相关论文: Benzonitrile as a proxy for benzene in the cold IS…
A novel, to the best of our knowledge, ultralow-temperature luminescence thermometry strategy is proposed, based on a measurement of relative intensities of hyperfine components in the spectra of Ho$^{3+}$ ions doped into a crystal. A…
We study the thermodynamic stability at low temperatures of a series of alkali metal/zinc double-cation borohydrides, including LiZn(BH$_4$)$_3$, LiZn$_2$(BH$_4$)$_5$, NaZn(BH$_4$)$_3$, NaZn$_2$(BH$_4$)$_5$, KZn(BH$_4$)$_3$, and…
Detection of the Warm-Hot Intergalactic Medium (WHIM) using Sunyaev-Zeldovich effect (SZE) surveys is an intriguing possibility, and one that may allow observers to quantify the amount of "missing baryons" in the WHIM phase. We estimate the…
HCN is a key ingredient for synthesizing biomolecules such as nucleobases and amino acids. We calculate 42 reaction rate coefficients directly involved with or in competition with the production of HCN in the early Earth or Titan…
We present a direct comparison of a chemical/physical model to multitransitional observations of C18O and 13CO towards the Barnard 68 pre-stellar core. These observations provide a sensitive test for models of low UV field photodissociation…
We compute the power spectrum of the Cosmic Microwave Background temperature anisotropies generated by the Intergalactic Medium. To estimate the electron pressure along the line of sight and its contribution to the Sunyaev-Zeldovich…
We present the first identification in interstellar space of the propargyl radical (CH2CCH). This species was observed in the cold dark cloud TMC-1 using the Yebes 40m telescope. The six strongest hyperfine components of the 2,0,2-1,0,1…
Cosmological hydrodynamical simulations predict that a large fraction of all baryons reside within mildly non-linear structures with temperatures in the range $10^{5}-10^{7}$K. As the gas is highly ionized, it could be detected by the…
To better understand the chemistry involved during the combustion of components of diesel fuel, the structure of a laminar lean premixed methane flame doped with n-butylbenzene has been investigated. The inlet gases contained 7.1% (molar)…
The intermetallic compound, YRhAl, has been prepared and is found to be isomorphic with RRhAl (R=Pr, Nd, Gd, Ho and Tm) compounds crystallizing in the orthorhombic TiNiSi-type structure (Space group Pnma). Heat capacity and electrical…
In the study presented here, we model the gas phase chemistry induced by plasma discharge at low temperature (150 K) in the NASA Ames COSmIC Simulation Chamber (COSmIC) using a 1-dimensional multi-fluid plasma model named CO-PRISM (COSmIC…
We present in this paper the main structural features and enthalpy details for the energy profiles of the title reactions, both for the exothermic (forward) path to NH$_{3}$ formation and for the endothermic (reverse) reaction to…
In order to better understand the chemistry involved during the combustion of components of diesel fuel, the structure of a laminar lean premixed methane flame doped with indane has been investigated. The gases of this flame contains 7.1%…
We investigated the chemistry of nitrogen--containing species, principally isotopomers of CN, HCN, and HNC, in a sample of pre-protostellar cores. We used the IRAM 30 m telescope to measure the emission in rotational and hyperfine…
In molecular clouds at temperatures as low as 10 K, all species except hydrogen and helium should be locked in the heterogeneous ice on dust grain surfaces. Nevertheless, astronomical observations have detected over 150 different species in…
The study of cyclic hydrocarbons is of utmost relevance in current astrochemical research, as they are considered to be among the most significant reservoirs of carbon in the interstellar medium. However, while unsaturated cyclic…
The effects of temperature and humidity on the estimation of air pollution by benzene by using the piezoelectric crystal gas sensor were studied. Polyvinylchloride films were used as substrate for the immobilization of…
Context. "Snow lines", marking regions where abundant volatiles freeze out onto the surface of dust grains, play an important role for planet growth and bulk composition in protoplanetary disks. They can already be observed in the envelopes…
We have reviewed the chemistry and cooling behaviour of low-density (n<10^4 cm^-3) primordial gas and devised a cooling model wich involves 19 collisional and 9 radiative processes and is applicable for temperatures in the range (1 K < T <…
Deuterium fractionation is highly efficient during the early stages of star formation, particularly in starless and prestellar cores where temperatures are low (<10 K) and molecular freeze-out onto dust grains is significant. Methanol forms…