相关论文: Sub-ppb measurement of a fundamental band rovibrat…
We measured the transition frequencies of the hyperfine components in the four lines (P(34) 39-0, R(36) 39-0, P(33) 39-0, and R(35) 39-0) of the B-X transitions of molecular iodine at 520.2 nm. The 520.2 nm laser was generated by…
Expectation values of the Breit operators and the $Q$ terms are calculated for HD$^+$ with the vibrational number $v=0-4$ and the total angular momentum $L=0-4$. Relativistic and radiative corrections to some ro-vibrational transition…
Precision spectroscopy of the hydrogen molecule is a test ground of quantum electrodynamics (QED), and may serve for determination of fundamental constants. Using a comb-locked cavity ring-down spectrometer, for the first time, we observed…
We present a combination of theoretical calculations and experiments for the low-lying vibrational excitations of H and D atoms adsorbed on the Pt(111) surface. The vibrational band states are calculated based on the full three-dimensional…
We present absolute frequency measurement of the unperturbed P7 P7 O$_2$ B-band transition with relative standard uncertainty of $2\times10^{-11}$. We reached the level of accuracy typical for Doppler-free techniques, with Doppler-limited…
A calculation of dynamic polarizabilities of rovibrational states with vibrational quantum number $v=0-7$ and rotational quantum number $J=0,1$ in the 1s$\sigma_g$ ground-state potential of HD$^+$ is presented. Polarizability contributions…
We describe a high-resolution spectroscopy method, in which the detection of single excitation events is enhanced by a complete loss of coherence of a superposition of two ground states. Thereby, transitions of a single isolated atom nearly…
Precision determination of the hyperfine splitting of cadmium ions is essential to study space-time variation of fundamental physical constants and isotope shifts. In this work, we present the precision frequency measurement of the…
The ground and excited vibrational states for the three hydrogen isotopes on the Pd(111) surface have been calculated. Notable features of these states are the high degree of anharmonicity, which is most prominently seen in the weak…
We report the measurement of sub-Doppler double-resonance transitions in methane using a 3.3 $\mu$m continuous wave optical parametric oscillator to pump transitions in the fundamental $\nu_3$ band and a 1.67 $\mu$m frequency comb to probe…
We report absolute frequency measurements of 81 hyperfine components of the rovibrational transitions of molecular iodine at 578 nm using the second harmonic generation of an 1156-nm external-cavity diode laser and a fiber-based optical…
The narrow transition from the lowest rovibrational level of the $\mathrm{X}^{1}\Sigma^{+}$ electronic ground state to the lowest vibrational level of the $\mathrm{b}^{3}\Pi_{0}$ potential provides opportunities for achieving…
This article reports the first optical frequency measurement of the $1\mathrm{S}-3\mathrm{S}$ transition in hydrogen. The excitation of this transition occurs at a wavelength of 205 nm which is obtained with two frequency doubling stages of…
Precision measurements are performed on highly excited vibrational quantum states of molecular hydrogen. The $v=12, J=0-3$ rovibrational levels of H$_2$ ($X^1\Sigma_g^+$), lying only $2000$ cm$^{-1}$ below the first dissociation limit, were…
The proton, deuteron and triton masses can be determined relative to the electron mass via rovibrational spectroscopy of molecular hydrogen ions. This has to occur via comparison of the experimentally measured transition frequencies and the…
Vibrational levels of the electronic ground states in dye molecules have not been previously explored at high resolution in solid matrices. We present new spectroscopic measurements on single polycyclic aromatic molecules of…
A novel mid-infrared/near-infrared double resonant absorption setup for studying infrared-inactive vibrational states is presented. A strong vibrational transition in the mid-infrared region is excited using an idler beam from a singly…
We use a diode laser locked to a Rb transition as the frequency reference along with a scanning Michelson interferometer to make precise measurements on the $D_1$ and $D_2$ lines of potassium. The Rb reference frequency is known with…
Molecular hydrogen is a benchmark system for bound state quantum calculation and tests of quantum electrodynamical effects. While spectroscopic measurements on the stable species have progressively improved over the years, high resolution…
We have completed measurements of two low-lying excited-state electric-dipole (E1) transition amplitudes in lead. Our measured reduced matrix elements of the $(6s^2 6p^2)^3P_1 \to (6s^2 6p7s)^3P_0$ transition at 368.3 nm and the 405.8 nm…