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Recently we reported a high precision optical frequency measurement of the (v,L):(0,2)->(8,3) vibrational overtone transition in trapped deuterated molecular hydrogen (HD+) ions at 10 mK temperature. Achieving a resolution of 0.85…

原子物理 · 物理学 2017-02-20 J. Biesheuvel , J. -Ph. Karr , L. Hilico , K. S. E. Eikema , W. Ubachs , J. C. J. Koelemeij

The fundamental ground tone vibration of H2, HD, and D2 is determined to an accuracy of 2 x 10^-4 cm^-1 from Doppler-free laser spectroscopy in the collisionless environment of a molecular beam. This rotationless vibrational splitting is…

Weak transitions in the (2,0) overtone band of the HD molecule at $\lambda = 1.38 \, \mu$m were measured in saturated absorption using the technique of noise-immune cavity-enhanced optical heterodyne molecular spectroscopy. Narrow…

原子物理 · 物理学 2018-04-18 F. M. J. Cozijn , P. Dupre , E. J. Salumbides , K. S. E. Eikema , W. Ubachs

We demonstrate a technique for frequency measurements of atomic transitions with a precision of 30 kHz. The frequency is measured using a ring-cavity resonator whose length is calibrated against a reference laser locked to the $D_2$ line of…

原子物理 · 物理学 2009-11-10 Ayan Banerjee , Dipankar Das , Vasant Natarajan

Accurate experimental values for the vibrational ground tone or fundamental vibrational energy splitting of H$_2$, HD, and D$_2$ are presented. Absolute accuracies of $2\times10^{-4}$ cm$^{-1}$ are obtained from Doppler-free laser…

Saturated absorption measurements of transitions in the (2-0) band of radioactive tritium hydride (HT) are performed with the ultra-sensitive NICE-OHMS intracavity absorption technique in the range 1460-1510 nm. The hyperfine structure of…

原子物理 · 物理学 2024-01-29 F. M. J. Cozijn , M. L. Diouf , W. Ubachs , V. Hermann , M. Schlösser

The ytterbium atom is widely used in the fields of atomic physics, cavity quantum electrodynamics, quantum information processing and optical frequency standards. There is however a strong dispersion among the reported values of the…

We report the measurement of absolute excitation frequencies of 87Rb to nS and nD Rydberg states. The Rydberg transition frequencies are obtained by observing electromagnetically induced transparency on a rubidium vapor cell. The accuracy…

The R(1), R(3) and P(3) ro-vibrational transitions in the (2-0) overtone band of the HD molecule are measured in Doppler-free saturation using the technique of NICE-OHMS spectroscopy. For the P(3) line, hitherto not observed in saturation,…

原子物理 · 物理学 2022-07-13 F. M. J. Cozijn , M. L. Diouf , V. Hermann , E. J. Salumbides , M. Schlösser , W. Ubachs

Precise molecular transition frequencies are of great interest in the test of fundamental physics and also in various applications. Two well isolated ro-vibrational transitions of $^{12}$C$^{16}$O at 1.57 $\mu$m, R(9) and R(10) in the…

原子物理 · 物理学 2017-10-11 Jin Wang , Yu R. Sun , Lei-Gang Tao , An-Wen Liu , Shui-Ming Hu

We report absolute optical frequencies of electronic transitions from the $X\, ^2\Pi_{3/2},v''=0,J''=3/2$ rovibronic ground state to the 12 lowest levels of the $A\, ^2\Sigma^+,v'=0$ vibronic state in $^{16}$OH, as well as to the 16 lowest…

原子物理 · 物理学 2018-12-05 Arthur Fast , John E. Furneaux , Samuel A. Meek

We demonstrate a technique for frequency measurements of UV transitions with sub-MHz precision. The frequency is measured using a ring-cavity resonator whose length is calibrated against a reference laser locked to the $D_2$ line of…

原子物理 · 物理学 2007-05-23 Ayan Banerjee , Umakant D. Rapol , Dipankar Das , Anusha Krishna , Vasant Natarajan

The fundamental vibrational interval of H$_{2}^+$ has been determined to be $\Delta G _{1/2} = 2191.126\,614(17)$ cm$^{-1}$ by continuous-wave laser spectroscopy of Stark manifolds of Rydberg states of H$_2$ with the H$_{2}^+$ ion core in…

原子物理 · 物理学 2024-01-18 Ioana Doran , Nicolas Hölsch , Maximilian Beyer , Frédéric Merkt

A saturation spectroscopy measurement of the P(1) line of the ($2-0$) band in HD is performed in a sensitive cavity-enhanced optical setup involving frequency comb calibration. The spectral signature is that of a Lamb-peak, in agreement…

原子物理 · 物理学 2020-05-08 M. L. Diouf , F. M. J. Cozijn , K. -F. Lai , E. J. Salumbides , W. Ubachs

The simplest molecules in nature, molecular hydrogen ions in the form of H2+ and HD+, provide an important benchmark system for tests of quantum electrodynamics in complex forms of matter. Here, we report on such a test based on a frequency…

原子物理 · 物理学 2016-02-03 J. Biesheuvel , J. -Ph. Karr , L. Hilico , K. S. E. Eikema , W. Ubachs , J. C. J. Koelemeij

Accurate $EF{}^1\Sigma^+_g-X{}^1\Sigma^+_g$ transition energies in molecular hydrogen were determined for transitions originating from levels with highly-excited vibrational quantum number, $v=11$, in the ground electronic state.…

原子物理 · 物理学 2016-09-23 T. Madhu Trivikram , M. L. Niu , P. Wcisło , W. Ubachs , E. J. Salumbides

The operation of a frequency comb at extreme ultraviolet (XUV) wavelengths based on pair-wise amplification and nonlinear upconversion to the 15th harmonic of pulses from a frequency comb laser in the near-infrared range is reported.…

We demonstrate a new technique for measuring the absolute frequencies of atomic transitions. The technique uses a ring-cavity resonator whose length is calibrated using a reference laser locked to the D_2 line in {87}Rb. The frequency of…

原子物理 · 物理学 2007-05-23 Ayan Banerjee , Dipankar Das , Vasant Natarajan

The rovibrational electric dipole transitions in the ground electronic state of the HD molecule are studied. A simple, yet rigorous formula is derived for the transition rates in terms of the electric dipole moment function $D(R)$, which is…

化学物理 · 物理学 2009-11-13 Krzysztof Pachucki , Jacek Komasa

We use optical-optical double-resonance (OODR) spectroscopy to measure for the first time hot-band transitions of ethylene (C${_2}$H${_4}$) between states in the 3000 cm$^{-1}$ and 9000 cm$^{-1}$ energy ranges. A 3.2 ${\mu}$m continuous…

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