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Static correlation is a difficult problem for density-functional theory (DFT) as it arises in cases of degenerate or quasi-degenerate states where a multideterminantal wave function provides the simplest reasonable first approximation to…

化学物理 · 物理学 2024-01-01 Abraham Ponra , Carolyne Bakasa , Anne Justine Etindele , Mark E. Casida

Methods based on the combination of the usual density functional theory (DFT) codes with the Hubbard models are widely used to investigate the properties of strongly correlated materials. Using first-principle calculations we study the…

材料科学 · 物理学 2015-08-04 Christos Tsirogiannis , Iosif Galanakis

A Multi-Phase Transport (AMPT) model is used to investigate the efficacy of several flow observables to constrain the initial-state deformation of the Uranium nuclei in U$+$U collisions at nucleon-nucleon center-of-mass energy…

核理论 · 物理学 2024-03-04 Niseem Magdy

Physically reasonable electronic structures of reconstructed rutile TiO_2(110)-(1x2) surfaces were studied using density functional theory (DFT) supplemented with Hubbard U on-site Coulomb repulsion acting on the d electrons, so called as…

强关联电子 · 物理学 2016-08-14 Hatice Ünal , Ersen Mete , Şinasi Ellialtioğlu

A brief account of the zero temperature magnetic response of a system of strongly correlated electrons in strong magnetic field is given in terms of its quasiparticle properties. The scenario is based on the paramagnetic phase of the…

强关联电子 · 物理学 2009-11-13 Johannes Bauer

An efficient method for computing the Landauer-Buettiker conductance of an open quantum system within DFT+U is presented. The Hubbard potential is included in electronic structure and transport calculations as a simple renormalization of…

介观与纳米尺度物理 · 物理学 2013-02-14 Gabriele Sclauzero , Andrea Dal Corso

Multi-center transition metal complexes (MCTMs) with magnetically interacting ions have been proposed as components for information processing devices and storage units. For any practical application of MCTMs as magnetic units, it is…

化学物理 · 物理学 2023-04-03 Henry C. Fitzhugh , James W. Furness , Mark R. Pederson , Juan E. Peralta , Jianwei Sun

Approximate density functional theory (DFT) suffers from many-electron self- interaction error, otherwise known as delocalization error, that may be diagnosed and then corrected through elimination of the deviation from exact piecewise…

材料科学 · 物理学 2016-11-08 Terry Z. H. Gani , Heather J. Kulik

We formulate the on-site occupation dependent exchange correlation energy and effective potential of hybrid functionals for localized states and connect them to the on-site correction term of the DFT+U method. Our derivation provides a…

强关联电子 · 物理学 2015-05-22 Viktor Ivády , Rickard Armiento , Krisztián Szász , Erik Janzén , Adam Gali , Igor A. Abrikosov

Multipolar magnetic phases in correlated insulators represent a great challenge for Density Functional Theory (DFT) due to the coexistence of intermingled interactions, typically spin-orbit coupling, crystal field and complex non-collinear…

强关联电子 · 物理学 2022-07-27 Dario Fiore Mosca , Leonid V. Pourovskii , Cesare Franchini

We show that when a molecular junction is under an external bias, its properties can not be uniquely determined by the total electron density in the same manner as the density functional theory (DFT) for ground state (GS) properties. In…

介观与纳米尺度物理 · 物理学 2013-11-26 Shuanglong Liu , Yuan Ping Feng , Chun Zhang

Dynamical mean field theory (DMFT) combined with the local density approximation (LDA) is widely used in solids to predict properties of correlated systems. In this paper, its application to one of the simplest strongly correlated systems,…

强关联电子 · 物理学 2015-05-18 Juho Lee , Kristjan Haule

We present a generalization of the spin-fluctuation theory of magnetism which allows us to treat the full rotational invariance of the exchange interaction. The approach is formulated in terms of the local density approximation plus…

强关联电子 · 物理学 2012-09-26 V. I. Anisimov , A. S. Belozerov , A. I. Poteryaev , I. Leonov

Within the nuclear DFT framework, employing the Skyrme UNEDF1 functional and incorporating pairing correlations, we determined the spectroscopic electric quadrupole and magnetic dipole moments of the $\nu11/2^{-}$ and $\pi7/2^{+}$…

Electronic structure calculation of atoms and molecules, in the past few decades has largely been dominated by density functional methods. This is primarily due to the fact that this can account for electron correlation effects in a…

化学物理 · 物理学 2013-07-12 Amlan K. Roy

We propose a new method of calculating electronically excited states that combines a density functional theory (DFT) based ground state calculation with a linear response treatment that employs approximations used in the time-dependent…

化学物理 · 物理学 2016-05-11 Robert Rüger , Erik van Lenthe , Thomas Heine , Lucas Visscher

We examine the nature of the transition to the antiferromagnetically ordered state in the half-filled three-dimensional Hubbard model using the dual-fermion multiscale approach. Consistent with analytics, in the weak-coupling regime we find…

We calculated the magnetic dipole and the electric quadrupole hyperfine interaction constants of 3s3p $^{3,1}P^o_1$ states and the isotope shift, including mass and field shift, factors for transitions from these two states to the ground…

原子物理 · 物理学 2017-09-13 Tingxian Zhang , Luyou Xie , Jiguang Li , Zehuang Lu

The crucial step in density-corrected Hartree-Fock density functional theory (DC(HF)-DFT) is to decide whether the density produced by the density functional for a specific calculation is erroneous and hence should be replaced by, in this…

化学物理 · 物理学 2023-09-20 Daniel Graf , Alex J. W. Thom

This chapter presents the development of a density functional theory (DFT)-based method for accurate, reliable treatment of various resonances in atoms. Many of these are known to be notorious for their strong correlation, proximity to more…

化学物理 · 物理学 2019-04-19 Amlan K. Roy
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