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We report a more than 10-fold enhancement of the piezoelectric coefficient $d_{33}$ of polycrystalline CH$_3$NH$_3$PbI$_3$ (MAPbI$_3$) films when interfacing them with ferroelectric PbZr$_{0.2}$Ti$_{0.8}$O$_3$ (PZT). Piezo-response force…

材料科学 · 物理学 2018-06-12 Jingfeng Song , Zhiyong Xiao , Bo Chen , Spencer Prockish , Xuegang Chen , Jinsong Huang , Xia Hong

Hybrid organic-inorganic metal halide perovskites are emerging materials in photovoltaics, whose bandgap is one of the most crucial parameters governing their light harvesting performance. Here we present the temperature and photocarrier…

Lead halide perovskites are causing a change of paradigm in photovoltaics. Among other peculiarities, these perovskites exhibit an atypical temperature dependence of the fundamental optical gap: It decreases in energy with decreasing…

Films of (FA$_{0.79}$MA$_{0.16}$Cs$_{0.05}$)$_{0.97}$Pb(I$_{0.84}$Br$_{0.16}$)$_{2.97}$ were grown over TiO$_{2}$, SnO$_{2}$, ITO, and NiO. Film conductivity was interrogated by measuring the in-phase and out-of-phase forces acting between…

Hybrid perovskite thin films have demonstrated impressive performance for solar energy conversion and optoelectronic applications. However, further progress will benefit from a better knowledge of the intrinsic photophysics of materials.…

Perovskite-based optoelectronic devices have shown great promise for solar conversion and other optoelectronic applications, but their long-term performance instability is regarded as a major obstacle to their widespread deployment.…

Tuning the thermal transport properties of hybrid halide perovskites is critical for their applications in optoelectronics, thermoelectrics, and photovoltaics. Here, we demonstrate an effective strategy to modulate the thermal transport…

材料科学 · 物理学 2024-01-02 Guang Wang , Hongzhao Fan , Zhongwei Chen , Yufei Gao , Zuankai Wang , Zhigang Li , Haipeng Lu , Yanguang Zhou

Mixed halide perovskites undergo phase segregation, manifested as spectral red-shifting of photoluminescence spectra under illumination. In the iodine-bromide mixed perovskites, the origin of the low-energy luminescence is related to…

Layered hybrid perovskites containing larger organic cations have demonstrated superior environmental stability, but the presence of these insulating spacers also strengthens the exciton binding energy, which contributes to reduced carrier…

Halide perovskites are a promising optical gain media with high tunability and simple solution synthesis. In this study, two gain regimes, namely amplified spontaneous emission and random lasing, are demonstrated in same MAPbBr$_3$ halide…

Organolead halide perovskites have attracted substantial attention due to their excellent physical properties, which enable them to serve as the active material in emerging hybrid solid-state solar cells. Here we investigate the…

材料科学 · 物理学 2015-10-28 Feng Li , Chun Ma , Hong Wang , Weijin Hu , Weili Yu , Arif D. Sheikh , Tom Wu

Double perovskites have emerged as promising alternatives to lead halide perovskites, aiming to mitigate challenges related to toxicity and chemical instability. Among them, mixed-valence gold halides such as Cs2Au+Au3+Cl6, which contain…

State-of-the-art hybrid perovskites have demonstrated excellent functionality in photovoltaics and light-emitting applications, and have emerged as a promising candidate for exciton-polariton (polariton) optoelectronics. In the strong…

Electric force microscopy was used to record the light-dependent impedance spectrum and the probe transient photoconductivity of a film of butylammonium lead iodide, BA$_{2}$PbI$_{4}$, a 2D Ruddlesden--Popper perovskite semiconductor. The…

介观与纳米尺度物理 · 物理学 2020-06-02 Ali Moeed Tirmzi , Ryan P. Dwyer , Fangyuan Jiang , John A. Marohn

We have investigated the electronic structure of A-site ordered CaCu$_3$Ti$_4$O$_{12}$ as a function of temperature by using angle-integrated and -resolved photoemission spectroscopies. Intrinsic changes of the electronic structure have…

强关联电子 · 物理学 2019-06-13 H. J. Im , T. Sakurada , M. Tsunekawa , T. Watanabe , H. Miyazaki , S. Kimura

Environmental effects and intrinsic energy-loss processes lead to fluctuations in the operational temperature of solar cells, which can profoundly influence their power conversion efficiency. Here we determine from first principles the…

材料科学 · 物理学 2016-12-16 Wissam A. Saidi , Samuel Poncé , Bartomeu Monserrat

Quantum technologic and spintronic applications require reliable semiconducting materials that enable a significant, long-living spin polarization of electronic excitations and offer the ability to manipulate it optically in an external…

Metal-halide perovskites are rapidly emerging as solution-processable optical materials for light emitting applications. Here we adopt a plasmonic metamaterial approach to enhance photoluminescence emission and extraction of methylammonium…

We report on optical spectroscopy (photoluminescence and photoluminescence excitation) on two-dimensional self-organized layers of $(C_{6}H_{5}C_{2}H_{4}-NH_{3})_{2}PbI_{4}$ perovskite. Temperature and excitation power dependance of the…

Electronic transport has been investigated for strong spin-orbit coupled perovskite SrIrO3 thin films grown at various substrate temperatures. The electronic transport of the SrIrO3 films is found to be very sensitive to the growth…

强关联电子 · 物理学 2015-03-17 Abhijit Biswas , Yoon Hee Jeong
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