相关论文: An atomistic description of alloys and core shells…
Absorption efficiency profiles and localized surface plasmon resonance (LSPR) wavelengths are reported for metallic core-shell nanoparticles (NPs) placed over a BK7 glass substrate. A numerical study is performed with the vectorized version…
Being able to predict and tune the colloidal stability of nanoparticles is essential for a wide range of applications, yet our ability to do so is currently poor due to a lack of understanding of how they interact with one another. Here, we…
The surface plasmon oscillations spectra in noble metal nanoparticles - rods and spheroids embedded in a host matrix is analyzed theoretically. The important role of - electrons in formation of surface plasmon resonances is shown. A simple…
Deciphering the three-dimensional atomic structure of solid-solid interfaces in core-shell nanomaterials is the key to understand their remarkable catalytical, optical and electronic properties. Here, we probe the three-dimensional atomic…
We study the linewidth of the surface plasmon resonance in the optical absorption spectrum of metallic nanoparticles, when the decay into electron-hole pairs is the dominant channel. Within a semiclassical approach, we find that the…
Noble metal nanoparticles have been utilized for a vast amount of optical applications. For the applications that used metal nanoparticles as nanosensors and optical labeling, larger radiation damping is preferred (higher optical signal).…
We develop a theoretical framework, based on a multipole, quasi-static approach, for the prediction of the localized surface plasmon resonances in Fanoshells formed via geometrical symmetry-breaking in multilayer nanoshells consisting of a…
Regular arrays of metal nanoparticles on metal films have tuneable optical resonances that can be applied for surface enhanced Raman scattering or biosensing. With the aim of developing more surface selective geometries we investigate…
Surface plasmons in a centrosymmetric metal nanocrystal have been perceived as achiral, based on the quantum-mechanical theory of molecular optical activity. The one-electron theory is insufficient to describe optical activity in crystals,…
In this paper, we investigate the hybridization theory of plasmon resonance in metallic nanostructures, which has been validated by the authors in [31] through a series of experiments. In an electrostatic field, we establish a mathematical…
The influence of morphology on the optical properties of silver nanoparticles is studied. A general relationship between the surface plasmon resonances and the morphology of each nanoparticle is established. The optical response is…
The electronic structure and optical properties of metallic nanoshells are investigated using a jellium model and the Time Dependent Local Density Approximation (TDLDA). An efficient numerical implementation enables applications to…
Linear clusters made by tightly connecting two or more metallic nanoparticles have new types of surface plasmon resonances as compared to isolated nanoparticles. These new resonances are related to the size of the junction and to the number…
We present an analytic theory for the optical properties of ellipsoidal plasmonic particles covered by anisotropic molecular layers. The theory is applied to the case of a prolate spheroid covered by chromophores oriented parallel and…
Understanding and mastering the mechanical properties of metallic nanoparticles is crucial for their use in a wide range of applications. In this context, we use atomic-scale (Molecular Dynamics) and continuous (Finite Elements)…
Core-shell nanowires made of Si and Ge can be grown experimentally with excellent control for different sizes of both core and shell. We have studied the structural properties of Si/Ge and Ge/Si core-shell nanowires aligned along the…
Nanoparticles supporting a distinct series of Mie resonances have enabled a new class of nanoantennas and provide efficient ways to manipulate light at the nanoscale. The ability to flexibly tune the optical resonances and scattering…
While nanoalloys are of paramount scientific and practical interests, the main processes leading to their formation are still poorly understood. Key structural features in the alloy systems, including crystal phase, chemical ordering, and…
Multipolar plasmon oscillation frequencies and corresponding damping rates for nanospheres formed of the simplest free-electron metals are studied. The possibility of controlling plasmon features by choosing the size and dielectric…
We study the effect of Coulomb correlations on the ultrafast optical dynamics of small metal particles. We demonstrate that a surface-induced dynamical screening of the electron-electron interactions leads to quasiparticle scattering with…