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Being able to predict and tune the colloidal stability of nanoparticles is essential for a wide range of applications, yet our ability to do so is currently poor due to a lack of understanding of how they interact with one another. Here, we…

软凝聚态物质 · 物理学 2018-08-30 Thomas Kister , Debora Monego , Paul Mulvaney , Asaph Widmer-Cooper , Tobias Kraus

Enhancing the transport of oxygen anions in the cathode while maintaining surface stability is essential for improving the performance of intermediate-temperature solid oxide fuel cells (IT-SOFCs). This study investigates a novel cathode…

材料科学 · 物理学 2025-03-04 Jyotsana Kalaa , Vicky Dhongde , Suddhasatwa Basu , Brajesh Kumar Mani , M. Ali Haider

MOF/polymer composites have been widely investigated in the past decade for gas separation applications. However, the impact of MOF nanoparticle morphology and size in gas separation have not yet been systematically studied by computer…

化学物理 · 物理学 2025-08-07 Cecilia M. S. Alvares , Rocio Semino

The biggest challenge for the commercialization of layered structured nickel rich lithium transition metal oxide cathode is the capacity and voltage fading. Resolving this problem over the years follows an incremental progress. In this…

材料科学 · 物理学 2017-10-18 Pengfei Yan , Jianming Zheng , Jian Liu , Biqiong Wang , Xueliang Sun , Chongmin Wang , Ji-Guang Zhang

One pot synthetic technique was used to synthesize mesoporous fullerene using highly ordered mesoporous template such as KIT6-150 and SBA-15-150. Highly ordered porous fullerene with cross linkage between the fullerene molecules was…

材料科学 · 物理学 2015-03-12 Sujit K. Mondal

The molecular dynamics method, based on an empirical potential energy surface, was used to study the effect of catalyst particle size on the growth mechanism and structure of single-walled carbon nanotubes (SWNTs). The temperature for…

材料科学 · 物理学 2009-11-11 Feng Ding , Arne Rosen , Kim Bolton

Uncovering microstructure evolution mechanisms that accompany the long-term operation of solid oxide fuel cells is a fundamental challenge in designing a more durable energy system for the future. To date, the study of fuel cell stack…

材料科学 · 物理学 2023-03-24 Piotr Pawłowski , Szymon Buchaniec , Tomasz Prokop , Hiroshi Iwai , Grzegorz Brus

This work describes the ethanol oxidation reaction (EOR) in alkaline medium using low-palladium nanoparticle electrocatalysts modified by Fe3O4 nano-octahedra and SnO2 nanorods. Operation studies on an alkaline direct ethanol fuel cell…

An extremely efficient ethanol fuel cell electrode is produced by combining the large surface area of vertically oriented and highly conductive few-layer graphene sheets with electrochemically deposited palladium nanoparticles. The…

化学物理 · 物理学 2016-10-18 Michael Höltig , Charlotte Ruhmlieb , Tobias Kipp , Alf Mews

This study presents a comprehensive computational investigation of magnetite nanoparticles, systematically evaluating a range of force fields against experimental results. We analyze the influence of particle size, temperature, and…

Controlled assembly of single-crystal, colloidal maghemite nanoparticles is facilitated via a high-temperature polyol-based pathway. Structural characterization shows that size-tunable nanoclusters of 50 and 86 nm diameters (D), with high…

The electrostatic charge density of particles is of paramount importance for the control of the dispersion stability. Conventional methods use potentiometric, conductometric or turbidity titration but require large amount of samples. Here…

材料科学 · 物理学 2021-09-21 F. Mousseau , L. Vitorazi , L. Herrmann , S. Mornet , J. -F. Berret

In this study we report the effect of sintering temperature on the low field magnetotransport properties of La_0.7Ca_0.3Mn_O3 manganite synthesized through polymeric precursor route. The La_0.7Ca_0.3MnO_3 has been sintered at 600^oC (S6),…

材料科学 · 物理学 2007-05-23 U. K. Goutam , P. K. Siwach , H. K. Singh , R. S. Tiwari , O. N. Srivastava

We evaluated for the first time the use of nanostructured layered perovskites of formulae LnBaCo2O6-d with Ln = Sm and Gd (SBCO and GBCO, respetively) as SOFC cathodes, finding promising electrochemical properties in the intermediate…

Based on the method of compact groups of inhomogeneities, we formulate new mixing rules for suspensions of charged insulating particles. They express the quasistatic conductivity and permittivity of a suspension in terms of the effective…

软凝聚态物质 · 物理学 2017-07-18 M. Ya. Sushko , V. Ya. Gotsulskiy , M. V. Stiranets

A new method based on the combination of small-anglescattering, reverse Monte Carlo simulations, and an aggregate recognition algorithm is proposed to characterize the structure of nanoparticle suspensions in solvents and polymer…

The fascinating phenomenon of destabilization of charge/orbital order in Nd0.5Sr0.5MnO3 with the reduction of grain size is critically investigated. Based on our magnetic and transport experiments followed by a theoretical analysis, we…

强关联电子 · 物理学 2010-06-16 S. Kundu , T. K. Nath , A. K. Nigam , T. Maitra , A. Taraphder

La$_2$NiO$_4$ is a very promising cathode material for intermediate and low temperature solid oxide cell applications, due to its good electronic and ionic conductivity, together with its high oxygen exchange activity with a low activation…

A novel 3-electrode cell type is introduced to run parametrical studies of H$_2$ evolution in an alkaline electrolyte on porous electrodes. Electrochemical methods combined with a high-speed optical measurement system are applied…

Fundamental knowledge of scattering in granular compacts is essential to ensure accuracy of spectroscopic measurements and determine material characteristics such as size and shape of scattering objects. Terahertz time-domain spectroscopy…

光学 · 物理学 2023-04-24 Keir N Murphy , Mira Naftaly , Alison Nordon , Daniel Markl