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Exploration of new superconductors has always been one of the research directions in condensed matter physics. We report here a new layered heterostructure of [(Fe,Al)(OH)2][FeSe]1.2, which is synthesized by the hydrothermal ion-exchange…

Platelet-like single crystals of the Ca(Fe1-xCox)2As2 series having lateral dimensions up to 15 mm and thickness up to 0.5 mm were obtained from the high temperature solution growth technique using Sn flux. Upon Co doping, the c-axis of the…

Recent investigations of the superconducting iron-arsenide families have highlighted the role of pressure, be it chemical or mechanical, in fostering superconductivity. Here we report that CaFe2As2 undergoes a pressure-induced transition to…

Recent high-pressure studies found that superconductivity can be achieved under very low pressure in the parent iron arsenide compound CaFe2As2, although details of the sharpness and temperature of transitions vary between liquid medium and…

超导电性 · 物理学 2009-11-13 W. Yu , A. A. Aczel , T. J. Williams , S. L. Bud'ko , N. Ni , P. C. Canfield , G. M. Luke

The iron-based pnictide LaFe2As2 is not superconducting as-synthesized, but it becomes such below Tc around 12 K upon annealing, as a consequence of a structural transition from a phase with collapsed tetragonal crystal structure to an…

The single crystal of ThCr2Si2-type BaPd2As2 was successfully prepared by a self-flux method, and the crystal structure was characterized by X-ray diffraction method with the lattice parameters a = 4.489(2) {\AA} and c = 10.322(3) {\AA}.…

超导电性 · 物理学 2016-02-17 Qi Guo , Jia Yu , Bin-Bin Ruan , Dong-Yun Chen , Xiao-Chuan Wang , Qing-Ge Mu , Bo-Jin Pan , Gen-Fu Chen , Zhi-An Ren

To explore the origin of the unusual non-bulk superconductivity with a Tc up to 49 K reported in the rare-earth-doped CaFe2As2 , the chemical composition, magnetization, specific heat, resistivity, and annealing effect are systematically…

超导电性 · 物理学 2016-03-02 L. Z. Deng , B. Lv , K. Zhao , F. Y. Wei , Y. Y. Xue , Z. Wu , C. W. Chu

The temperature dependence of in plane optical conductivity has been investigated for Ca0.86Pr0.14Fe2As2 which shows a structural transition from tetragonal (T) to collapsed tetragonal(cT) phase at TcT=73 K. Upon entering the cT phase,…

超导电性 · 物理学 2015-06-17 Run Yang , Congcong Le , Lei Zhang , Bing Xu , Wei Zhang , Kashif Nadeem , Hong Xiao , Jiangping Hu , Xianggang Qiu

Recently, KFe$_2$As$_2$ was shown to exhibit a structural phase transition from a tetragonal to a collapsed tetragonal phase under applied pressure of about $15~\mathrm{GPa}$. Surprisingly, the collapsed tetragonal phase hosts a…

超导电性 · 物理学 2015-04-14 Daniel Guterding , Steffen Backes , Harald O. Jeschke , Roser Valenti

A new layered iron arsenide oxide (Fe2As2)(Ca4(Mg,Ti)3Oy) was discovered. Its crystal structure is tetragonal with a space group of I4/mmm consisted of the anti-fluorite type FeAs layer and blocking layer of triple perovskite cells and is…

Here we report the discovery of superconductivity in the ternary LaRu2As2 compound. The polycrystalline LaRu2As2 samples were synthesized by the conventional solid state reaction method. Powder X-ray diffraction analysis indicates that…

超导电性 · 物理学 2016-05-31 Qi Guo , Bo-Jin Pan , Jia Yu , Bin-Bin Ruan , Dong-Yun Chen , Xiao-Chuan Wang , Qing-Ge Mu , Gen-Fu Chen , Zhi-An Ren

Polycrystalline Eu0.5La0.5BiS2F was synthesized by solid state reaction which crystallizes in the tetragonal CeOBiS2 structure (P4/nmm). We report here enhancement of Tc to 2.2 K in Eu0.5La0.5BiS2F (by electron doping in EuBiS2F with Tc ~…

超导电性 · 物理学 2015-10-28 Gohil S. Thakur , Rajveer Jha , Zeba Haque , V. P. S. Awana , L. C. Gupta , A. K. Ganguli

The discovery of a new family of high Tc materials, the iron arsenides (FeAs), has led to a resurgence of interest in superconductivity. Several important traits of these materials are now apparent, for example, layers of iron tetrahedrally…

Here we report the synthesis and discovery of superconductivity in a novel ternary iridium-arsenide compound BaIr2As2. The polycrystalline BaIr2As2 sample was synthesized by a high temperature and high pressure method. Crystal structural…

超导电性 · 物理学 2017-08-22 Xiao-Chuan Wang , Bin-Bin Ruan , Jia Yu , Bo-Jin Pan , Qing-Ge Mu , Tong Liu , Gen-Fu Chen , Zhi-An Ren

Superconductivity was achieved in Ti-doped iron-arsenide compound Sr4Cr0.8Ti1.2O6Fe2As2 (abbreviated as Cr-FeAs-42622). The x-ray diffraction measurement shows that this material has a layered structure with the space group of…

超导电性 · 物理学 2015-05-13 Xiyu Zhu , Fei Han , Gang Mu , Peng Cheng , Bing Shen , Bin Zeng , Hai-Hu Wen

The finding of superconductivity in Ba0.6K0.4Fe2As2 put the attention on the investigation of compounds that crystallize with ThCr2Si2 structure type such as AT2X2 (A = alkali/ alkaline earth/ rare earth element; T = transition metal and X…

超导电性 · 物理学 2012-12-10 Andrea V. Hoffmann , Viktor Hlukhyy , Thomas F. Fässler

Fe-based superconductors exhibit a diverse interplay between charge, orbital, and magnetic ordering1-4. Variations in atomic geometry affect electron hopping between Fe atoms5,6 and the Fermi surface topology, influencing magnetic…

Single crystals of Tl0.58Rb0.42Fe1.72Se2 are successfully grown with the superconducting transition temperatures Tconset=32K and Tczero=31.4K. The Hall coefficient exhibits a multi-band behavior, which is very similar to that of all other…

超导电性 · 物理学 2011-02-21 Hangdong Wang , Chihen Dong , Zujuan Li , Shasha Zhu , Qianhui Mao , Chunmu Feng , H. Q. Yuan , Minghu Fang

Single crystals of SrFe2As2 grown using a self-flux solution method were characterized via x-ray, transport and magnetization studies, revealing a superconducting phase below T_c = 21 K characterized by a full electrical resistivity…

超导电性 · 物理学 2009-07-21 S. R. Saha , N. P. Butch , K. Kirshenbaum , J. Paglione

We report the observation of the pressure-induced, fully-collapsed tetragonal phase of CaRbFe4As4 for P~ 22 GPa via high-pressure x-ray diffraction and magnetotransport measurements. The x-ray measurements, along with resistivity…