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We study the crystallization of a colloidal model system in presence of secondary nanoparticles acting as impurities. Using confocal microscopy, we show that the nanoparticles segregate in the grain boundaries of the colloidal polycrystal.…

软凝聚态物质 · 物理学 2012-05-25 Neda Ghofraniha , Elisa Tamborini , Julian Oberdisse , Luca Cipelletti , Laurence Ramos

We describe an optical scattering study of grain boundary premelting in water ice. Ubiquitous long ranged attractive polarization forces act to suppress grain boundary melting whereas repulsive forces originating in screened Coulomb…

材料科学 · 物理学 2013-05-23 E. S. Thomson , Hendrik Hansen-Goos , L. A. Wilen , J. S. Wettlaufer

Achieving a combination of high mechanical strength and high electrical conductivity in low-weight Al alloys requires a full understanding of the relationships between nanoscaled features and physical properties. Grain boundary…

材料科学 · 物理学 2020-08-27 Xavier Sauvage , Fabien Cuvilly , Alan Russell , Kaveh Edalati

Complex concentrated alloys with intrinsic chemical heterogeneity are promising candidates for nuclear applications, where local chemical order can strongly influence defect evolution under irradiation. Grain boundaries also contribute to…

材料科学 · 物理学 2026-03-20 Ian Geiger , Penghui Cao , Timothy J. Rupert

The structure and evolution of grain boundaries underlies the nature of polycrystalline materials. Here we describe an experimental apparatus and light reflection technique for measuring disorder at grain boundaries in optically clear…

材料科学 · 物理学 2009-10-27 E. S. Thomson , J. S. Wettlaufer , L. A. Wilen

Segregation of impurities to grain boundaries plays an important role in both the stability and macroscopic behavior of polycrystalline materials. The research objective in this work is to better characterize the energetics and length…

材料科学 · 物理学 2013-09-02 N. R. Rhodes , M. A. Tschopp , K. N. Solanki

We demonstrate insights into the three-dimensional structure of defects in graphene, in particular grain boundaries, obtained via a new approach from two transmission electron microscopy images recorded at different angles. The structure is…

Hydrogen embrittlement of metals is widely observed, but its atomistic origins remain little understood and much debated. Combining a unique identification of interstitial sites through polyhedral tessellation and first-principles…

材料科学 · 物理学 2016-02-24 Xiao Zhou , Daniel Marchand , David L. McDowell , Ting Zhu , Jun Song

Understanding the composition evolution of grain boundaries and grain boundary precipitation at near-atomic scale in aluminum alloys is crucial to tailor mechanical properties and to increase resistance to corrosion and stress corrosion…

It is shown that mechanical alignment of grains can be efficient for grains rotating suprathermally, i.e. with kinetic energy substantially exceeding $k$ (the Boltzmann constant) over any temperature in the system. The paper studies…

天体物理学 · 物理学 2009-10-28 A. Lazarian

Intergranular attack of alloys under hydrothermal conditions is a complex problem that depends on metal and oxygen transport kinetics via solid-state and channel-like pathways to an advancing oxidation front. Experiments reveal very…

化学物理 · 物理学 2018-09-03 Zhijie Xu , Dongsheng Li , Daniel K. Schreiber , Kevin M. Rosso , Stephen M. Bruemmer

Segregated impurities at grain boundaries can dramatically change the mechanical behavior of metals, while the mechanism is still obscure in some cases. Here, we suggest an unified approach to investigate segregation and its effects on the…

材料科学 · 物理学 2017-12-20 Yunguo Li , Pavel Korzhavyi , Rolf Sandström , Christina Lilja

Faceted grain boundaries exhibit unusual segregation and migration tendencies. To gain a deeper understanding of how solute atoms interact with faceted interfacial structures during migration, this study probes the migration behavior of a…

材料科学 · 物理学 2020-11-20 Megan J. McCarthy , Timothy J. Rupert

Using the transport and magnetization measurements the influence of neutron irradiation at a fluence of 5x10$^{17}$ n cm$^{-2}$ on (B0.65C0.35)Ba1.4Sr0.6Ca2Cu3Oz has been investigated. The neutron irradiation was found to decrease critical…

超导电性 · 物理学 2015-06-25 V. Mihalache , A. Totovana , V. Sandu , S. Popa , G. Aldica , A. Iyo

Grain boundaries can exist as different grain boundary phases (also called complexions) with individual atomic structures. The thermodynamics of these defect phases in high-angle grain boundaries were studied mostly with atomistic and phase…

The effect of grain boundaries and wrinkles on the electrical properties of polycrystalline graphene is pronounced. Here we investigate the stitching between grains of polycrystalline graphene, specifically, overlapping of layers at the…

材料科学 · 物理学 2014-06-09 Rahul Rao , Neal Pierce , Avetik R. Harutyunyan

It is believed that grain boundary segregation of light interstitials can serve as possible mechanism of thermal stability in commercially pure nanostructured titanium alloys. In this paper, using first-principles calculations, we show that…

材料科学 · 物理学 2015-06-15 D. A. Aksyonov , A. G. Lipnitskii , Yu. R. Kolobov

Engineering structure of grain boundaries (GBs) by solute segregation is a promising strategy to tailor the properties of polycrystalline materials. Theoretically it has been suggested that solute segregation can trigger phase transitions…

材料科学 · 物理学 2025-01-28 Vivek Devulapalli , Enze Chen , Tobias Brink , Timofey Frolov , Christian H. Liebscher

The local variation of grain boundary atomic structure and chemistry caused by segregation of impurities influences the macroscopic properties of poylcrystalline materials. Here, the effect of co-segregation of carbon and boron on the…

In this work the coupled motion of two different phases of {\Sigma}5(210)[001] grain boundaries were investigated by molecular dynamics simulations of fcc Cu. The effect of interfacial structural phase transitions is shown to have a…

材料科学 · 物理学 2015-06-19 Timofey Frolov