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High-pressure polyhydrides are leading contenders for room temperature superconductivity. The next frontier lies in stabilizing them at ambient pressure, which would allow their practical applications. In this first-principles computational…

超导电性 · 物理学 2026-05-18 Đorđe Dangić , Manex Alkorta , Yuewen Fang , Ion Errea

Hydrogen and hydrides materials have long been considered promising materials for high-temperature superconductivity. But the extreme pressures required for the metallization of hydrogen-based superconductors limit their applications. Here,…

超导电性 · 物理学 2024-07-08 Mingyang Du , Hongyu Huang , Zihan Zhang , Min Wang , Hao Song , Defang Duan , Tian Cui

Following the idea that hydrogen-rich compounds might be high-T$_c$ superconductors at high pressures, and the very recent breakthrough in predicting and synthesizing hydrogen sulfide with record-high T$_c$ = 203 K, ab initio evolutionary…

超导电性 · 物理学 2017-04-19 M. M. Davari Esfahani , A. R. Oganov , H. Niu , J. Zhang

Inspired by recent predictions of superconductivity in B-C framework clathrates, we employ density functional theory to explore potential superconductors among hexagonal hydride-substituted compounds with compositions XB$_8$C, XB$_7$C$_2$,…

超导电性 · 物理学 2025-03-11 Bin Li , Yuxiang Fan , Chuanhui Yin , Junjie Zhai , Cong Zhu , Zhisi Cao , Jie Cheng , Shengli Liu

The pursuit of room-temperature superconductors has recently advanced with the discovery of high-temperature superconductivity in compressed hydrides, although sustaining the superconductivity of hydrides at ambient pressure remains…

超导电性 · 物理学 2025-01-28 Ying Sun , Li Zhu

Lanthanum, yttrium, and cerium hydrides are the three most well-known superconducting binary hydrides (La-H, Y-H, and Ce-H systems), which have gained great attention in both theoretical and experimental studies. Recent studies have shown…

超导电性 · 物理学 2022-11-15 Peng Song , Zhufeng Hou , Kousuke Nakano , Kenta Hongo , Ryo Maezono

The low-pressure stabilization of superconducting hydrides with high critical temperatures ($T_c$s) remains a significant challenge, and experimentally verified superconducting hydrides are generally constrained to a limited number of…

A key challenge in materials discovery is to find high-temperature superconductors. Hydrogen and hydride materials have long been considered promising materials displaying conventional phonon-mediated superconductivity. However, the high…

The current search for room-temperature superconductivity is inspired by the unique properties of the electron-phonon interaction in metal superhydrides. Encouraged by the recently found highest-$T_C$ superconductor fcc-$LaH_{10}$, here we…

The discovery of superconductivity at 203 K in H3S brought attention back to conventional superconductors whose properties can be described by the Bardeen-Cooper-Schrieffer (BCS) and the Migdal-Eliashberg theories. These theories predict…

The uniquely characteristic macrostructures of binary hydrogen-clathrate compounds $M$H$_\textrm{n}$ formed at high pressure, a cage of hydrogens surrounding a central-atom host, is theoretically predicted in various studies to include…

超导电性 · 物理学 2020-06-22 Dale R. Harshman , Anthony T. Fiory

The prediction of superconductivity above 200 K in CaH$_6$ revolutionized research on hydrogen-rich superconductors, and subsequent experiments have verified this prediction, while unidentified peaks in XRD and the decrease in…

超导电性 · 物理学 2026-03-10 Wenbo Zhao , Zefang Wang , Ying Sun , Hefei Li , Hanyu Liu , Yu Xie

We predicted a new ternary hydride Li$_2$SiH$_6$ at high pressures. A systematic structure search in Li$_2$SiH$_6$ compound reveals novel stable phases with intriguing electronic and phonon properties. It is found that Li$_2$SiH$_6$ is…

材料科学 · 物理学 2022-09-13 Sixuan Wu , Bin Li , Zhi Chen , Yu Hou , Yan Bai , Xiaofeng Hao , Yeqian Yang , Shengli Liu , Jie Cheng , Zhixiang Shi

Noble metals adopt close-packed structures at ambient pressure and rarely undergo structural transformation at high pressures. Platinum (Pt), in particular, is normally considered to be unreactive and is therefore not expected to form…

超导电性 · 物理学 2015-03-19 Duck Young Kim , Ralph H. Scheicher , Chris J. Pickard , R. J. Needs , R. Ahuja

Polyhydrides offer intriguing perspectives as high-temperature superconductors. Here we report the high-pressure synthesis of a series of lanthanum-yttrium ternary hydrides: cubic hexahydride $(La,Y)H_{6}$ with a critical temperature…

In this work, global search for crystal structures of ternary Mg-Sc-H hydrides (Mg$_x$Sc$_y$H$_z$) under high pressure ($100 \le P \le 200$ GPa) were performed using the evolutionary algorithm and first-principles calculations. Based on…

Achieving superconductivity at room temperature (RT) is a holy grail in physics. Recent discoveries on high-Tc superconductivity in binary hydrides H3S and LaH10 at high pressure have directed the search for RT superconductors to compress…

超导电性 · 物理学 2024-07-30 Qiwen Jiang , Defang Duan , Hao Song , Zihan Zhang , Zihao Huo , Shuqing Jiang , Tian Cui , Yansun Yao

Compressed hydrogen-rich compounds have received extensive attention as appealing contenders for superconductors, and further challenges are maintaining the stability and superconductivity of hydrides at lower pressures. In this work, we…

超导电性 · 物理学 2023-02-22 Wendi Zhao , Defang Duan , Hao Song , Mingyang Du , Qiwen Jiang , Tiancheng Ma , Ming Xu , Tian Cui

Evolutionary structure searches are used to predict a new class of compounds in the lithium--rich region of the lithium/hydrogen phase diagram under pressure. First principles computations show that LimH, 4<m<9, are stabilized with respect…

材料科学 · 物理学 2012-11-09 James Hooper , Eva Zurek

Motivated by recent discovery of yttrium-based high-temperature ternary superconducting hydrides (e.g., CaYH$_{12}$, LaYH$_{12}$, and ScYH$_{6}$), we have employed evolutionary algorithm and first-principles calculations to comprehensively…