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We study the influence of laser radiation on the electron transport through a molecular wire weakly coupled to two leads. In the absence of a generalized parity symmetry, the molecule rectifies the laser induced current, resulting in…

介观与纳米尺度物理 · 物理学 2007-05-23 Jörg Lehmann , Sigmund Kohler , Peter Hänggi , Abraham Nitzan

We excite diatomic oxygen and nitrogen to high rotational states with an optical centrifuge and study their dynamics in external magnetic field. Ion imaging is employed to directly visualize, and follow in time, the rotation plane of…

化学物理 · 物理学 2015-04-08 Aleksey Korobenko , Valery Milner

We investigate the full control over the orientation of a non-symmetric molecule by using moderate and weak electric fields. Quantum Optimal Control techniques allow us to orient any axis of 6-chloropyridazine-3-carbonitrile, which is taken…

量子物理 · 物理学 2023-11-21 Rosario González-Férez , Juan J. Omiste

The soft character of organic materials leads to strong coupling between molecular nuclear and electronic dynamics. This coupling opens the way to control charge transport in organic electronic devices by inducing molecular vibrational…

The goal of the present article is to review the major developments that have led to the current understanding of molecule-field interactions and experimental methods for manipulating molecules with electromagnetic fields. Molecule-field…

原子物理 · 物理学 2013-09-18 Mikhail Lemeshko , Roman V. Krems , John M. Doyle , Sabre Kais

We theoretically explore the precise control of a molecular polariton by strongly coupling the lowest three rotational states of a single molecule with a single-mode cavity. We examine two distinct cavity resonance configurations: a…

量子物理 · 物理学 2025-02-17 Li-Bao Fan , Hai-Ji Li , Qi Chen , Hang Zhou , Heng Liu , Chuan-Cun Shu

We experimentally demonstrate control of molecular rotation in bulk superfluid $^4\mathrm{He}$. Metastable helium dimers, $\mathrm{He}_2^*$, are rotationally excited by a periodic train of linearly polarized femtosecond laser pulses. We…

A general method for rotational microwave spectroscopy and control of polar molecular ions via direct microwave addressing is considered. Our method makes use of spatially varying AC Stark shifts, induced by far off-resonant, focused laser…

原子物理 · 物理学 2015-06-16 M. Shi , P. F. Herskind , M. Drewsen , I. L. Chuang

Understanding and controlling the electronic as well as ro-vibrational motion and, thus, the entire chemical dynamics in molecules is the ultimate goal of ultrafast laser and imaging science. In photochemistry, laser-induced dissociation…

We demonstrate that the current laser technology used for field-free molecular alignment via a cascade of Raman rotational transitions allows for observing long-discussed non-linear quantum phenomena in the dynamics of the periodically…

量子物理 · 物理学 2015-05-30 Johannes Floß , Ilya Sh. Averbukh

We report the first experimental observation of non-adiabatic field-free orientation of a heteronuclear diatomic molecule (CO) induced by an intense two-color (800 and 400 nm) femtosecond laser field. We monitor orientation by measuring…

A theoretical model of nuclear spin conversion in molecules controlled by an external electromagnetic radiation resonant to rotational transition has been developed. It has been shown that one can produce an enrichment of spin isomers and…

化学物理 · 物理学 2009-11-06 P. L. Chapovsky

Combining the features of molecular wires and femtosecond laser pulses gives the unique opportunity to optically switch electron currents in molecular devices with very high speed. Based on a weak-coupling approximation between wire and…

介观与纳米尺度物理 · 物理学 2007-08-22 GuangQi Li , Sven Welack , Michael Schreiber , Ulrich Kleinekathoefer

We propose a new type of a chiral metamaterial based on an ensemble of artificial molecules formed by three identical quantum-dots in a triangular arrangement. A static magnetic field oriented perpendicular to the plane breaks mirror…

介观与纳米尺度物理 · 物理学 2014-12-04 Panagiotis Kotetes , Pei-Qing Jin , Michael Marthaler , Gerd Schön

Simulations can help unravel the complicated ways in which molecular structure determines function. Here, we use molecular simulations to show how slight alterations of a molecular motor's structure can cause the motor's typical dynamical…

统计力学 · 物理学 2023-08-21 Alex Albaugh , Geyao Gu , Todd R. Gingrich

Localized heating of a gas by intense laser pulses leads to interesting acoustic, hydrodynamic and optical effects with numerous applications in science and technology, including controlled wave guiding and remote atmosphere sensing.…

光学 · 物理学 2015-09-30 A. A. Milner , A. Korobenko , K. Rezaiezadeh , V. Milner

Half-cycle laser pulse is applied on an absorbed molecule to investigate its alignment and orientation behavior. Crossover from field-free to hindered rotation motion is observed by varying the angel of hindrance of potential well. At small…

原子物理 · 物理学 2007-05-23 Y. Y. Liao , Y. N. Chen , D. S. Chuu

A molecule can be optically accelerated to rotate unidirectionally at a frequency of a few terahertzes which is many orders higher than the classical mechanical rotor. Such a photon-induced ultrafast molecular unidirectional rotation has…

Chirality and chiral molecules are key elements in modern chemical and biochemical industries. Individual addressing, and the eventual separation of chiral enantiomers has been and still is an important elusive task in molecular physics and…

The generation of chiral laser emission offers promising opportunities for modern photonic applications and the study of chiral light-mater interactions. Despite the great process made in recent years, the direct generation of chiral lasers…

光学 · 物理学 2020-08-19 Hamim Rivy , Yu-Cheng Chen