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TiO$_2$ and SrTiO$_3$ are well known materials in the field of photocatalysis due to their exceptional electronic structure, high chemical stability, non-toxicity and low cost. However, owing to the wide band gap, these can be utilized only…

材料科学 · 物理学 2020-09-25 Manish Kumar , Pooja Basera , Shikha Saini , Saswata Bhattacharya

The band gap of SrTiO$_{3}$ retards its photocatalytic application. Regardless narrowing the band gap of the anion doped SrTiO$_{3}$, the anion doping structures have low photoconversion efficiency. The co-cation dopings are used to modify…

材料科学 · 物理学 2015-10-27 M. M. Fadlallah , T. J. H. Vlugt , M. F. Shibl

Perovskite SrTiO3 (STO) is an attractive photocatalyst for solar water splitting, but suffers from a limited photoresponse in the ultraviolet spectral range due to its wide band gap. By means of hybrid density functional theory…

材料科学 · 物理学 2021-06-16 Y. S. Hou , S. Ardo , R. Q. Wu

Photoelectrochemical solar water splitting is a promising approach to convert solar energy into sustainable hydrogen fuel using semiconductor electrodes. Due to their visible light absorption properties, oxynitrides have shown to be…

SrTiO$_3$ is a highly efficient photocatalyst for the overall water splitting reaction under UV irradiation. However, an atomic-level understanding of the active surface sites responsible for the oxidation and reduction reactions is still…

The structural, electronic, and optical properties of metal (Si, Ge, Sn, and Pb) mono- and co-doped anatase TiO$_{2}$ nanotubes are investigated, in order to elucidate their potential for photocatalytic applications. It is found that Si…

介观与纳米尺度物理 · 物理学 2020-04-29 Mohamed M. Fadlallah , Ulrich Eckern

Noble metal cocatalysts are conventionally a crucial factor in oxide-semiconductor-based photocatalytic hydrogen generation. In the present work, we show that optimized high-temperature hydrogenation of commercially available strontium…

Strontium titanate (SrTiO3) is widely used as a promising photocatalyst due to its unique band edge alignment with respect to the oxidation and reduction potential corresponding to oxygen evolution reaction (OER) and hydrogen evolution…

We propose a novel excellent two-dimensional photocatalyst SnN3 monolayer using first-principles calculations. The stability of SnN3 monolayer have been examined via formation energy, phonon spectrum and ab initio molecular dynamics…

材料科学 · 物理学 2019-07-02 Shengyao Wu , Yanqing Shen , Xu Gao , Yanyan Ma , Zhongxiang Zhou

Molybdenum and nitrogen co-doped $TiO_2$ nanotube arrays (TNAs) were prepared by anodizing in association with hydrothermal treatment. As-prepared Mo and N co-doped TNAs were characterized by field emission scanning electron microscopy,…

材料科学 · 物理学 2014-01-06 Min Zhang , Juan Wu , Jian Hou , Jianjun Yang

Advanced theoretical investigations are crucial for understanding the structural growth mechanisms, optoelectronic properties, and photocatalytic activity of photoelectrodes for efficient photoelectrochemical water splitting. In this work,…

材料科学 · 物理学 2025-03-24 Abdul Ahad Mamun , Muhammad Anisuzzaman Talukder

Due to their characteristic geometry, TiO$_2$ nanotubes (TNTs), suitably doped by metal-substitution to enhance their photocatalytic properties, have a high potential for applications such as clean fuel production. In this context, we…

材料科学 · 物理学 2020-09-17 Mohamed M. Fadlallah , Ulrich Eckern

Photocatalytic water splitting represents a pivotal pathway for converting solar energy into chemical energy, with the core challenge lying in the design and optimization of photocatalysts [1] . TiO2, as a quintessential photocatalytic…

材料科学 · 物理学 2025-02-20 Zhihao Shen

By means of first-principles calculations within the density functional theory, we study the structural and optical properties of codoped ZnO nanowires and compare them with those of the bulk and film. It is disclosed that the low…

介观与纳米尺度物理 · 物理学 2012-02-27 Zhuo Xu , Qing-Rong Zheng , Gang Su

The photocatalytic production of hydrogen peroxide (H$_2$O$_2$) from water is a promising strategy for solar-to-chemical energy conversion. Herein, we investigate the effect of metal-free heteroatom doping (B, O, P, and S) on the…

Using density functional theory (DFT), we investigated the structural, electronic and optical properties of functionalized and doped MXenes such as M$_1$M$_2$CO$_2$ (M$_1$ = Zr,Hf; M$_2$ = Hf,Ti,Sc). This study aimed to find a suitable…

材料科学 · 物理学 2023-05-29 Sima Rastegar , Alireza Rastkar Ebrahimzadeh , Jaber Jahanbin Sardroodi

The electronic, thermal, magnetic and optical properties of BN-codoped strontium oxide (SrO) monolayers are studied taking into account the interaction effects between the B and the N dopant atoms. The indirect band gap of a pure two…

材料科学 · 物理学 2023-07-19 Nzar Rauf Abdullah , Hemn Gharib Hussein , Vidar Gudmundsson

Light element based two dimensional (2D) materials are promising photocatalysts for hydrogen production via water splitting. Boron oxide (BO) is a recently synthesized 2D monolayer which has yet to be thoroughly explored for its potential…

Mn-doped SrTiO_3.0, when synthesized free of impurities, is a paramagnetic insulator with interesting dielectric properties. Since delocalized charge carriers are known to promote ferromagnetism in a large number of systems via diverse…

材料科学 · 物理学 2013-10-08 D. Choudhury , B. Pal , A. Sharma , S. V. Bhat , D. D. Sarma

We report magnetotransport properties of photogenerated electrons in undoped SrTiO$_3$ single crystals under ultraviolet illumination down to 2 K. By tuning the light intensity, the steady state carrier density can be controlled, while…

强关联电子 · 物理学 2009-11-13 Y. Kozuka , Y. Hikita , T. Susaki , H. Y. Hwang
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