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Graphene flakes were produced by nanosecond plasma discharge at atmospheric pressure between an electrode and the surface of distilled water, in which were placed graphite flakes. The discharge ionizes the gas and forms free radicals on the…

Liquid-phase exfoliation, the use of a sheared liquid to delaminate graphite into few-layer graphene, is a promising technique for the large-scale production of graphene. But the micro and nanoscale fluid-structure processes controlling the…

软凝聚态物质 · 物理学 2020-04-22 Simon Gravelle , Catherine Kamal , Lorenzo Botto

Plasma functionalization of graphene is one of the facile ways to tune its doping level without the need for wet chemicals making graphene photoluminescent. Microscopic corrugations in the two-dimensional structure of bilayer CVD graphene…

Graphene stands as a promising material with vast potential across energy storage, electronics, etc. Here, we present a novel mechanical approach utilizing ultrasonic high-energy intercalation exfoliation to extract monolayer graphene from…

材料科学 · 物理学 2025-01-15 Kaitong Sun , Si Wu , Junchao Xia , Yinghao Zhu , Guanping Xu , Hai-Feng Li

We present a fabrication method producing large and flat graphene flakes that have a few layers down to a single layer based on substrate bonding of a thick sample of highly oriented pyrolytic graphite (HOPG), followed by its controlled…

介观与纳米尺度物理 · 物理学 2012-07-03 Vincent Huc , Nedjma Bendiab , Noel Rosman , Thomas Ebbesen , Cecile Delacour , Vincent Bouchiat

Graphene is at the centre of nanotechnology research. In order to fully exploit its outstanding properties, a mass production method is necessary. Two main routes are possible: large-scale growth or large-scale exfoliation. Here, we…

The removal of single atomic layers from multi-layer graphene using a He plasma is reported. By applying sample biases of -60 and +60 V during He plasma exposure, layer removal is found to be due to electrons instead of He ions or neutrals…

材料科学 · 物理学 2012-02-17 Jason D. Jones , Rakesh K. Shah , Guido F. Verbeck , Jose M. Perez

High surface area graphene sheets were obtained by electrochemical exfoliation of graphite in an acid media under constant potential conditions. Filtration and centrifugation processes played an important role in order to obtain stable…

材料科学 · 物理学 2016-06-22 M. Hurtado-Morales , M. Ortiz , C. Acuna , H. C. Nerl , V. Nicolosi , Y. Hernandez

Highly oriented pyrolytic graphite (HOPG) was scribed by pulsed laser beam to produce square patterns. Patterning of HOPG surface facilitates the detachment of graphene layers during contact printing. Direct HOPG-to-substrate and…

材料科学 · 物理学 2015-06-12 Jelena Butikova , Boris Polyakov , Lauris Dimitrocenko , Edgars Butanovs , Ivars Tale

We show that strong photoluminescence (PL) can be induced in single-layer graphene on using an oxygen plasma treatment. PL characteristics are spatially uniform across the flakes and connected to elastic scattering spectra distinctly…

其他凝聚态物理 · 物理学 2010-01-07 T. Gokus , R. R. Nair , A. Bonetti , M. Bohmler , A. Lombardo , K. S. Novoselov , A. K. Geim , A. C. Ferrari , A. Hartschuh

Synthesis of graphene with reduced use of chemical reagents is essential for manufacturing scale-up and to control its structure and properties. In this paper, we report on a novel chemical-free mechanism of graphene exfoliation from…

Graphene on a SiO$_2$/Si substrate was removed by ultraviolet pulsed laser irradiation. Threshold laser power density to remove graphene depended on the graphene thickness. The mechanism is discussed using kinetic energy of thermal…

应用物理 · 物理学 2018-12-27 Fujio Wakaya , Tadashi Kurihara , Nariaki Yurugi , Satoshi Abo , Masayuki Abe , Mikio Takai

Liquid-phase exfoliation is one of the most promising routes for large scale production of multilayer graphene dispersions. These dispersions, which may be used in coatings, composites or paints, are believed to contain disorder-free…

介观与纳米尺度物理 · 物理学 2014-09-05 M. V. Bracamonte , G. I. Lacconi , S. Urreta , L. E. F. Foa Torres

We present a high scale method to produce few layer graphene (FLG) based on the mechanical exfoliation of graphite and compare the obtained FLG with the one reported earlier arising from pencil lead ablation. Several things are modified and…

A simple and effective stepwise-method has been developed to remove defects from the top graphene layers of highly orientated pyrolytic graphite. Using a combination of ozone exposure and moderately high temperature we have shown that a…

材料科学 · 物理学 2011-04-01 M. J. Webb , P. Palmgren , P. Pal , O. Karis , H. Grennberg

We use molecular dynamics simulation to study the exfoliation of graphene and fluorographene in molecular and ionic liquids, by performing computer experiments in which one layer of the 2D nanomaterial is peeled from a stack, in vacuum and…

介观与纳米尺度物理 · 物理学 2018-02-07 Emilie Bordes , Joanna Szala-Bilnik , Agílio A. H. Pádua

Graphene as a single-atomic-layer material is fully exposed to environment and has therefore a great potential for creating of sensitive gas sensors. However, in order to realize this potential for different polluting gases, graphene has to…

We investigated the influence of thickness reduction on the transport properties of graphite microflakes. Using oxygen plasma etching we decreased the thickness of highly oriented pyrolytic graphite (HOPG) microflakes from $\sim 100$~nm to…

Catalytic hydrogenation of graphite has recently attracted renewed attention, as a route for nano-patterning of graphene and to produce graphene nano-ribbons. These reports show that metallic nanoparticles etch surface layers of graphite,…

介观与纳米尺度物理 · 物理学 2015-06-05 Maya Lukas , Velimir Meded , Aravind Vijayaraghavan , Li Song , Pulickel M. Ajayan , Karin Fink , Wolfgang Wenzel , Ralph Krupke

Metal surface cleaning or etching techniques using reactive plasma are emerging as one of the dry processing techniques for surface contaminants with high bond energy, especially for cleaning and decontamination of nuclear components and…

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