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The bulk photovoltaic effect (BPVE) occurs in solids with broken inversion symmetry and refers to DC current generation due to uniform illumination, without the need of heterostructures or interfaces, a feature that is distinct from the…

材料科学 · 物理学 2022-06-02 Zhenbang Dai , Andrew M. Rappe

Shift current and ballistic current have been proposed to explain the bulk photovoltaic effect (BPVE), and there have been experiments designed to separate the two mechanisms. These experiments are based on the assumption that under…

材料科学 · 物理学 2023-05-24 Zhenbang Dai , Andrew M. Rappe

The bulk photovoltaic effect (BPVE) refers to current generation due to illumination by light in a homogeneous bulk material lacking inversion symmetry. In addition to the intensively studied shift current, the ballistic current, which…

材料科学 · 物理学 2021-05-05 Zhenbang Dai , Aaron M. Schankler , Lingyuan Gao , Liang Z. Tan , Andrew M. Rappe

The bulk photovoltaic effect (BPVE) generates a direct current photocurrent under uniform irradiation and is a nonlinear optical effect traditionally studied in non-centrosymmetric materials. The two main origins of BPVE are the shift and…

介观与纳米尺度物理 · 物理学 2025-03-03 Ying-Ming Xie , Naoto Nagaosa

A bulk material without inversion symmetry can generate a direct current under illumination. This interface-free current generation mechanism, referred to as the bulk photovoltaic effect (BPVE), does not rely on $p$-$n$ junctions. Here, we…

材料科学 · 物理学 2023-05-01 Zhuang Qian , Jian Zhou , Hua Wang , Shi Liu

The bulk photovoltaic effect (BPVE) has attracted an increasing interest due to its potential to overcome the efficiency limit of traditional photovoltaics, and much effort has been devoted to understanding its underlying physics. However,…

材料科学 · 物理学 2022-01-05 Zhenbang Dai , Andrew M. Rappe

The bulk photovoltaic effect (BPVE) refers to the direct current generation in a noncentrosymmetric material under illumination and can be applied to solar energy technology. BPVE includes injection and shift currents, led by the change of…

介观与纳米尺度物理 · 物理学 2025-11-04 Bo-Xin Lin , Hsiu-Chuan Hsu

The bulk photovoltaic effect (BPVE), a manifestation of broken centrosymmetry, has attracted interest as a probe of the symmetry and quantum geometry of materials, and for use in novel optoelectronic devices. Despite its bulk nature, the…

The correlation between the shift current mechanism for the bulk photovoltaic effect (BPVE) and the structural and electronic properties of ferroelectric perovskite oxides is not well understood. Here, we study and engineer the shift…

材料科学 · 物理学 2015-03-03 Fenggong Wang , Steve M. Young , Fan Zheng , Ilya Grinberg , Andrew M. Rappe

Photodetection is an indispensable function of optoelectronic devices in modern communication and sensing systems. Contrary to the near-infrared/visible regions, the fast and sensitive photodetectors operated at room temperature for the…

The bulk photovoltaic effect (BPVE) refers to the phenomenon of generating photocurrent or photovoltage in homogeneous noncentrosymmetric materials under illumination, and the intrinsic contribution to the BPVE is known as the shift current…

材料科学 · 物理学 2023-02-01 Gan Jin , Lixin He

The bulk photovoltaic effect (BPVE) is a second-order optical process in noncentrosymmetric materials that converts the light into DC currents. BPVE is classified into shift current and injection current according to the generation…

材料科学 · 物理学 2023-02-21 Hanqi Pi , Shuai Zhang , Hongming Weng

The bulk photovoltaic effect (BPVE) is a phenomenon which creates a net electrical current from sunlight in a polar noncentrosymmetric material possessing a moderate band gap. This effect is being explored as an alternative to traditional…

材料科学 · 物理学 2018-02-14 John A. Brehm

We compute the shift current bulk photovoltaic effect (BPVE) in bulk BaTiO$_3$ and two-dimensional monochalcogenide SnSe considering quasi-particle corrections and exciton effects. We explore changes in shift current peak position and…

材料科学 · 物理学 2020-01-15 Ruixiang Fei , Liang Z. Tan , Andrew M. Rappe

The connection between noncentrosymmetric materials' structure, electronic structure, and bulk photovoltaic performance remains not well understood. In particular, it is still unclear which photovoltaic (PV) mechanism(s) are relevant for…

材料科学 · 物理学 2015-05-20 Fenggong Wang , Andrew M. Rappe

Spin current generators are critical components for spintronics-based information processing. In this work, we theoretically and computationally investigate the bulk spin photovoltaic (BSPV) effect for creating DC spin current under light…

材料科学 · 物理学 2021-07-20 Haowei Xu , Hua Wang , Jian Zhou , Ju Li

The bulk photovoltaic (BPV) effect that converts light into electric current is highly sensitive to the system symmetry and its electronic Bloch wavefunction. To create a sizable net electric current, it is necessary to break the…

材料科学 · 物理学 2024-07-08 Chunmei Zhang , Jian Zhou

Shift current---a photocurrent induced by light irradiating noncentrosymmetric materials in the absence of any bias voltage or built-in electric field---is one of the mechanisms of the so-called bulk photovoltaic effect. It has been…

介观与纳米尺度物理 · 物理学 2019-03-28 U. Bajpai , B. S. Popescu , P. Plechac , B. K. Nikolic , L. E. F. Foa Torres , H. Ishizuka , N. Nagaosa

Steady illumination of a non-centrosymmetric semiconductor results in a bulk photovoltaic current, which is contributed by real-space displacements (`shifts') of charged quasiparticles as they transit between Bloch states. The shift induced…

介观与纳米尺度物理 · 物理学 2025-08-12 Penghao Zhu , A. Alexandradinata

The nonlinear shift current, also known as the bulk photovoltaic current generated by linearly polarized light, has long been known to be absent in crystals with inversion symmetry. Here we argue that a non-zero shift current in…

介观与纳米尺度物理 · 物理学 2021-05-19 Li-kun Shi , Dong Zhang , Kai Chang , Justin C. W. Song
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