相关论文: Evolution of CTAB/NaSal Micelles: Structural Analy…

Several surfactant molecules self-assemble in solution to form long, cylindrical, flexible wormlike micelles. These micelles can be entangled with each other leading to viscoelastic phases. The rheological properties of such phases are very…

We report the flow dynamics of two shear-banding wormlike micellar solutions with distinct surfactant chemistries in a Taylor-Couette (TC) setup following a startup shear. The solutions, formulated with CTAB/NaSal and CPyCl/NaSal, exhibit…

Micelle formation in binary mixtures of surfactants is studied using a coarse-grained molecular simulation. When a vesicle composed of lipid and detergent types of molecules is ruptured, a disk-shaped micelle, the bicelle, is typically…

We report our studies of the linear and nonlinear rheology of aqueous solutions of the surfactant cetyl trimethylammonium tosylate (CTAT) with varying amounts of sodium chloride (NaCl). The CTAT concentration is fixed at 42mM and the salt…

We present the first molecular dynamics study to probe the mechanisms of anomalous diffusion in cationic surfactant micelles in the presence of explicit salt and solvent-mediated interactions. Simulations show that when the counter ion…

In this work, we use flow visualization and rheometry techniques to study the dynamics and evolution of secondary flows in a model wormlike micellar solution sheared between concentric cylinders, i.e., in a Taylor-Couette (TC) cell. The…

The effect of salt concentration Cs on the critical shear rate required for the onset of shear thickening and apparent relaxation time of the shear-thickened phase, has been investigated systematically for dilute CTAB/NaSal solutions.…

It is shown that structuring at the microlevel, a previously not described in detail phenomenon, is the intrinsic property of water and aqueous solutions. At room conditions water (including "ultrapure" one) and aqueous solutions are…

Hypotheses: The aggregation number and length of spherocylindrical (rodlike, wormlike) micelles in solutions of an ionic surfactant and salt can be predicted knowing the molecular parameters and the input concentrations of the species. This…

We investigate the morphology and energetics of a self-associating model cationic surfactant in water using coarse-grained molecular dynamics simulations. We develop an algorithm to track micelles contours and quantify various…

The micellization process of the aqueous mixed system Triton X-100 (TX100)-Dodecyltrimethylammonium Bromide (DTAB) was studied with a battery of procedures: surface tension, static and dynamic light scattering and ion-selective electrodes.…

In this review, we report recent developments on the shear-induced transitions and instabilities found in surfactant wormlike micelles. The survey focuses on the non-linear shear rheology and covers a broad range of surfactant…

The formation of self assembled structures such as micelles has been intensively studied and is well understood. The ability of a solution of amphiphilic molecules to develop micelles is depending on the concentration and characterized by…

Velocity profiles in a wormlike micelle solution (CTAB in D2O) are recorded using ultrasound every 2 s after a step-like shear rate into the shear-banding regime. The stress relaxation occurs over more than six hours and corresponds to the…

Complex fluids such as emulsions, colloidal gels, polymer or surfactant solutions are all characterized by the existence of a "microstructure" which may couple to an external flow on timescales that are easily probed in experiments. Such a…

Previous observations of the nontransient oscillations of rising bubbles and falling spheres in wormlike micellar fluids were limited to a single surfactant system. We present an extensive survey of rising bubbles in another system, an…

The interplay between shear band (SB) formation and boundary conditions (BC) is investigated in wormlike micellar systems (CPyCl--NaSal) using ultrasonic velocimetry coupled to standard rheology in Couette geometry. Time-resolved velocity…

Many surfactant-based formulations are utilised in industry as they produce desirable visco-elastic properties at low-concentrations. These properties are due to the presence of worm-like micelles (WLM) and, as a result, understanding the…

Chemical surfactants are omnipresent in consumers' products but they suffer from environmental concerns. For this reason, complete replacement of petrochemical surfactants by biosurfactants constitute a holy grail but this is far from…

Shear-flow-induced structure formation in surfactant-water mixtures is investigated numerically using a meshless-membrane model in combination with a particle-based hydrodynamics simulation approach for the solvent. At low shear rates,…