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We show that strong coupling between graphene and the substrate is mitigated when 0.8 monolayer of Na is adsorbed and consolidated on top graphene-on-Ni(111). Specifically, the {\pi} state is partially restored near the K-point and the…

We show using scanning tunneling microscopy, spectroscopy, and ab initio calculations that several intercalation structures exist for Na in epitaxial graphene on SiC(0001). Intercalation takes place at room temperature and Na electron-dopes…

介观与纳米尺度物理 · 物理学 2011-12-01 Andreas Sandin , Thushari Jayasekera , J. E. , Rowe , Ki Wook Kim , M. Buongiorno Nardelli , Daniel B. Dougherty

We perform a density functional theory study of the effects of oxygen adsorption on the structural and electronic properties of Gr/Co(0001) and Gr/Co/Ir(111) interfaces. In both interfaces, the graphene-Co distance increases with increasing…

材料科学 · 物理学 2022-08-05 Dario A. Leon , Andrea Ferretti , Daniele Varsano , Elisa Molinari , Claudia Cardoso

Graphene is a fascinating 2D material that is being widely investigated for use in electronic devices due to its unique electronic and materials properties. Also, because of its high thermal stability and inertness, it is considered a…

介观与纳米尺度物理 · 物理学 2017-10-25 Tianbai Li , Jory A. Yarmoff

Graphene stands as a promising material with vast potential across energy storage, electronics, etc. Here, we present a novel mechanical approach utilizing ultrasonic high-energy intercalation exfoliation to extract monolayer graphene from…

材料科学 · 物理学 2025-01-15 Kaitong Sun , Si Wu , Junchao Xia , Yinghao Zhu , Guanping Xu , Hai-Feng Li

The process of anion intercalation in graphite and its reversibility plays a crucial role in the next generation energy-storage devices. Herein the reaction mechanism of the aluminum graphite dual ion cell by operando X-ray scattering from…

Understanding the interactions of ambient molecules with graphene and adjacent dielectrics is of fundamental importance for a range of graphene-based devices, particularly sensors, where such interactions could influence the operation of…

介观与纳米尺度物理 · 物理学 2015-11-30 Eric J. Olson , Rui Ma , Tao Sun , Mona A. Ebrish , Nazila Haratipour , Kyoungmin Min , Narayana R. Aluru , Steven J. Koester

Graphite is a ubiquitous electrode material with particular promise for use in e.g., energy storage and desalination devices, but very little is known about the properties of the graphite-electrolyte double layer at technologically relevant…

材料科学 · 物理学 2021-09-03 Aaron R. Finney , Ian J. McPherson , Patrick R. Unwin , Matteo Salvalaglio

Electronic decoupling of graphene from metallic and semiconducting substrates via intercalation of different species is one of the widely used approaches in studies of graphene. In the present work the modification of the electronic and…

材料科学 · 物理学 2021-12-24 Yong Zhou , Roman Ovcharenko , Beate Paulus , Yuriy Dedkov , Elena Voloshina

The interaction of metals with carbon materials, specifically with graphene, is of importance for various technological applications. In particular, intercalation of alkali metals is believed to provide a means for tuning the electronic…

介观与纳米尺度物理 · 物理学 2023-01-26 Marianna Lorenzo , Conrad Escher , Tatiana Latychevskaia , Hans-Werner Fink

Graphene flakes were produced by nanosecond plasma discharge at atmospheric pressure between an electrode and the surface of distilled water, in which were placed graphite flakes. The discharge ionizes the gas and forms free radicals on the…

Magnesium intercalated 'quasi-freestanding' bilayer graphene on 6H-SiC(0001) (Mg-QFSBLG) has many favorable properties (e.g., highly n-type doped, relatively stable in ambient conditions). However, intercalation of Mg underneath monolayer…

Graphene intercalation materials are potentially promising for the implementation of the ultra-low power, excitonic-condensate-based Bilayer pseudoSpin Field-Effect Transistor (BiSFET) concept, as well as other novel device concepts…

介观与纳米尺度物理 · 物理学 2013-08-13 Priyamvada Jadaun , Hema C. P. Movva , Leonard F. Register , Sanjay K. Banerjee

Atomically precise graphene nanoribbons (GNRs) have a wide range of electronic properties that depend sensitively on their chemical structure. Several types of GNRs have been synthesized on metal surfaces through selective surface-catalyzed…

Metal contacts are fundamental building components for graphene based electronic devices and their properties are greatly influenced by interface quality during device fabrication, leading to resistance variation. Here we show that nickel…

化学物理 · 物理学 2016-01-28 Zhenjun Zhang , Fan Yang , Pratik Agnihotri , Ji Ung Lee , Jim R. Lloyd

The covalent functionalization of graphene represents a main topic in the growing field of nano materials. The reductive exfoliation of graphite with concomitant functionalization of the respective graphenide intermediates provides a…

化学物理 · 物理学 2018-05-31 Philipp Vecera , Konstantin Edelthalhammer , Frank Hauke , Andreas Hirsch

Intercalation of rare earth metals ($RE$ = Eu, Dy, and Gd) is achieved by depositing the $RE$ metal on graphene that is grown on silicon-carbide (SiC) and by subsequent annealing at high temperatures to promote intercalation. STM images of…

介观与纳米尺度物理 · 物理学 2018-11-16 Nathaniel A. Anderson , Myron Hupalo , David Keavney , Michael Tringides , David Vaknin

The cointercalation of sodium with the solvent organic molecule into graphite can resolve difficulty of forming the stage-I Na-graphite intercalation compound, which is a predominant anode of Na-ion battery. To clarify the mechanism of such…

材料科学 · 物理学 2017-09-26 Chol-Jun Yu , Song-Bok Ri , Song-Hyok Choe , Gum-Chol Ri , Yun-Hyok Kye , Sung-Chol Kim

Graphene and few-layer graphene at high bias expose a wealth of phenomena due to the high temperatures reached. With in-situ transmission electron microscopy (TEM) we observe directly how the current modifies the structure, and vice versa.…

介观与纳米尺度物理 · 物理学 2013-01-30 Amelia Barreiro , Felix Boerrnert , Mark H. Ruemmeli , Bernd Buechner , Lieven M. K. Vandersypen

Intrinsic layered structure of graphite is the source of ongoing and expanding search of ways of obtaining low-cost and promising graphite thin layers. We report on a novel method of obtaining and separating rubbed graphite sheets by using…

材料科学 · 物理学 2015-06-23 Manuel R. Mailian , Aram R. Mailian
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