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In this work we introduce an effective approach to quantize the electromagnetic response of plasmonic metallic nanostructures. Their shape is arbitrary and they feature a realistic description of the frequency-dependent metal dielectric…

化学物理 · 物理学 2025-12-17 Marco Romanelli , Gabriel Gil , Stefano Corni

We systematically investigated and quantified how gold (Au) metal nanoparticles (NPs) optical spectra change upon introduction into biological tissue phantoms environment, in which the AuNPs can agglomerate. Quantitative knowledge of how…

应用物理 · 物理学 2021-03-17 J. C. R. Araujo , A. F. G. Monte , R. L. Serrano , W. Iwamoto , A. Antunes , O. Brener , M. Foschini

Quantum plasmonics is a rapidly growing field of research that involves the study of the quantum properties of light and its interaction with matter at the nanoscale. Here, surface plasmons - electromagnetic excitations coupled to electron…

量子物理 · 物理学 2013-12-25 M. S. Tame , K. R. McEnery , S. K. Ozdemir , J. Lee , S. A. Maier , M. S. Kim

The challenging question on possible plasmon type excitations in finite ionic systems is discussed. The related theoretical model is formulated and developed in order to describe surface and volume plasmons of ion liquid in finite…

介观与纳米尺度物理 · 物理学 2014-11-20 Witold Jacak

The optical response of metallic nanoparticle arrays is dominated by localized surface plasmon excitations and is the sum of individual particle contributions modified by inter-particle coupling depending on specific array geometry. Here we…

This paper provides new insights concerning the simulation of plasmon driven chemical reactions using real-time TDDFT based on the tight-binding electronic structure code DFTB+, with applications to the dissociation of H$_2$ on octahedral…

化学物理 · 物理学 2023-03-21 Sajal Kumar Giri , George C. Schatz

Combining miniaturization and good operating speed is a compelling yet crucial task for our society. Plasmonic waveguides enable the possibility of carrying information at optical operating speed while maintaining the dimension of the…

介观与纳米尺度物理 · 物理学 2023-01-18 C. E. A. Cordaro , G. Piccitto , F. Priolo

Energetic electromagnetic fields produce a variety of elementary excitations in solids that can strongly modify their primary photoemission spectra. Such is the plasmon excitation or pumping mechanism which, although indirect, is very…

材料科学 · 物理学 2025-04-11 Branko Gumhalter

Historically, the field of plasmonics has been relying on the framework of classical electrodynamics, with the local-response approximation of material response being applied even when dealing with nanoscale metallic structures. However,…

Gold nanoclusters are grown by 1.8 MeV Au++ implantation in silica matrix and subsequent air annealing in the temperature range of 873K-1273K. Post-annealed samples show plasmon resonance in the optical region (~ 2.38-2.51 eV) for average…

材料科学 · 物理学 2007-05-23 S. Dhara , B. Sundaravel , T. R. Ravindran , K. G. M. Nair , B. K. Panigrahi , P. Magudapathy

A quantum mechanical approach and local response theory are applied to study plasmons propagating in nanometer-thin gold slabs sandwiched between different dielectrics. The metal slab supports two different kinds of modes, classified as…

Hot carriers produced from the decay of localized surface plasmons in metallic nanoparticles are intensely studied because of their optoelectronic, photovoltaic and photocatalytic applications. From a classical perspective, plasmons are…

介观与纳米尺度物理 · 物理学 2019-04-09 Lara Román Castellanos , Ortwin Hess , Johannes Lischner

The random-phase-approximation semiclassical scheme for description of plasmon excitations in large metallic nanospheres, with radius range 10-60 nm, is formulated in an all-analytical version. The spectrum of plasmons is determined…

介观与纳米尺度物理 · 物理学 2015-05-14 J. Jacak , J. Krasnyj , W. Jacak , R. Gonczarek , A. Chepok , L. Jacak

We report on the nanoparticle-size-dependent onset of quantum tunneling of electrons across the sub-nanometer gaps in three different sizes (30, 50, and 80 nm) of highly uniform gold nanosphere dimers. For precision plasmonics, the gap…

The change in refractive index around plasmonic nanoparticles upon binding to biomolecules is routinely used in localized surface plasmon resonance (LSPR) based biosensors and in bio-sensing platforms. In this study, the plasmon sensitivity…

化学物理 · 物理学 2019-06-05 Masoud Shabaninezhad , Guda Ramakrishna

Plasmon resonance in metals represents the collective oscillation of the free electron gas density and enables enhanced light-matter interactions in nanoscale dimensions. Traditionally, the classical Drude model describes the plasmonic…

We develop a theory for spontaneous decay of a quantum emitter (QE) situated near metal-dielectric structure supporting localized surface plasmons. If plasmon resonance is tuned close to the QE emission frequency, the emission is enhanced…

介观与纳米尺度物理 · 物理学 2022-10-19 Tigran V. Shahbazyan

Electron beam imaging is a common technique used for characterizing the morphology of plasmonic nanostructures. During the imaging process, the electron beam interacts with traces of organic material in the chamber and produces a well-know…

介观与纳米尺度物理 · 物理学 2013-11-13 Mingxia Song , Gérard Colas-des-Francs , Alexandre Bouhelier

Motivated by often contradictory literature reports on size dependence of surface energy of gold nanoparticles, we performed an atomistic study combining molecular dynamics and \textit{ab initio} calculations. We show that in the case of Au…

材料科学 · 物理学 2018-03-16 D. Holec , P. Dumitraschkewitz , F. D. Fischer , D. Vollath

Band structures of electrons in a periodic potential are well-known to host topologies that impact their behaviors at edges and interfaces. The concept however is more general than the single-electron setting. In this work, we consider…

介观与纳米尺度物理 · 物理学 2024-10-16 Luis Brey , H. A. Fertig