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Herein we employed high-resolution spectroscopic techniques in combination with periodic ab initio density functional theory (DFT) calculations to establish the different polarization processes for a porous copper-based MOF, termed HKUST-1.…

Metal-organic frameworks (MOFs) can provide exceptional porosity for molecular guest encapsulation useful for emergent applications in sensing, gas storage, drug delivery and optoelectronics. Central to the realisation of such applications…

软凝聚态物质 · 物理学 2021-01-05 Annika F. Möslein , Mario Gutiérrez , Boiko Cohen , Jin-Chong Tan

Improving interfacial thermal transport is crucial for heat dissipation in systems. Here, we design a strategy by utilizing the water adsorption-desorption process in porous metal-organic frameworks (MOFs) to tune the interfacial heat…

材料科学 · 物理学 2023-02-24 Guang Wang , Hongzhao Fan , Jiawang Li , Zhigang Li , Yanguang Zhou

In a world where capture and separation processes represent above 10% of global energy consumption, novel porous materials, such as Metal-Organic Frameworks (MOFs) used in adsorption-based processes are a promising alternative to dethrone…

材料科学 · 物理学 2022-10-20 Azahara Luna-Triguero , Eduardo Andres-Garcia , Pedro Leo , Willy Rook , Freek Kapteijn

Outstanding functional tunability underpinning metal-organic framework (MOF) confers a versatile platform to contrive next-generation chemical sensors, optoelectronics, energy harvesters and converters. We report a rare exemplar of a porous…

材料科学 · 物理学 2019-08-27 Abhijeet K. Chaudhari , Ha Jin Kim , Intaek Han , Jin-Chong Tan

Mechanoluminescent materials have a wide range of promising nanotechnological applications, such as photonics based sensors and smart optoelectronics. Examples of mechanoluminescent metal-organic framework (MOF) materials, however, are…

材料科学 · 物理学 2019-08-27 Abhijeet K. Chaudhari , Jin-Chong Tan

Metal organic frameworks (MOFs) are nanoporous materials with high surface-to-volume ratio that have potential applications as gas sorbents. Sample quality is, however, often compromised and it is unclear how defects and surface…

Thermal batteries based on a reversible adsorption-desorption of a working fluid rather than the conventional vapor compression is a promising alternative to exploit waste thermal energy for heat reallocation. In this context, there is an…

介观与纳米尺度物理 · 物理学 2017-02-24 Daiane Damasceno Borges , Guillaume Maurin , Douglas S. Galvao

Atomically thin, single-crystalline transition metal dichalcogenides (TMDCs) grown via chemical vapor deposition (CVD) on sapphire substrates exhibit exceptional mechanical and electrical properties, positioning them as excellent channel…

The compressive properties of metal-organic framework (MOF) crystals are not only crucial for their densification but also key in determining their performance in many applications. We herein investigated the mechanical responses of a…

材料科学 · 物理学 2023-07-31 Jin Zhang , Jin Ke , Bing Wang , Ximing Chen

Recent years have seen a large increase in the number of reported framework materials, including the nowadays-ubiquitous metal-organic frameworks (MOFs). Many of these materials show flexibility and stimuli-responsiveness, i.e. their…

材料科学 · 物理学 2019-07-11 François-Xavier Coudert

Luminescent metal-organic frameworks (MOFs) offer a multifunctional platform for creating non-invasive sensors and tuneable optoelectronics. However, fluorochromic materials that are photophysically resilient and show high sensitivity…

材料科学 · 物理学 2021-01-05 Yang Zhang , Mario Gutiérrez , Abhijeet K. Chaudhari , Jin-Chong Tan

Organic molecular crystals are ideally placed to become next-generation piezoelectric materials due to their diverse chemistries that can be used to engineer tailor-made solid-state assemblies. Using crystal engineering principles, and…

材料科学 · 物理学 2024-12-11 Shubham Vishnoi , Geetu Kumari , Robert Guest , Pierre-André Cazade , Sarah Guerin

Semiconducting two-dimensional transition metal chalcogenide crystals have been regarded as the promising candidate for the future generation of transistor in modern electronics. However, how to fabricate those crystals into practical…

介观与纳米尺度物理 · 物理学 2014-11-18 Xue Liu , Jin Hu , Chunlei Yue , Nicholas D. Della Fera , Yun Ling , Zhiqiang Mao , Jiang Wei

Ultrathin layers of semiconducting molybdenum disulfide (MoS2) offer significant prospects in future electronic and optoelectronic applications. Although an increasing number of experiments bring light into the electronic transport…

介观与纳米尺度物理 · 物理学 2014-07-10 Jing Wu , Hennrik Schmidt , Amara Kiran Kumar , Xiangfan Xu , Goki Eda , Barbaros Özyilmaz

Transition-metal dichalcogenides open novel opportunities for the exploration of exciting new physics and devices. As a representative system, 2H-MoS$_2$ has been extensively investigated owing to its unique band structure with a large band…

Measurements on 'free-standing' single crystal barium titanate capacitors with thicknesses down to 75nm show a dielectric response typical of large single crystals rather than conventional thin films. There is a notable absence of any…

材料科学 · 物理学 2007-05-23 M. M. Saad , P. Baxter , R. M. Bowman , J. M. Gregg , F. Morrison , J. F. Scott

We present an overview of recent studies of the charge transport in the field effect transistors on the surface of single crystals of organic low-molecular-weight materials. We first discuss in detail the technological progress that has…

其他凝聚态物理 · 物理学 2009-11-10 R. W. I. de Boer , M. E. Gershenson , A. F. Morpurgo , V. Podzorov

This work presents a detailed experimental investigation of the interaction between molecular hydrogen (H$_2$) and monolayer MoS$_2$ field effect transistors (MoS$_2$ FET), aiming for sensing application. The MoS$_2$ FET exhibits a response…

The guest-host liquid crystal display, first proposed in 1968, relies on controlling the orientation of dichroic dyes dissolved in a nematic liquid crystal host. Controlling the orientation of the liquid crystal and of the dissolved dye…

软凝聚态物质 · 物理学 2022-08-31 Obeng Appiagyei Addai , Ruilin Xiao , Xiaoyu Zheng , Peter Palffy-Muhoray
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