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From a structural point of view, plasmonic nanoparticles are always at least two-layer structures with a dielectric layer of stabilizing, targeting, fluorescent, Raman, or other functional molecules. To optimize the optical properties of…

光学 · 物理学 2025-05-13 Nikolai G. Khlebtsov , Sergey V. Zarkov

We study the role of collective surface excitations in the electron relaxation in small metal particles. We show that the dynamically screened electron-electron interaction in a nanoparticle contains a size-dependent correction induced by…

凝聚态物理 · 物理学 2009-10-31 T. V. Shahbazyan , I. E. Perakis

Advances in the ability to manipulate free electron phase profiles within the electron microscope have spurred development of quantum-mechanical descriptions of electron energy loss (EEL) processes involving transitions between phase-shaped…

介观与纳米尺度物理 · 物理学 2024-02-09 Marc R. Bourgeois , Austin G. Nixon , Matthieu Chalifour , David J. Masiello

We present analytical expressions for the resonance frequencies of the plasmonic modes hosted in a cylindrical nanoparticle within the quasistatic approximation. Our theoretical model gives us access to both the longitudinally and…

介观与纳米尺度物理 · 物理学 2021-01-29 Charles A. Downing , Guillaume Weick

Optical plasmon-polariton modes confined in both transverse dimensions to significantly less than a wavelength are exhibited in open waveguides structured as sharp metal wedges. The analysis reveals two distinctive modes corresponding to a…

光学 · 物理学 2009-11-11 Eyal Feigenbaum , Meir Orenstein

Electromagnetic hot-spots at ultra-narrow plasmonic nanogaps carry immense potential to drive detection limits down to few molecules in sensors based on surface enhanced Raman or Fluorescence spectroscopies. However, leveraging the EM…

Plasmonic nanocavities are a promising platform for strong light-matter coupling and enhanced spectroscopies at the single-molecule level. These nanoscale environments are challenging to model due to their strongly multimodal character and…

化学物理 · 物理学 2026-03-16 Jonathan H. Fetherolf , Tao E. Li , Sharon Hammes-Schiffer

Nanoscale localization of electromagnetic fields near metallic nanostructures underpins the fundamentals and applications of plasmonics. The unavoidable energy loss from plasmon decay, initially seen as a detriment, has now expanded the…

We present a semi-analytical point-dipole method that uses Ewald lattice summation to find the dispersion relation of guided plasmonic and bianisotropic modes in metasurfaces composed of 2D periodic lattices of arbitrarily strongly…

光学 · 物理学 2015-06-23 Per Lunnemann , A. Femius Koenderink

We study the blueshift of the surface plasmon (SP) resonance energy of isolated Ag nanoparticles with decreasing particle diameter, which we recently measured using electron energy loss spectroscopy (EELS). As the particle diameter…

光学 · 物理学 2013-11-05 Søren Raza , Wei Yan , Nicolas Stenger , Martijn Wubs , N. Asger Mortensen

Optical polaritons appear when a material excitation strongly couples to the optical mode. Such strong coupling between molecular transitions and optical cavities results in far-reaching opportunities in modifying fundamental properties of…

光学 · 物理学 2022-07-14 Artyom Assadillayev , Ihar Faniayeu , Alexandre Dmitriev , Søren Raza

Based on first-principles calculations, we systematically study the electronic, dielectric, and plasmonic properties of two-dimensional (2D) electride materials X$_2$N (X=Ca, Sr). We show that both Ca$_2$N and Sr$_2$N are stable down to…

材料科学 · 物理学 2015-09-22 Shan Guan , Shengyuan A. Yang , Liyan Zhu , Junping Hu , Yu-Gui Yao

Damping rates of multipolar, localized surface plasmons (SP) of gold and silver nanospheres of radii up to $1000nm$ were found with the tools of classical electrodynamics. The significant increase in damping rates followed by noteworthy…

光学 · 物理学 2012-11-21 Krystyna Kolwas , Anastasiya Derkachova

The electronic properties of heterojunction electron gases formed in GaN/AlGaN core/shell nanowires with hexagonal and triangular cross-sections are studied theoretically. We show that at nanoscale dimensions, the non-polar hexagonal system…

材料科学 · 物理学 2015-05-28 Bryan M. Wong , François Léonard , Qiming Li , George T. Wang

Electron energy-loss spectroscopy (EELS) coupled with scanning transmission electron microscopy (STEM) is a powerful technique to determine materials composition and bonding with high spatial resolution. Noise is often a limitation…

仪器与探测器 · 物理学 2025-05-21 Yifan Wang , Mai Tan , Carlos Fernandez-Granda , Peter A. Crozier

We analyze the plasmonic modes of a metal nanoparticle circular array. Closed form solutions to the eigenmode problem are given. For each polarization, the plasmonic mode with the highest quality is found to be an antiphase mode. We found…

光学 · 物理学 2016-07-29 Kin Hung Fung , C. T. Chan

Chains of metallic nanoparticles sustain strongly confined surface plasmons with relatively low dielectric losses. To exploit these properties in applications,such as waveguides, the fabrication of long chains of low disorder and a thorough…

The plasmon coupling in a nanorod dimer obeys the exponential size dependence according to the Universal Plasmon Ruler Equation. However, it was shown recently that such a model does not hold at short nanorod distance (Nano Lett. 2009, 9,…

介观与纳米尺度物理 · 物理学 2010-12-17 Cheng-ping Huang , Xiao-gang Yin , Ling-bao Kong , Yong-yuan Zhu

We develop a theory of momentum-resolved electron energy-loss spectra in the scanning transmission microscope (STEM-EELS) that captures the effects of coupled phonon and magnon excitations within a unified formalism, and apply it to…

Thermodynamic properties of fluids confined in nanopores differ from those observed in the bulk. To investigate the effect of nanoconfinement on water compressibility, we performed water sorption experiments on two nanoporous glass samples…