相关论文: Laboratory-based sticking coefficients for ices on…
The desorption characteristics of molecules on interstellar dust grains are important for modelling the behaviour of molecules in icy mantles and, critically, in describing the solid-gas interface. In this study, a series of laboratory…
Up to 90% of the chemical reactions during star formation occurs on ice surfaces, probably including the formation of complex organics. Only the most abundant ice species are however observed directly by infrared spectroscopy. This study…
Diffusion of species in icy dust grain mantles is a fundamental process that shapes the chemistry of interstellar regions; yet measurements of diffusion in interstellar ice analogs are scarce. Here we present measurements of CO diffusion…
Millimeter and centimeter observations are discovering an increasing number of interstellar complex organic molecules (iCOMs) in a large variety of star forming sites, from the earliest stages of star formation to protoplanetary disks and…
In protoplanetary disks, the distribution and abundance of small (sub)micron grains are important for a range of physical and chemical processes. For example, they dominate the optical depth at short wavelengths and their surfaces are the…
Interstellar grain mantles present in dense interstellar clouds are in constant exchange with the gas phase via accretion and desorption mechanisms such as UV, X-ray photodesorption, cosmic ray induced sputtering, grain thermal…
The mobility of atoms, molecules and radicals in icy grain mantles regulate ice restructuring, desorption, and chemistry in astrophysical environments. Interstellar ices are dominated by H2O, and diffusion on external and internal (pore)…
Gaseous H2O has been detected in several cold astrophysical environments, where the observed abundances cannot be explained by thermal desorption of H2O ice or by H2O gas phase formation. These observations hence suggest an efficient…
Aims. We attempt to understand the presence of gas phase CO below its freezing temperature in circumstellar disks. We study two promising mechanisms to explain this phenomenon: turbulent mixing and photodesorption. Methods. We compute the…
We investigate the evolution of the ortho-to-para ratio of overall (gas + ice) H$_2$ via the nuclear spin conversion on grain surfaces coated with water ice under physical conditions that are relevant to star- and planet-forming regions. We…
We show that the growth rate of dust grains in cold molecular clouds is enhanced by the high degree of compressibility of a turbulent, dilute gas. By means of high resolution (10243) numerical simulations, we confirm the theory that the…
We combine the latest observationally motivated constraints on stellar properties in dark matter haloes, along with data-driven predictions for the atomic (HI) and molecular (H$_2$) gas evolution in galaxies, to derive empirical…
Aims: The production of molecular hydrogen and its deuterated forms onto carbonaceous dust grains is investigated in detail. The goal of this study is to estimate the importance of the chemistry occuring on grain surfaces for the…
Observations of protoplanetary disks suggest that the gas and dust follow significantly different radial distributions. This finding can be theoretically explained by a combination of radial drift and gas drag of intermediate-sized dust…
Cosmic-ray-induced sputtering is one of the important desorption mechanisms at work in astrophysical environments. The chemical evolution observed in high-density regions, from dense clouds to protoplanetary disks, and the release of…
Context. Interstellar dust particles, which represent 1% of the total mass, are recognized to be very powerful interstellar catalysts in star-forming regions. The presence of dust can have a strong impact on the chemical composition of…
Stars form within molecular clouds, so characterizing the physical states of molecular clouds is key in understanding the process of star formation. Cloud structure and stability is frequently assessed using metrics including the virial…
The C/O ratio is a defining feature of both gas giant atmospheric and protoplanetary disk chemistry. In disks, the C/O ratio is regulated by the presence of snowlines of major volatiles at different distances from the central star. We…
Non-thermal desorption of ices on interstellar grains is required to explain observations of molecules that are not synthesized efficiently in the gas phase in cold dense clouds. Perhaps the most important non-thermal desorption mechanism…
The gas-to-dust mass ratios found for interstellar dust within the Solar System, versus values determined astronomically for the cloud around the Solar System, suggest that large and small interstellar grains have separate histories, and…