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When the weak-forces producing parity-violating effects are taken into account, there is a tiny energy difference between the total electronic energies of two enantiomers ($\Delta E_{PV}$), which might be the key to understand the evolution…

化学物理 · 物理学 2026-03-03 Juan J. Aucar , Alessandro Stroppa , Gustavo A. Aucar

The parity-violating energy difference (PVED) between two enantiomers of a chiral molecule is caused by the weak interaction. Because of the smallness of the PVED, nonzero PVED is yet to be discovered in experimental searches. To detect the…

化学物理 · 物理学 2022-02-09 Naoya Kuroda , Takumi Oho , Ayaki Sunaga , Masato Senami

Previously, it was predicted that the parity-violating energy difference (PVED) between enantiomers and the molecular electron chirality (MEC), which is the integrated value of the electron chirality density over the entire molecule are…

化学物理 · 物理学 2024-10-30 Naoya Kuroda , Masato Senami

Pseudoscalar or pseudovector cosmic fields, that serve as a source of parity ($\mathcal{P}$) violation, are invoked in different models for cold dark matter or in the standard model extension that allows for Lorentz invariance violation. A…

化学物理 · 物理学 2020-09-23 Konstantin Gaul , Mikhail G. Kozlov , Timur A. Isaev , Robert Berger

We present a study of parity (P) violating contributions to the eigenenergies of stationary systems containing atoms in spatially inhomogeneous external electric fields. In this context the subtle interplay of P-violation and time reversal…

高能物理 - 唯象学 · 物理学 2007-05-23 D. Bruss , T. Gasenzer , O. Nachtmann

P-violation of the nuclear weak force was hitherto believed to manifest itself only in asymmetric $\beta$-emission due to neutron decay. Molecules with space asymmetry (like L and D amino acids) are affected by this parity violation,…

化学物理 · 物理学 2007-05-23 Avshalom C. Elizur , Meir Shinitzky

Searches for violations of the fundamental symmetries of parity P and time reversal T in atomic and molecular systems provide a powerful tool for precise measurements of the physics of and beyond the standard model. In this work, we…

原子物理 · 物理学 2024-12-12 Sebastian Lahs , Daniel Comparat

We study chiral symmetry breaking for fundamental charged fermions coupled electromagnetically to photons with the inclusion of four-fermion contact self-interaction term. We employ multiplicatively renormalizable models for the photon…

There exist two deformations of standard electrodynamics that describe Lorentz symmetry violation in the photon sector: CPT-odd Maxwell-Chern-Simons theory and CPT-even modified Maxwell theory. In this article, we focus on the parity-odd…

高能物理 - 理论 · 物理学 2015-03-19 Marco Schreck

The energy shift in molecular spectra due to interaction of nuclear magnetic quadrupole moment ($M$) with electrons is equal to $\delta E_M = MW_M P_{ M}$, where $W_M$ is a constant determined by the electronic structure of the molecule and…

原子物理 · 物理学 2022-12-13 Igor Kurchavov , Alexander Petrov

We consider hydrogen-like atoms in unstable levels of principal quantum number n=2, confined to a finite size region in a non-homogeneous electric field carrying handedness. The interplay between the internal degrees of freedom of the atoms…

高能物理 - 唯象学 · 物理学 2009-10-30 D. Bruss , T. Gasenzer , O. Nachtmann

Spectroscopic techniques that are sensitive to molecular chirality are important analytical tools to quantitatively determine enantiomeric excess and purity of chiral molecular samples. Many chiroptical processes however produce weak…

化学物理 · 物理学 2026-04-02 Sebastian Hartweg , Dusan k. Bozanic , Gustavo A. Garcia-Macias , Laurent Nahon

This review is based on the talk in the conference of "Spectroscopic Studies on Molecular Chirality" held on Dec 20-21 2013. The objects of the present paper are to (1) derive the energy difference between Laevorotatory, or left-handed,…

高能物理 - 唯象学 · 物理学 2014-04-02 Takeshi Fukuyama

In this perspective, we discuss where and how accounting for electronic many-body polarization affects the accuracy of classical molecular dynamics simulations of biomolecules.While the effects of electronic polarization are highly…

化学物理 · 物理学 2021-03-29 Josef Melcr , Jean-Philip Piquemal

A permanent electric dipole moment (EDM) of a particle or system is a separation of charge along its angular-momentum axis and is a direct signal of T-violation and, assuming CPT symmetry, CP violation. For over sixty years EDMs have been…

原子物理 · 物理学 2019-02-08 Timothy Chupp , Peter Fierlinger , Michael Ramsey-Musolf , Jaideep Singh

The Standard Model cannot explain the dominance of matter over anti-matter in our universe. This imbalance indicates undiscovered physics that violates combined CP symmetry. Many extensions to the Standard Model seek to explain the…

The relations between matrix elements of different P- and T-odd weak interactions are derived. We demonstrate that similar relations hold for parity nonconserving (PNC) transition amplitudes and electron electric dipole moments (EDM) of…

原子物理 · 物理学 2015-05-30 V. A. Dzuba , V. V. Flambaum , C. Harabati

Nuclear spin-dependent parity violation (NSD-PV) effects in atoms and molecules arise from $Z^0$ boson exchange between electrons and the nucleus, and from the magnetic interaction between electrons and the parity-violating nuclear anapole…

原子物理 · 物理学 2018-04-06 Emine Altuntas , Jeffrey Ammon , Sidney B. Cahn , David DeMille

Chiral molecules are instrumental for molecular recognition in living organisms. Distinguishing between two opposite enantiomers, the mirror twins of the same chiral molecule, is both vital and challenging. Photoelectron circular dichroism…

化学物理 · 物理学 2021-12-07 Andres F. Ordonez , David Ayuso , Piero Decleva , Olga Smirnova
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