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Within the framework of the density matrix method, general formulas obtained that are convenient for describing fast pulsed photoemission that occurs in a time less than or on the order of the times of relaxation processes inside the…

介观与纳米尺度物理 · 物理学 2022-01-12 Yu. G. Peisakhovich , A. A. Shtygashev

Donor-acceptor (D-A) type copolymers show great potential for the application in the active layer of organic solar cells. Nevertheless the nature of the excited states, the coupling mechanism and the relaxation pathways following…

Understanding the mechanisms of efficient and robust energy transfer in light-harvesting systems provides new insights for the optimal design of artificial systems. In this paper, we use the Fenna-Matthews-Olson (FMO) protein complex and…

化学物理 · 物理学 2011-09-27 Jianlan Wu , Fan Liu , Young Shen , Jianshu Cao , Robert J. Silbey

Primitive photosynthetic cells appear over three billion years prior to any other more complex life-forms, thus it is reasonable to assume that Nature has designed a photosynthetic mechanism using minimal resources but honed to perfection…

量子物理 · 物理学 2011-06-23 B. Cui , X. Y. Zhang , X. X. Yi

In this work we give a comprehensive derivation of an exact and numerically feasible method to perform ab-initio calculations of quantum particles interacting with a quantized electromagnetic field. We present a hierachy of…

The collective absorption and emission of light by an ensemble of atoms is at the heart of many fundamental quantum optical effects and the basis for numerous applications. However, beyond weak excitation, both experiment and theory become…

Light-harvesting bacteria Rhodospirillum Photometricum were recently found to adopt strikingly different architectures depending on illumination conditions. We present analytic and numerical calculations which explain this observation by…

软凝聚态物质 · 物理学 2015-05-18 Felipe Caycedo-Soler , Ferney J. Rodriguez , Luis Quiroga , Neil F. Johnson

Direct detection experiments utilizing electronic excitations are spearheading the search for light, sub-GeV, dark matter (DM). It is thus crucial to have accurate predictions for any DM-electron interaction rate in this regime. EXCEED-DM…

高能物理 - 唯象学 · 物理学 2023-03-16 Tanner Trickle

The electronic excitation population and coherence dynamics in the chromophores of the photosynthetic light harvesting complex 2 (LH2) B850 ring from purple bacteria (Rhodopseudomonas acidophila) have been studied theoretically at both…

化学物理 · 物理学 2012-08-29 Shu-Hao Yeh , Jing Zhu , Sabre Kais

We study the dynamics of a single Frenkel exciton in a disordered molecular chain. The coherent-potential approximation (CPA) is applied to the situation when the single-molecule excitation energies as well as the transition dipole moments,…

无序系统与神经网络 · 物理学 2011-05-11 D. B. Balagurov , G. C. La Rocca , V. M. Agranovich

We review our recent quantum stochastic model for spectroscopic lineshapes in the presence of a co-evolving and non-stationary background population of excitations. Starting from a field theory description for interacting bosonic excitons,…

Excitons, Coulomb-bound electron-hole pairs, are the fundamental excitations governing the optoelectronic properties of semiconductors. While optical signatures of excitons have been studied extensively, experimental access to the excitonic…

Recent experiments have shown contradictory effects of strong light-matter coupling on exciton-exciton annihilation (EEA) in organic molecular systems. In this work, we perform numerical simulations of polariton dynamics and reveal the role…

化学物理 · 物理学 2026-05-20 I. Sokolovskii , B. S. Humphries , J. Blumberger , G. Groenhof

In the last decade, much theoretical research has focused on studying the strong coupling between organic molecules (or quantum emitters, in general) and light modes. The description and prediction of polaritonic phenomena emerging in this…

A general theory of electronic excitations in aggregates of molecules coupled to intramolecular vibrations and the harmonic environment is developed for simulation of the third-order nonlinear spectroscopy signals. The model is applied in…

化学物理 · 物理学 2014-01-17 Vytautas Butkus , Leonas Valkunas , Darius Abramavicius

When the interaction between a molecular system and confined light modes in an optical or plasmonic cavity is strong enough to overcome the dissipative process, hybrid light-matter states (polaritons) become the fundamental excitations in…

介观与纳米尺度物理 · 物理学 2020-01-08 Yu Zhang , Tammie Nelson , Sergei Tretiak

Excitons in the weakly interacting regime can be well-described by many-body perturbation theories such as the Bethe-Salpeter equation formalism. However, for materials such as transition metal dichalcogenides moir\'e heterostructures under…

材料科学 · 物理学 2026-03-16 Fangzhou Zhao , Carlos Mejuto-Zaera , Angel Rubio , Vojtěch Vlček

Exciton transport in molecular aggregates is a fundamental process governing the performance of organic optoelectronics and light-harvesting systems. While most theoretical studies have emphasized long-time transport behavior, recent…

化学物理 · 物理学 2026-03-25 Siwei Wang , Guangming Liu , Hsing-Ta Chen

Nanoplasmonics has been used to enhance molecular spectroscopic signals, with exquisite spatial resolution down to the sub-molecular scale. By means of a rigorous, state-of-the-art multiscale model based on a quantum chemical description,…

介观与纳米尺度物理 · 物理学 2018-09-27 Stefano Caprasecca , Stefano Corni , Benedetta Mennucci

In photosynthetic organisms, the energy of light during illumination is absorbed by the antenna complexes, which is transmitted by excitons and is either absorbed by the reaction centers (RCs), which have been closed in this way, or emitted…

统计力学 · 物理学 2021-05-12 Jean-Christian Anglès d'Auriac , Ferenc Iglói