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We demonstrate that an applied electric field causes piezoelectric distortion across single molecular monolayers of oligopeptides. We deposited self-assembled monolayers ~1.5 nm high onto smooth gold surfaces. These monolayers exhibit…

应用物理 · 物理学 2017-10-13 Xinfeng Quan , Jeffry D. Madura , Geoffrey R. Hutchison

We report here an original single-step process for synthesis and self-organization of gold colloids by simply incorporating gold salts into a solution prepared with Polystyrene (PS) - Polymethylmethacrylate (PMMA) copolymer, thiolated PS…

We present a method for density-functional modeling of metallic overlayers grown on metallic supports. It offers a tool to study nanostructures and combines the power of self-consistent pseudopotential calculations with the simplicity of a…

介观与纳米尺度物理 · 物理学 2009-11-10 E. Ogando , N. Zabala , E. V. Chulkov , M. J. Puska

In this feature article, we provide an overview of our research on statistical copolymers as a coating material for metal oxide nanoparticles and surfaces. These copolymers contain functional groups enabling non-covalent binding to oxide…

软凝聚态物质 · 物理学 2022-04-29 Jean-Francois Berret , Alain Graillot

The unique thinness of two-dimensional materials enables control over chemical phenomena at their surfaces by means of various gating techniques. For example, gating methods based on field-effect-transistor configurations have been…

材料科学 · 物理学 2021-06-10 Ryo Nouchi , Kei-ichiro Ikeda

Bio-conjugated nanomaterials play a promising role in the development of novel supramolecular structures, molecular machines, and biosensing devices. In this study, lipid-conjugated gold nanoparticles were synthesized and allowed to form a…

材料科学 · 物理学 2012-07-24 Subhasish Chatterjee , Markrete Krikorian , Harry D. Gafney , Bonnie Gersten

The ability to create micro/nano patterns of organic self-assembled monolayers on semiconductor surfaces is crucial for fundamental studies and applications in a number of emerging fields in nanoscience. Here, we demonstrate the patterning…

应用物理 · 物理学 2020-01-06 Tianhan Liu , Timothy Keiper , Xiaolei Wang , Guang Yang , Daniel Hallinan , Jianhua Zhao , Peng Xiong

In this article, the stability of a complex plasma monolayer levitating in the sheath of the poweredelectrode of an asymmetric capacitively coupled radio-frequency argon discharge is studied. Com-pared to earlier studies, a better…

等离子体物理 · 物理学 2022-02-09 Lénaïc Couëdel , V Nosenko

Amphiphilic phospholipids and nanoparticles functionalized with hydrophobic capping ligands have previously been extensively investigated for their capacity to self-assemble into Langmuir monolayers at the air/water interface. However,…

Water-metal interfaces are ubiquitous and play a key role in many chemical processes, from catalysis to corrosion. Whereas water adlayers on atomically flat transition metal surfaces have been investigated in depth, little is known about…

材料科学 · 物理学 2013-05-08 Davide Donadio , Luca M. Ghiringhelli , Luigi Delle Site

Freestanding graphene membranes were successfully functionalized with platinum nanoparticles (Pt NPs). High-resolution transmission electron microscopy revealed a homogeneous distribution of single-crystal Pt NPs that tend to exhibit a…

Polycrystalline boron-doped diamond (BDD) is widely used as a working electrode material in electrochemistry, and its properties, such as its stability, make it an appealing support material for nanostructures for electrocatalytic…

材料科学 · 物理学 2023-06-13 Shayantan Chaudhuri , Andrew J. Logsdail , Reinhard J. Maurer

2D van der Waals materials have rich and unique functional properties, but many are susceptible to corrosion under ambient conditions. Here we show that linear alkylamines are highly effective in protecting the optoelectronic properties of…

Hypothesis: Introducing charged terminal groups to polymers that graft nanoparticles enables Coulombic control over their assembly by tuning the pH and salinity of aqueous suspensions. Experiments: Gold nanoparticles (AuNPs) are grafted…

Crystallization from an amorphous atomic structure is usually seen as a spontaneous process in pursuit of a lower energy state, but for alloy systems it is often hard to elucidate because of the intrinsic structural and compositional…

材料科学 · 物理学 2020-04-10 Y. Huang , L. Xie , D. S. He , J. Q. He

Here we a present a density functional theory study of pentacene ultra-thin films on flat [(111)] and vicinal [(455)] Au surfaces. We have performed crystal and electronic structure calculations by using PBE and optB86b-vdW functionals and…

材料科学 · 物理学 2020-05-20 Ersen Mete , Mehmet Fatih Danisman

The picosecond thermal response of a normal octadecanethiol self-assembled monolayer on a gold surface was studied using pump-probe, broadband-infrared, background-suppressed and vibrational sum frequency generation spectroscopy. The…

材料科学 · 物理学 2014-05-27 Hiroki Fujiwara

For applications in nanomedicine, particles need to be functionalized to prevent protein corona formation and or aggregation. Most advanced strategies take advantage of functional polymers and assembly techniques. Nowadays there is an…

应用物理 · 物理学 2021-09-21 V. Baldim , A. Graillot , N. Bia , C. Loubat , J. -F. Berret

Organic paramagnetic and electroactive molecules are attracting interest as core components of molecular electronic and spintronic devices. Currently, further progress is hindered by the modest stability and reproducibility of the…

We demonstrate how self-assembled monolayers of aromatic molecules on copper substrates can be converted into high-quality single-layer graphene using low-energy electron irradiation and subsequent annealing. We characterize this…

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