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We present high-accuracy correlated calculations of small Si$_x$H$_y$ molecular systems both in the ground and excited states. We employ quantum Monte Carlo (QMC) together with a variety of many-body wave function approaches based on basis…

化学物理 · 物理学 2020-10-21 Guangming Wang , Abdulgani Annaberdiyev , Lubos Mitas

Here the recently proposed time-dependent quantum Monte Carlo method is applied to three dimensional para- and ortho-helium atoms subjected to an external electromagnetic field with amplitude sufficient to cause significant ionization. By…

原子物理 · 物理学 2025-02-05 Ivan P. Christov

An implementation of the coupled-cluster single- and double excitations (CCSD) method on two-dimensional quantum dots is presented. Advantages and limitations are studied through comparison with other high accuracy approaches for two to…

介观与纳米尺度物理 · 物理学 2013-05-30 Erik Waltersson , Eva Lindroth

We present a variational MonteCarlo (VMC) and lattice regularized diffusion MonteCarlo (LRDMC) study of the binding energy and dispersion curve of the water dimer. As a variation ansatz we use the JAGP wave function, an implementation of…

化学物理 · 物理学 2008-06-26 Fabio Sterpone , Leonardo Spanu , Luca Ferraro , Sandro Sorella , Leonardo Guidoni

The properties of hydrogen under extreme conditions are important for many applications, including inertial confinement fusion and astrophysical models. A key quantity is given by the electronic density response to an external perturbation,…

计算物理 · 物理学 2022-08-17 Maximilian Böhme , Zhandos Moldabekov , Jan Vorberger , Tobias Dornheim

The methodology based on the association of the Variational Method with Supersymmetric Quantum Mechanics is used to evaluate the energy states of the confined hydrogen atom.

高能物理 - 理论 · 物理学 2015-06-26 Elso Drigo Filho , Regina Maria Ricotta

The diffusion Monte Carlo method is applied to describe a trapped atomic Bose-Einstein condensate at zero temperature, fully quantum mechanically and nonperturbatively. For low densities, $n(0)a^3 \le 2 \cdot 10^{-3}$ [n(0): peak density,…

凝聚态物理 · 物理学 2009-10-31 D. Blume , Chris H. Greene

Previous works have controversially claimed near-room temperature ferromagnetism in two-dimensional (2D) VSe$_2$, with conflicting results throughout the literature. These discrepancies in magnetic properties between both phases (T and H…

强关联电子 · 物理学 2023-07-28 Daniel Wines , Juha Tiihonen , Kayahan Saritas , Jaron Krogel , Can Ataca

The Dirac equation is used to provide a relativistic calculation of the binding energy of a hydrogen-like atom confined within a penetrable spherical barrier. We take the potential to be Coulombic within the barrier and constant outside the…

原子物理 · 物理学 2023-02-08 J. M. Noon

We report results of both Diffusion Quantum Monte Carlo(DMC) method and Reptation Quantum Monte Carlo(RMC) method on the potential energy curve of the helium dimer. We show that it is possible to obtain a highly accurate description of the…

化学物理 · 物理学 2015-05-18 Xuebin Wu , Xianru Hu , Chenlei Du , Yunchuan Dai , Shibin Chu , Leibo Hu , Jianbo Deng , Yuanping Feng

We report a numerical study of the equation of state of crystalline body-centered-cubic (BCC) hydrogen, tackled with a variety of complementary many-body wave function methods. These include continuum stochastic techniques of fixed-node…

材料科学 · 物理学 2020-11-25 Sam Azadi , George H. Booth , Thomas D. Kühne

The small magnitude and long-range character of non-covalent interactions pose a significant challenge for computational quantum chemical and electronic-structure methods alike. State-of-the-art coupled cluster (CC) theory and…

化学物理 · 物理学 2026-01-22 S. Lambie , P. López-Ríos , D. Kats , Ali Alavi

We have used diffusion Monte Carlo (DMC) calculations to study the structural properties of magnesium hydride (MgH$_2$), including the pressure-volume equation of state, the cohesive energy and the enthalpy of formation from magnesium bulk…

材料科学 · 物理学 2009-11-13 M. Pozzo , D. Alfè

We have used the variational and diffusion quantum Monte Carlo methods to calculate the energy, pair correlation function, static structure factor, and momentum density of the ground state of the two-dimensional homogeneous electron gas. We…

介观与纳米尺度物理 · 物理学 2010-03-02 N. D. Drummond , R. J. Needs

We employ machine learning techniques to provide accurate variational wavefunctions for matrix quantum mechanics, with multiple bosonic and fermionic matrices. Variational quantum Monte Carlo is implemented with deep generative flows to…

高能物理 - 理论 · 物理学 2020-04-01 Xizhi Han , Sean A. Hartnoll

We consider a quantum system coupled to a dissipative background with many degrees of freedom using the Monte Carlo Wave Function method. Instead of dealing with a density matrix which can be very high-dimensional, the method consists of…

量子物理 · 物理学 2009-11-07 S. C. Badescu , S. C. Ying , T. Ala-Nissila

The diffusion quantum Monte Carlo method is extended to solve the old theoretical physics problem of many-electron atoms and ions in intense magnetic fields. The feature of our approach is the use of adiabatic approximation wave functions…

量子物理 · 物理学 2009-11-13 S. Bucheler , D. Engel , J. Main , G. Wunner

Quantum Monte Carlo methods are used to study a quantum phase transition in a 1D Hubbard model with a staggered ionic potential (D). Using recently formulated methods, the electronic polarization and localization are determined directly…

强关联电子 · 物理学 2009-10-31 Tim Wilkens , Richard M. Martin

We explore correlated electron states in harmonically confined few-electron quantum dots in an external magnetic field by the path-integral Monte Carlo method for a wide range of the field and the Coulomb interaction strength. Using the…

强关联电子 · 物理学 2020-01-07 Csaba Tőke , Tamás Haidekker Galambos

We studied the hydrogen atom as a system of two quantum particles in different confinement conditions; a spherical-impenetrable-wall cavity and a fullerene molecule cage. The motion is referred to the center of spherical cavities, and the…

原子与分子团簇 · 物理学 2016-12-21 Juan M. Randazzo , Carlos A. Rios