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Ambipolar charge carrier transport in Copper phthalocyanine (CuPc) is studied experimentally in field-effect transistors and metal-insulator-semiconductor diodes at various temperatures. The electronic structure and the transport properties…

介观与纳米尺度物理 · 物理学 2015-03-13 C. Schuster , M. Kraus , A. Opitz , W. Brütting , U. Eckern

Well-ordered organic molecular layers on oxide surfaces are key for organic electronics. Using a combination of scanning tunneling microscopy (STM) and non-contact atomic force microscopy (nc-AFM) we probe the structures of copper…

We study an impurity Anderson model to describe an iron phthalocyanine (FePc) molecule on Au(111), motivated by previous results of scanning tunneling spectroscopy (STS) and theoretical studies. The model hybridizes a spin doublet…

强关联电子 · 物理学 2018-09-13 J. Fernández , P. Roura-Bas , A. Camjayi , A. A. Aligia

The adsorption geometry of perfluorinated copper-phthalocyanine molecules (F_{16}CuPc) on Cu(111) and Ag(111) is studied using X-ray standing waves. A detailed, element-specific analysis taking into account non-dipolar corrections to the…

软凝聚态物质 · 物理学 2009-11-11 A. Gerlach , F. Schreiber , S. Sellner , H. Dosch , I. A. Vartanyants , B. C. C. Cowie , T. -L. Lee , J. Zegenhagen

We present a systematic investigation of molecule-metal interactions for transition-metal phthalocyanines (TMPc, with TM = Fe, Co, Ni, Cu) adsorbed on Ag(100). Scanning tunneling spectroscopy and density functional theory provide insight…

材料科学 · 物理学 2012-04-20 A. Mugarza , R. Robles , C. Krull , R. Korytar , N. Lorente , P. Gambardella

The interface formation between copper phthalocyanine (CuPc) and two representative metal substrates, i.e., Au and Co, was investigated by the combination of ultraviolet photoelectron spectroscopy and inverse photoelectron spectroscopy. The…

The Kondo effect observed in recent STM experiments on transport through CoPc and TBrPP-Co molecules adsorbed on Au(111) and Cu(111) surfaces, respectively, is discussed within the framework of a simple model (Phys. Rev. Lett. {\bf 97},…

强关联电子 · 物理学 2009-11-13 J. M. Aguiar-Hualde , G. Chiappe , E. Louis , E. V. Anda

The system of an iron phthalocyanine molecule on the Au(111) surface, has been studied recently due to its peculiar properties. In particular, several surprising results of scanning tunneling spectroscopy changing the position of the…

强关联电子 · 物理学 2022-05-19 A. A. Aligia

A recent experimental study showed that, distorting a CoPc molecule adsorbed on a Au(111) surface, a Kondo effect is induced with a temperature higher than 200 K. We examine a model in which an atom with strong Coulomb repulsion (Co) is…

强关联电子 · 物理学 2009-11-11 G. Chiappe , E. Louis

Indium oxide offers optical transparency paired with electric conductivity, a combination required in many optoelectronic applications. The most-stable In2O3(111) surface has a large unit cell (1.43 nm lattice constant). It contains a…

We present the growth morphology, the long range ordering, and the evolution of the valence band electronic states of ultra-thin films of copper phthalocyanine (CuPc) deposited on the Au(110)-(1x2) reconstructed surface, as a function of…

材料科学 · 物理学 2009-11-10 F. Evangelista , A. Ruocco , V. Corradini , M. P. Donzello , C. Mariani , M. G. Betti

We present a systematic density functional theory study of the electronic structure of copper phthalocyanine (CuPc), using several different (semi)-local and hybrid functionals, and compare the results to experimental photoemission data. We…

材料科学 · 物理学 2009-11-13 Noa Marom , Oded Hod , Gustavo E. Scuseria , Leeor Kronik

We study theoretically a square lattice of the organometallic Kondo adsorbate iron(II) phtalocyanine (FePc) deposited on top of Au(111), motivated by recent scanning tunneling microscopy experiments. We describe the system by means of an…

强关联电子 · 物理学 2015-02-23 J. Fernández , A. A. Aligia , Alejandro M. Lobos

Electrical and thermal transport properties of C60 molecules are investigated with density-functional-theory based calculations. These calculations suggest that the optimum contact geometry for an electrode terminated with a single-Au atom…

介观与纳米尺度物理 · 物理学 2015-06-05 G. Géranton , C. Seiler , A. Bagrets , L. Venkataraman , F. Evers

The interplay of exchange correlations and spin-orbit interaction (SOI) on the many-body spectrum of a copper phtalocyanine (CuPc) molecule and their signatures in transport are investigated. We first derive a minimal model Hamiltonian in a…

介观与纳米尺度物理 · 物理学 2015-08-20 Benjamin Siegert , Andrea Donarini , Milena Grifoni

We present a computational method to quantitatively describe the linear-response conductance of nanoscale devices in the Kondo regime. This method relies on a projection scheme to extract an Anderson impurity model from the results of…

介观与纳米尺度物理 · 物理学 2017-04-05 Andrea Droghetti , Ivan Rungger

The electronic transport properties of a point-contact system formed by a single Co atom adsorbed on Cu (100) and contacted by a copper tip is evaluated in the presence of intra-atomic Coulomb interactions and spin-orbit coupling. The…

介观与纳米尺度物理 · 物理学 2017-08-16 C. García Fernández , P. Abufager , N. Lorente

The spectroscopic characteristics of systems with adsorbed d impurities on noble metal surfaces should depend on the number and geometric arrangement of the adsorbed atoms and also on their d band filling. Recent experiments using scanning…

材料科学 · 物理学 2009-10-31 M. Weissmann , A. M. Llois

The studies of electronic and magnetic properties of V-Pc molecule adsorbed onto Au(111) surface are based on ab-initio calculations in the framework of density functional theory. We compute adsorption energies, investigate interaction…

材料科学 · 物理学 2021-03-30 Manel Mabrouk , Jacek A. Majewski

The paradigm of Landau's Fermi liquid theory has been challenged with the finding of a strongly interacting Fermi liquid that cannot be adiabatically connected to a non-interacting system. A spin-1 two-channel Kondo impurity with anisotropy…

强关联电子 · 物理学 2021-11-17 R. Žitko , G. G. Blesio , L. O. Manuel , A. A. Aligia
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