相关论文: Non-thermal desorption of complex organic molecule…
Aims. In this paper we investigate the detectability of the molecular oxygen in icy dust grain mantles towards astronomical objects. Methods. We present a systematic set of experiments with O2-H2O ice mixtures designed to disentangle how…
Extremely high deuteration of several molecules have been observed around low mass protostars since a decade. Among them, formaldehyde and methanol present particularly high deuteration, with observations of abundant doubly and triply…
Here we present high spatial resolution (<1 arcsecond) observations of molecular emission in Orion-KL conducted using the Combined Array for Research in Millimeter-Wave Astronomy (CARMA). This work was motivated by recent millimeter…
In cold molecular clouds, UV photolysis of icy grain mantles generates radicals that lead to new molecule formation. When radical diffusion is limited by low temperatures, oxygen atom addition and insertion reactions, enabled by photolysis…
Observations with the Short Wavelength Spectrometer (SWS) onboard the {\it Infrared Space Observatory} (ISO) have led to the first detection of the methyl radical ${\rm CH_3}$ in the interstellar medium. The $\nu_2$ $Q-$branch at 16.5…
Sputtering by solar wind ions is a key process driving the ejection of high-energy particles into the exospheres of airless bodies like asteroids, Mercury and the Moon. In view of upcoming missions which will deliver new in-situ data on…
In this paper we use observations of molecular tracers in metal rich and alpha-enhanced galaxies to study the effect of abundance changes on molecular chemistry. We selected a sample of metal rich spiral and star bursting objects from the…
Acetone (CH3COCH3) is one of the most abundant three-carbon oxygen-bearing complex organic molecules (O-COMs) that have been detected in space. Recently, acetone ice has been reported as (tentatively) detected toward B1-c, which enables the…
Methanol (CH$_3$OH) and formaldehyde (H$_2$CO) are chemically coupled organic molecules proposed to act as an intermediate step between simple molecules and more complex prebiotic compounds. Their abundance distributions across disks…
Deuterium fractionation, as studied through mono-deuterated methanol, is frequently used as a diagnostic tool to trace the physical conditions and chemical evolution of interstellar sources. This study investigates methanol deuteration in…
We report the first high angular resolution imaging (3.4\arcsec $\times$ 3.0\arcsec) of deuterated formaldehyde (HDCO) toward Orion--KL, carried out with the Submillimeter Array (SMA). We find that the spatial distribution of the…
The physical conditions in a collapsing cloud can be traced by observations of molecular lines. To correctly interpret these observations the abundance distributions of the observed species need to be derived. The chemistry in a collapsing…
Complex Organic Molecules (COMs) have been detected in the interstellar medium (ISM). However, it is not clear whether their synthesis occurs on the icy surfaces of interstellar grains or via a series of gas-phase reactions. As a test case…
Non-thermal desorption of inter- and circum-stellar ice mantles on dust grains, in particular ultraviolet photon-induced desorption, has gained importance in recent years. These processes may account for the observed gas phase abundances of…
Spectroscopic studies play a key role in the identification and analysis of interstellar ices and their structure. Some molecules have been identified within the interstellar ices either as pure, mixed, or even as layered structures.…
Complex organic molecules (COMs) in starless cores provide critical insights into the early stages of star formation and prebiotic chemistry. We present a chemical survey of 16 starless cores (including five prestellar cores) in the Orion A…
The formation of singly and doubly deuterated isotopomers of formaldehyde and of singly, doubly, and multiply deuterated isotopomers of methanol on interstellar grain surfaces has been studied with a semi-empirical modified rate approach…
Ice mantles play a crucial role in shaping the astrochemical inventory of molecules during star and planet formation. Small-scale molecular processes have a profound impact on large-scale astronomical evolution. The areas of solid-state…
Recent studies suggest that infrared dark clouds (IRDCs) have the potential of harboring the earliest stages of massive star formation and indeed evidence for this is found toward distinct regions within them. We present a study with the…
Solid-phase photo-processes involving icy dust grains greatly affect the chemical evolution of the interstellar medium by leading to the formation of complex organic molecules and by inducing photodesorption. So far, the focus of laboratory…