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As high-performance organic semiconductors, {\pi}-conjugated polymers have attracted much attention due to their charming advantages including low-cost, solution processability, mechanical flexibility, and tunable optoelectronic properties.…

材料科学 · 物理学 2021-02-09 Lixing Luo , Wanning Huang , Canglei Yang , Jing Zhang , Qichun Zhang

Conjugated polymers are experiencing a surge of renewed interest due to their promising applications in various organic electronic devices. These include organic light-emitting diodes (OLEDs), field-effect transistors (FETs), and organic…

材料科学 · 物理学 2025-09-24 Miguel Lagos , Miguel Kiwi , Rodrigo Paredes

Organic semiconductors have the remarkable property that their optical excitation not only generates charge-neutral electron-hole pairs (excitons) but also charge-separated polaron pairs with high yield. The microscopic mechanisms…

Electronic conduction in conjugated polymers is of emerging technological interest for high-performance optoelectronic and thermoelectric devices. A completely new aspect and understanding of the conduction mechanism on conducting polymers…

材料科学 · 物理学 2015-08-18 Asli Ugur , Ferhat Katmis , Mingda Li , Lijun Wu , Yimei Zhu , Kripa K. Varanasi , Karen K. Gleason

Organic semiconductors have generated considerable interest for their potential for creating inexpensive and flexible devices easily processed on a large scale [1-11]. However technological applications are currently limited by the low…

Coordination compounds with tin centre surrounded by both organic and inorganic ligands ([SnI4{(C6H5)3PO}2], [SnI4{(C6H5)2SO}2] and [SnI4(C5H5NO)2]), acting as molecular semiconductors are in the spotlight of this article. This is a new…

材料科学 · 物理学 2018-11-05 Ewelina Wlazlak , Wojciech Macyk , Wojciech Nitek , Konrad Szacilowski

Conjugated polymers are soft, one-dimensional conductors that admit complex interactions between their polymeric, conformational degrees of freedom and their electronic ones. The presence of extended electronic states along their backbone…

软凝聚态物质 · 物理学 2011-07-29 Jeremy D. Schmit , Alex J. Levine

There is currently a great need for solid state lasers that emit in the infrared, as this is the operating wavelength regime for applications in telecommunications. Existing $\pi$--conjugated polymers all emit in the visible or ultraviolet,…

材料科学 · 物理学 2009-11-07 S. Dallakyan , M. Chandross , S. Mazumdar

The electronic properties of interfaces between two different solids can differ strikingly from those of the constituent materials. For instance, metallic conductivity, and even superconductivity, have been recently discovered at interfaces…

材料科学 · 物理学 2009-11-13 H. Dias Alves , A. S. Molinari , H. Xie , A. F. Morpurgo

We describe both pi-conjugated polymers and semiconducting single-walled carbon nanotubes because of the remarkable similarities in their behavior under photoexcitation. The common themes between these two seemingly different classes of…

材料科学 · 物理学 2009-02-17 Sumit Mazumdar , Zhendong Wang , Hongbo Zhao

We review the binding and energy level alignment of $\pi$-conjugated systems on metals, a field which during the last two decades has seen tremendous progress both in terms of experimental characterization as well as in the depth of…

材料科学 · 物理学 2020-05-01 Antoni Franco-Cañellas , Steffen Duhm , Alexander Gerlach , Frank Schreiber

The photophysics of $\pi$-conjugated polymers has been of considerable interest over the last three decades because of their organic semiconductor properties. Primary photoexcitations, Frenkel excitons, can be probed optically by means of…

Research on conjugated polymers for thermoelectric applications has made tremendous progress in recent years, which is accompanied by surging interest in molecular doping as a means to achieve the high electrical conductivities that are…

The interaction of light with solids gives rise to new bosonic quasiparticles, with the exciton being---undoubtedly---the most famous of these polaritons. While excitons are the generic polaritons of semiconductors, we show that for…

强关联电子 · 物理学 2020-02-04 Anna Kauch , Petra Pudleiner , Katharina Astleithner , Patrik Thunström , Tin Ribic , Karsten Held

Electrons in condensed matter may transition into a variety of broken-symmetry phase states due to electron-electron interactions. Applying diverse mean-field approximations to the interaction term is arguably the simplest way to identify…

强关联电子 · 物理学 2024-06-17 Maxim Trushin , Liangtao Peng , Gargee Sharma , Giovanni Vignale , Shaffique Adam

Composite oxides have been indeed proved to be valuable materials in optoelectronic applications. The combination of indium oxide and gallium oxide and other materials can lead to enhanced optical and electronic properties, making them…

材料科学 · 物理学 2024-03-20 Chrislene Lionel , Shubham Das , Diparnab Banik , S. Koley

Modeling the electronic and optical properties of organic semiconductors remains a challenge for theory, despite the remarkable progress achieved in the last three decades. The complexity of these systems, including structural (dis)order…

We present a first-principles investigation of the electronic and optical properties of hybrid organic-inorganic interfaces consisting of MoS$_2$ monolayer and the $\pi$-conjugate molecules pyrene and pyridine. For both hybrid systems, the…

材料科学 · 物理学 2021-12-16 Ignacio Gonzalez Oliva , Fabio Caruso , Pasquale Pavone , Claudia Draxl

Conduction in pristine conjugated polymers (other than polyacetylene) is by polaron hopping between sites corresponding to conjugation lengths. The strong increase of current $I$ with voltage $V$ observed for both emission-limited and ohmic…

软凝聚态物质 · 物理学 2015-06-25 E. M. Conwell , M. W. Wu

For a class of 2D hybrid organic-inorganic perovskite semiconductors based on $\pi$-conjugated organic cations, we predict quantitatively how varying the organic and inorganic component allows control over the nature, energy and…

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