by disjoining pressure, meaning that a non-wetting liquid film of homogeneous thickness in the range of tens of nanometers will spontaneously break into droplets.…

流体动力学 · 物理学 2025-04-11 Tilman Richter , Paolo Malgaretti , Jens Harting

The stability of thin liquid films on a surface depends on the excess free energy of the system involving various short-range and long-range interactions. In an unstable condition, thin liquid films may dewet into multiple small-sized…

软凝聚态物质 · 物理学 2022-03-24 Bidisha Bhatt , Shivam Gupta , Vasudevan Sumathi , Sivasurender Chandran , Krishnacharya Khare

The spontaneous formation of droplets via dewetting of a thin fluid film from a solid substrate allows for materials nanostructuring, under appropriate experimental control. While thermal fluctuations are expected to play a role in this…

软凝聚态物质 · 物理学 2015-05-21 S. Nesic , R. Cuerno , E. Moro , L. Kondic

Dewetting of thin liquid films is monitored in situ by atomic force microscopy, results are compared with simulations. The experimental setting is mimicked as close as possible using the experimental parameters including the effective…

软凝聚态物质 · 物理学 2007-05-23 Jürgen Becker , Günther Grün , Ralf Seemann , Karin Jacobs

The instability, dynamics and morphological transitions of patterns in thin liquid films on periodic striped surfaces (consisting of alternating less and more wettable stripes) are investigated based on 3-D nonlinear simulations that…

软凝聚态物质 · 物理学 2009-11-07 K. Kargupta , A. Sharma

Based on the thermodynamic variation to the free energy functional, we propose a sharp-interface model for simulating solid-state dewetting of thin films on rigid curved substrates in two dimensions. This model describes the interface…

材料科学 · 物理学 2018-11-14 Wei Jiang , Yan Wang , David J. Srolovitz , Weizhu Bao

Switchable and adaptive substrates emerged as valuable tools for the control of wetting and actuation of droplet motion. Here we report a computational study of the dynamics of an unstable thin liquid film deposited on a switchable…

流体动力学 · 物理学 2024-01-03 Stefan Zitz , Andrea Scagliarini , Jens Harting

Solid-state dewetting is the process by which thin solid films break up and retract on a substrate, forming nanostructures. While dewetting of single-crystalline films is understood as a surface-energy-driven process mediated by surface…

The dewetting of thin nanofilms is significantly impacted by thermal fluctuations, liquid-solid slip, and disjoining pressure, which can be described by lubrication equations augmented by appropriately scaled noise terms, known as…

流体动力学 · 物理学 2024-10-29 Yixin Zhang

The stability of thin liquid coatings is of fundamental interest in every- day life. Homogeneous and non-volatile liquid coatings may dewet either by heterogeneous nucleation, thermal nucleation, or spinodal dewetting. Wetting and dewetting…

软凝聚态物质 · 物理学 2008-05-29 Karin Jacobs , Ralf Seemann , Stephan Herminghaus

We review recent experiments on dewetting thin films of evaporating colloidal nanoparticle suspensions (nanofluids) and discuss several theoretical approaches to describe the ongoing processes including coupled transport and phase changes.…

A mathematical model is developed to analyze the growth/decay rate of surface perturbations of an ultrathin metal film on an amorphous substrate (SiO_{2}). The formulation combines the approach of Mullins [J. Appl. Phys. v30, 77, 1959] for…

材料科学 · 物理学 2015-06-25 Christopher Favazza , Ramki Kalyanaraman , Radhakrishna Sureshkumar

The dewetting dynamics of an ultrathin film is studied in the presence of evaporation - or reaction - of adatoms on the substrate. KMC simulations are in good agreement with an analytical model with diffusion, rim facetting, and substrate…

材料科学 · 物理学 2015-06-03 A. Chame , O. Pierre-Louis

Controlling the spatial distribution of liquid droplets on surfaces via surface energy patterning can be used to control material delivery to specified regions via selective liquid/solid wetting. While studies of the equilibrium shape of…

软凝聚态物质 · 物理学 2007-05-23 Gary S. Grest , David R. Heine , Edmund B. Webb

It is known from both experiments and molecular dynamics simulations that chemically patterning a solid surface has an effect on the flow of an adjacent liquid. This fact is in stark contrast with predictions of classical fluid mechanics…

流体动力学 · 物理学 2012-02-17 J. E. Sprittles , Y. D. Shikhmurzaev

We present a phase-field model for simulating the solid-state dewetting of anisotropic crystalline films on non-planar substrates. This model exploits two order parameters to trace implicitly the crystal free surface and the substrate…

介观与纳米尺度物理 · 物理学 2025-05-01 Emma Radice , Marco Salvalaglio , Roberto Bergamaschini

When a film of a liquid suspension of nanoparticles or a polymer solution is deposited on a surface, it may dewet from the surface and as the solvent evaporates the solute particles/polymer can be deposited on the surface in regular line…

软凝聚态物质 · 物理学 2013-03-25 Lubor Frastia , Andrew J. Archer , Uwe Thiele

We study a model for a thin liquid film dewetting from a periodic heterogeneous substrate (template). The amplitude and periodicity of a striped template heterogeneity necessary to obtain a stable periodic stripe pattern, i.e. pinning, are…

软凝聚态物质 · 物理学 2007-05-23 Lutz Brusch , Heiko Kuehne , Uwe Thiele , Markus Baer

When thin films are grown on a substrate by chemical vapor deposition, the evolution of the first deposited layers may be described, on mesoscopic scales, by dynamical models of the reaction-diffusion type. For monoatomic layers, such…

介观与纳米尺度物理 · 物理学 2015-06-16 Daniel Walgraef

Recent experiments have shown that the striking structure formation in dewetting films of evaporating colloidal nanoparticle suspensions occurs in an ultrathin `postcursor' layer that is left behind by a mesoscopic dewetting front. Various…

软凝聚态物质 · 物理学 2010-02-04 A. J. Archer , M. J. Robbins , U. Thiele
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