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We have observed reversible light-induced mechanical switching for a single organic molecule bound to a metal surface. Scanning tunneling microscopy (STM) was used to image the features of an individual azobenzene molecule on Au(111) before…

Controlling the activity of proteins with azobenzene photoswitches is a potent tool for manipulating their biological function. With the help of light, one can change e.g. binding affinities, control allostery or temper with complex…

化学物理 · 物理学 2021-09-24 Olga Bozovic , Brankica Jankovic , Peter Hamm

Photoswitchable organic molecules can undergo reversible structural changes with an external light stimulus. These optically controlled molecules have been used in the development of smart polymers, optical writing of grating films, and…

The persistent motility of the individual constituents in microbial suspensions represents a prime example of so-called active matter systems. Cells consume energy, exert forces and move, overall releasing the constraints of equilibrium…

生物物理 · 物理学 2020-11-02 Armand Javadi , Jorge Arrieta , Idan Tuval , Marco Polin

Strongly differing static dipole moments of the trans and cis isomers of photochromic azobenzene allow for optical switching the work function of azobenzene-functionalized self-assembled monolayers (SAMs). We apply these properties in a…

介观与纳米尺度物理 · 物理学 2024-02-26 Jan Böhnke , Beatrice Andres , Larissa Boie , Angela Richter , Cornelius Gahl , Martin Weinelt , Wibke Bronsch

By first principles calculations, we demonstrate that when decorated with photochromic molecules, it is possible to use light to reversibly control the magnetic properties of a nanoscale magnetic system. The combination of a graphene-based…

介观与纳米尺度物理 · 物理学 2013-11-26 Argo Nurbawono , Chun Zhang

Living systems are capable of locomotion, reconfiguration, and replication. To perform these tasks, cells spatiotemporally coordinate the interactions of force-generating, "active" molecules that create and manipulate non-equilibrium…

软凝聚态物质 · 物理学 2019-08-28 Tyler D. Ross , Heun Jin Lee , Zijie Qu , Rachel A. Banks , Rob Phillips , Matt Thomson

The next frontier in photonics will rely on the synergistic combination of disparate material systems. One unique organic molecule is azobenzene. This molecule can reversibly change conformations when optically excited in the blue…

Substrate engineering for steering cell growth is a wide and well-established area of research in the field of modern biotechnology. Here we introduce a micromachining technique to pattern an inert, transparent polymer matrix blended with a…

Photoactive liquid crystal elastomers are polymer networks of liquid crystal mesogens embedded with chromophores like azobenzene. They undergo large deformation when illuminated by light of a certain wavelength through photochemical…

软凝聚态物质 · 物理学 2022-01-10 Zhengxuan Wei , Ruobing Bai

Biophotonic techniques are growing in rapid rhythms enabling the monitoring of subcellular structures and non-invasive theranostic interventions in cancer and autoimmune diseases. The integration of Biophotonics with nanotechnology and…

医学物理 · 物理学 2021-06-15 Ellas Spyratou

In a joint theoretical and experimental work the optical properties of azobenzene-functionalized self-assembled monolayers (SAMs) are studied at different molecular packing densities. Our results, based on density-functional and many-body…

材料科学 · 物理学 2016-12-19 Caterina Cocchi , Thomas Moldt , Cornelius Gahl , Martin Weinelt , Claudia Draxl

Photoresponsive materials feature properties that can be adjusted near- instantaneously, reversibly, and with high spatiotemporal precision, by light. There is considerable interest in maximising the degree of switching, and in measuring…

Microorganismal motility is often characterised by complex responses to environmental physico-chemical stimuli. Although the biological basis of these responses is often not well understood, their exploitation already promises novel avenues…

生物物理 · 物理学 2019-11-26 Jorge Arrieta , Marco Polin , Ramón Saleta-Piersanti , Idan Tuval

The soft character of organic materials leads to strong coupling between molecular nuclear and electronic dynamics. This coupling opens the way to control charge transport in organic electronic devices by inducing molecular vibrational…

The emergent photoactive materials through photochemistry make it possible to directly convert photon energy to mechanical work. There is much recent work in developing appropriate materials and a promising new system is semi-crystalline…

软凝聚态物质 · 物理学 2021-03-24 Ruobing Bai , Eric Ocegueda , Kaushik Bhattacharya

Recently, "photovoltaic photographs" were proposed as a creative application of photovoltaic technologies, relevant in fields such as architecture or the automotive industry. In this application an image is created by light-induced…

Interfacing artificial functional materials and living neuronal tissues is at the forefront of bio-nano-technology. Attempts have been so far based onto microscale processing of metals and inorganic semiconductors as electrodes or…

Recent studies of AzoTAB activity in excitable cell cultures have shown that this substance is able to control excitability depending on isomer, cis or trans, predominating in the cellular membrane. Control of isomerization can be performed…

化学物理 · 物理学 2014-01-03 D. Shcherbakov , K. Motovilov , I. Erofeev , A. Astafiev

Photomechanically active materials undergo reversible deformation on illumination, making them ideal for remote, tether-free actuation. Much of the work on these materials has focused on one-dimensional structures, such as strips. In this…

材料科学 · 物理学 2024-10-28 Sathvik Sanagala , Kaushik Bhattacharya
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