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Using full-potential density functional theory (DFT) calculations, we found a small asymmetry in the Fermi velocity of electrons and holes in graphene. These Fermi velocity values and their average were found to decrease with increasing…

介观与纳米尺度物理 · 物理学 2013-02-08 Harihar Behera , Gautam Mukhopadhyay

Stochastic and mixed stochastic-deterministic density functional theory (DFT) are promising new approaches for the calculation of the equation-of-state and transport properties in materials under extreme conditions. In the intermediate warm…

计算物理 · 物理学 2023-09-27 Vidushi Sharma , Lee A. Collins , Alexander J. White

Subsystem Density-Functional Theory (DFT) is an emerging technique for calculating the electronic structure of complex molecular and condensed phase systems. In this topical review, we focus on some recent advances in this field related to…

化学物理 · 物理学 2015-06-24 Alisa Krishtal , Debalina Sinha , Alessandro Genova , Michele Pavanello

First principles methods can provide insight into materials that is otherwise impossible to acquire. Density Functional Theory (DFT) has been the first principles method of choice for numerous applications, but it falls short of predicting…

材料科学 · 物理学 2019-07-24 Arpita Paul , Turan Birol

According to the Hohenberg-Kohn theorem of density-functional theory (DFT), all observable quantities of systems of interacting electrons can be expressed as functionals of the ground-state density. This includes, in principle, the spin…

强关联电子 · 物理学 2019-09-04 Carsten A. Ullrich

Fluids in nanopores are of importance for many engineering applications, including energy storage in supercapacitors, hydrocarbons recovery from unconventional sources, or water desalination. Thermodynamic properties of fluids confined in…

化学物理 · 物理学 2026-02-25 Gennady Y. Gor , Geordy Jomon , Andrei L. Kolesnikov

Density functional theory (DFT) has become the most popular approach to electronic structure across disciplines, especially in material and chemical sciences. Last year, at least 30,000 papers used DFT to make useful predictions or give…

化学物理 · 物理学 2017-01-05 Justin C. Smith , Francisca Sagredo , Kieron Burke

Graphene-based materials (GBMs) constitute a large family of materials which has attracted great interest for potential applications. In this work, we apply first-principles calculations based on density functional theory (DFT) and fully…

材料科学 · 物理学 2021-05-05 Enesio Marinho , Pedro A. S. Autreto

Density functional theory (DFT) and thermal DFT (thDFT) calculations were used to evaluate the energy band structure, bandgap, and the total energy of various graphene quantum dots (GQDs). The DFT calculations were performed using local…

材料科学 · 物理学 2021-12-20 Majid Ghandchi , Ghafar Darvish , Mohammad Kazem Moravvej-Farshi

A density functional theory (DFT) of lattice fermion models is presented, which uses the single-particle density matrix gamma_{ij} as basic variable. A simple, explicit approximation to the interaction-energy functional W[gamma] of the…

强关联电子 · 物理学 2009-11-07 R. Lopez-Sandoval , G. M. Pastor

Density functional theory (DFT) is an incredible success story. The low computational cost, combined with useful (but not yet chemical) accuracy, has made DFT a standard technique in most branches of chemistry and materials science.…

化学物理 · 物理学 2015-06-03 Kieron Burke

Density functional theory (DFT), one of the most widely utilized methods available to computational chemistry, fails to describe systems with statically correlated electrons. To address this shortcoming, in previous work we transformed DFT…

化学物理 · 物理学 2023-01-02 Daniel Gibney , Jan-Niklas Boyn , David A. Mazziotti

We examine the nanoscale behavior of an equilibrium three-phase contact line in the presence of long-ranged intermolecular forces by employing a statistical mechanics of fluids approach, namely density functional theory (DFT) together with…

流体动力学 · 物理学 2014-08-05 Andreas Nold , David N. Sibley , Benjamin D. Goddard , Serafim Kalliadasis

Using dynamical density functional theory (DDFT), we theoretically study Brownian self-diffusion and structural relaxation of hard disks and compare to experimental results on quasi two-dimensional colloidal hard spheres. To this end, we…

软凝聚态物质 · 物理学 2018-04-04 Daniel Stopper , Alice Thorneywork , Roel Dullens , Roland Roth

We derive an exact representation of the exchange-correlation energy within density functional theory (DFT) which spawns a class of approximations leading to correct long-range asymptotic behavior. In what amounts to be the simplest…

材料科学 · 物理学 2009-11-10 Roi Baer , Daniel Neuhauser

We present a Density Functional Theory (DFT) study of the structural and electronic properties of bare rutile VO$_{2}$(110) surfaces and its oxygen-rich terminations. We discuss the performance of various DFT functionals, including PBE,…

材料科学 · 物理学 2021-08-31 Jakub Planer , Florian Mittendorfer , Josef Redinger

Density functional theory (DFT) embedding provides a formally exact framework for interfacing correlated wave-function theory (WFT) methods with lower-level descriptions of electronic structure. Here, we report techniques to improve the…

化学物理 · 物理学 2015-06-12 Jason D. Goodpaster , Taylor A. Barnes , Frederick R. Manby , Thomas F. Miller

Density functional theory (DFT) provides a theoretical framework for efficient and fairly accurate calculations of the electronic structure of molecules and crystals. The main features of density functional theory are described and DFT…

化学物理 · 物理学 2012-06-12 Hauke Paulsen , Alfred Xaver Trautwein

We analyze the density functional theory (DFT) description of weak interactions by employing diffusion and reptation quantum Monte Carlo (QMC) calculations, for a set of benzene-molecule complexes. While the binding energies depend…

材料科学 · 物理学 2015-05-14 Yosuke Kanai , Jeffrey C. Grossman

We present exemplary results of extensive studies of mechanical, electronic and transport properties of covalent functionalization of graphene monolayers (GML) with -NH2. We report new results of ab initio studies of covalent…

材料科学 · 物理学 2014-01-24 Karolina Z. Milowska , Jacek A. Majewski