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We have started a measurement campaign of numerous methanol isotopologs in low-lying torsional states in order to provide extensive line lists for radio astronomical observations from an adequate spectroscopic model and to investigate how…

We present the first astrophysical detection of methanol (CH3OH) in the torsional band near 25 um. Using high resolution mid-infrared (MIR) spectroscopy, we identified over seventy gas-phase CH3OH absorption lines between 20 and 28 um…

From STIS observations of Uranus in 2012, we found that the methane volume mixing ratio declined from about 4% at low latitudes to about 2% at 60 deg N and beyond. This is similar to that found in the south polar regions in 2002, in spite…

地球与行星天体物理 · 物理学 2015-02-24 Lawrence Sromovsky , Erich Karkoschka , Patrick Fry , Heidi Hammel , Imke de Pater , Kathy Rages

A longstanding problem in astrochemistry is how molecules can be maintained in the gas phase in dense inter- and circumstellar regions. Photodesorption is a non-thermal desorption mechanism, which may explain the small amounts of observed…

天体物理学 · 物理学 2015-05-13 Karin I. Oberg , Ewine F. van Dishoeck , Harold Linnartz

We present experimental results obtained from photoionization and photodissociation processes of abundant interstellar methanol (CH$_3$OH) as an alternative route for the production of H$_3^+$ in dense clouds. The measurements were taken at…

天体物理学 · 物理学 2009-11-13 S. Pilling , D. P. P. Andrade , A. C. F. Santos , H. M. Boechat-Roberty

Context: Hydrogenation reactions are expected to be among the most important surface reactions on interstellar ices. However, solid state astrochemical laboratory data on reactions of H-atoms with common interstellar ice constituents are…

天体物理学 · 物理学 2009-11-13 S. E. Bisschop , G. W. Fuchs , E. F. van Dishoeck , H. Linnartz

Cosmic rays are able to heat interstellar dust grains. This may enhance molecule mobility in icy mantles that have accumulated on the grains in dark cloud cores. A three-phase astrochemical model was used to investigate the molecule…

星系天体物理 · 物理学 2018-03-14 Juris Kalvans

Observations of star forming environments revealed that the abundances of some deuterated interstellar molecules are markedly larger than the cosmic D/H ratio of 10-5. Possible reasons for this pointed to grain surface chemistry. How- ever,…

太阳与恒星天体物理 · 物理学 2015-05-28 S. Cazaux , P. Caselli , M. Spaans

We present experimental results obtained from photoionization and photodissociation processes of abundant interstellar CH$_3$-X type organic molecules like methanol (CH$_3$OH), methylamine (CH$_3$NH$_2$) and acetonitrile (CH$_3$CN) as…

We present new models of the deuterium chemistry in protoplanetary disks, including, for the first time, multiply deuterated species. We use these models to explore whether observations in combination with models can give us clues as to…

天体物理学 · 物理学 2011-02-11 K. Willacy

The fate of metals ejected by young OB associations into the Interstellar Medium (ISM) is investigated numerically. In particular, we study the enrichment of the cold gas phase, which is the material that forms molecular clouds. Following…

星系天体物理 · 物理学 2011-11-09 Evangelia Ntormousi , Andreas Burkert

Ice chemistry in the dense, cold interstellar medium (ISM) is probably responsible for the formation of interstellar complex organic molecules (COMs). Recent laboratory experiments performed at T=4 K have shown that irradiation of CO:N2 ice…

星系天体物理 · 物理学 2024-01-09 Rafael Martín-Doménech , Alexander DelFranco , Karin I. Öberg , Mahesh Rajappan

We report the discovery of a widespread population of collisionally excited methanol J = 4_{-1} to 3$_0 E sources at 36.2 GHz from the inner 66'x18' (160x43 pc) of the Galactic center. This spectral feature was imaged with a spectral…

星系天体物理 · 物理学 2015-06-12 F. Yusef-Zadeh , W. Cotton , S. Viti , M. Wardle , M. Royster

The radiolysis of a nitrogen-acetone mixture, condensed at 11 K, by 40 MeV $^{58}$Ni$^{11+}$ ions is studied. These results are representative of studies concerning solar system objects exposed to cosmic rays. In the Kuiper Belt, region of…

地球与行星天体物理 · 物理学 2017-12-06 A. L. F. de Barros , D. P. P. Andrade , E. F. da Silveira , K. F. Alcantara , P. Boduch , H. Rothard

We report the result of a systematic methanol observation toward IRAS 19312+1950. The properties of the SiO, H2O and OH masers of this object are consistent with those of mass-losing evolved stars, but some other properties are difficult to…

太阳与恒星天体物理 · 物理学 2015-08-06 Jun-ichi Nakashima , Andrej M. Sobolev , Svetlana V. Salii , Yong Zhang , Bosco H. K. Yung , Shuji Deguchi

Gas-phase hydroxylamine (NH$_2$OH) has recently been detected within dense clouds in the interstellar medium. However, it is also likely present within interstellar ices, as well as on the icy surfaces of outer Solar System bodies, where it…

Complex organic molecules (COMs) have been detected abundantly at various stages of star formation, particularly in the warm protostellar phase. The progress in gas-phase measurements has been accelerated by the advent of the Atacama Large…

星系天体物理 · 物理学 2025-10-20 P. Nazari

Optically dense clouds in the interstellar medium composed predominantly of molecular hydrogen, known as molecular clouds, are sensitive to energy injection in the form of photon absorption, cosmic-ray scattering, and dark matter (DM)…

高能物理 - 唯象学 · 物理学 2024-02-19 Carlos Blanco , Ian Harris , Yonatan Kahn , Anirudh Prabhu

Pure acetonitrile (CH3CN) and mixed CO:CH3CN and H2O:CH3CN ices have been irradiated at 15K with Vacuum UltraViolet (VUV) photons in the 7-13.6 eV range using synchrotron radiation. VUV photodesorption yields of CH3CN and of photo-products…

Water (H2O) ice is an important solid constituent of many astrophysical environments. To comprehend the role of such ices in the chemistry and evolution of dense molecular clouds and comets, it is necessary to understand the freeze-out,…

天体物理学 · 物理学 2009-11-06 Helen J. Fraser , Mark P. Collings , Martin R. S. McCoustra , David A. Williams
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