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Despite its fundamental importance for nano physics and chemistry and potential device applications, the relationship between atomic structure and electronic transport in molecular nanostructures is not well understood. Thus the…

介观与纳米尺度物理 · 物理学 2014-02-04 Alireza Saffarzadeh , Firuz Demir , George Kirczenow

We present ab-initio transport calculations for molecular junctions that include graphene as a protecting layer between a single molecule and gold electrodes. This vertical setup has recently gained significant interest in experiment for…

介观与纳米尺度物理 · 物理学 2015-12-15 Falco Hüser , Gemma C. Solomon

Electrical excitation of light using inelastic electron tunneling is a promising approach for the realization of ultra-compact on-chip optical sources with high modulation bandwidth. However, the practical implementation of these nanoscale…

光学 · 物理学 2020-09-14 Saurabh Kishen , Jinal Tapar , Naresh Kumar Emani

The discovery of a two-dimensional electron gas (2DEG) at the interface between insulating oxides has led to a well-deserved level of excitement due to possible applications as "in-plane" all-oxide nanoelectronics. Here we expand the range…

材料科学 · 物理学 2009-09-16 J. D. Burton , J. P. Velev , E. Y. Tsymbal

The process of creating an atomically defined and robust metallic tip is described and quantified using measurements of contact conductance between gold electrodes and numerical simulations. Our experiments show how the same conductance…

材料科学 · 物理学 2012-05-30 C. Sabater , C. Untiedt , J. J. Palacios , M. J. Caturla

We present atomistic calculations of quantum coherent electron transport through fulleropyrrolidine terminated molecules bridging a graphene nanogap. We predict that three difficult problems in molecular electronics with single molecules…

介观与纳米尺度物理 · 物理学 2013-06-14 A. Bergvall , K. Berland , P. Hyldgaard , S. Kubatkin , T. Lofwander

Spin crossover (SCO) molecules are promising bi-stable magnetic switches with applications in molecular spintronics. However, little is known about the switching effects of a single SCO molecule when it is confined between two metal…

介观与纳米尺度物理 · 物理学 2020-06-12 Alex Gee , Ayoub H. Jaafar , Barbora Brachňaková , Jamie Massey , Christopher H. Marrows , Ivan Šalitroš , N. T. Kemp

Electrical conductance through various nanocontacts between gold electrodes is studied by using the density functional theory, scalar-relativistic pseudopotentials, generalized gradient approximation for the exchange-correlation energy and…

材料科学 · 物理学 2009-11-13 O. Lopez-Acevedo , D. Koudela , H. Häkkinen

Capturing molecular dynamics in nanoconfined channels with high spatiotemporal resolution is a key challenge in nanoscience, crucial for advancing catalysis, energy conversion, and molecular sensing. Bottom-up ultrathin plasmonic nanogaps,…

We assess the performances of the transition voltage spectroscopy (TVS) method to determine the energies of the molecular orbitals involved in the electronic transport though molecular junctions. A large number of various molecular…

介观与纳米尺度物理 · 物理学 2013-02-11 Guillaume Ricœur , Stéphane Lenfant , David Guérin , Dominique Vuillaume

We have developed a technology to reproducibly make gaps with distance control on the single atom scale. The gold contacts are flat on the nanometre scale and are fabricated on an oxidized aluminium film that serves as a gate. We show that…

材料科学 · 物理学 2009-11-10 Y. V. Kervennic , D. Vanmaekelbergh , L. P Kouwenhoven , H. S. J Van der Zant

We measure electronic conductance through single conjugated molecules bonded to Au metal electrodes with direct Au-C covalent bonds using the scanning tunneling microscope based break-junction technique. We start with molecules terminated…

We present the design, fabrication and response of humidity sensor based on electrical tunneling through temperature-stabilized nanometer gaps. The sensor consists of two stacked metal electrodes separated by 2.5 nm of vertical air gap.…

应用物理 · 物理学 2019-11-06 Aishwaryadev Banerjee , Rugved Likhite , Hanseup Kim , Carlos H. Mastrangelo

Although it was demonstrated that discrete molecular levels determine the sign and magnitude of the thermoelectric effect in single-molecule junctions, full electrostatic control of these levels has not been achieved to date. Here, we show…

This letter reports on the observation of optoelectronic switching in addressable molecular crossbar junctions fabricated using polymer stamp-printing method. The active medium in the junction is a molecular self-assembled monolayer softly…

软凝聚态物质 · 物理学 2009-04-28 J. C. Li

Characterization of the structural and electron transport properties of single chiral molecules provides critical insights into the interplay between their electronic structure and electrochemical environments, providing broader…

化学物理 · 物理学 2024-09-26 Yueqing Shi , Liya Bi , Zihao Wang , Kangkai Liang , Ji-Kun Li , Xiao-Ye Wang , Wan-Lu Li , Shaowei Li

Pairs of electrodes with nanometer separation (nano-gap) are achieved through an electromigration-induced break-junction (EIBJ) technique at room temperature. Lithographically defined gold (Au) wires are formed by e-beam evaporation over…

介观与纳米尺度物理 · 物理学 2007-05-23 Ajit K. Mahapatro , Subhasis Ghosh , David B. Janes

We report the fabrication and characteristics of GaAs/Si p+/n+ heterojunction tunnel diodes. These diodes were fabricated via grafting the freestanding single-crystalline p-type degenerately doped GaAs (4E19 cm-3) nanomembrane (NM) onto…

We report on a quantum dot device design that combines the low disorder properties of undoped SiGe heterostructure materials with an overlapping gate stack in which each electrostatic gate has a dominant and unique function -- control of…

A scanning tunneling microscope (STM) supplemented with a force sensor is used to study the mechanical properties of a novel metallic nanostructure: a freely suspended chain of single gold atoms. We find that the bond strength of the…

凝聚态物理 · 物理学 2009-11-07 G. Rubio-Bollinger , S. R. Bahn , N. Agrait , K. W. Jacobsen , S. Vieira