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This thesis looks at the electronic energy transfer in the Fenna-Matthews-Olson complex, in which evidence of long-lived coherence has been observed in 2-dimensional infrared experiments. I use three techniques: the numerically exact…

化学物理 · 物理学 2015-03-12 David M. Wilkins

A remarkable amount of theoretical research has been carried out to elucidate the physical origins of the recently observed long-lived quantum coherence in the electronic energy transfer process in biological photosynthetic systems.…

量子物理 · 物理学 2015-03-19 Sangwoo Shim , Patrick Rebentrost , Stéphanie Valleau , Alan Aspuru-Guzik

Based on quantum thermodynamic processes, we make a quantum-mechanical (QM) extension of the typical heat engine cycles, such as the Carnot, Brayton, Otto, and Diesel cycles, etc. The temperature is not included in these QM engine cycles,…

统计力学 · 物理学 2013-02-05 Jianhui Wang , Yongli Ma , Jizhou He

A linear chain of connected electron sites with two asymmetric sinks, one attached to each end, is used as a simple model of quantum electron transfer in photosynthetic bio-complexes. For a symmetric initial population in the middle of the…

量子物理 · 物理学 2014-03-31 D. Ferrari , G. L. Celardo , G. P. Berman , R. T. Sayre , F. Borgonovi

Quantum thermodynamics aims at investigating both the emergence and the limits of the laws of thermodynamics from a quantum mechanical microscopic approach. In this scenario, thermodynamic processes with no heat exchange, namely, adiabatic…

We study a quantum thermal engine model for which the heat transfer law is determined by Einstein's theory of radiation. The working substance of the quantum engine is assumed to be a two-level quantum systems of which the constituent…

统计力学 · 物理学 2012-11-30 H. Yan , Hao Guo

Within quantum thermodynamics, many tasks are modelled by processes that require work sources represented by out-of-equilibrium quantum systems, often dubbed quantum batteries, in which work can be deposited or from which work can be…

量子物理 · 物理学 2024-01-26 Pharnam Bakhshinezhad , Beniamin R. Jablonski , Felix C. Binder , Nicolai Friis

We examine a simple model of proton pumping through the inner membrane of mitochondria in the living cell. We demonstrate that the pumping process can be described using approaches of condensed matter physics. In the framework of this…

介观与纳米尺度物理 · 物理学 2009-11-13 Anatoly Yu. Smirnov , Lev G. Mourokh , Franco Nori

We investigate the quantum thermodynamic cycle of a quantum heat engine carrying out an Otto thermodynamic cycle. We use the thermal properties of a moving heat bath with relativistic velocity with respect to the cold bath. As a working…

量子物理 · 物理学 2021-10-25 Nikolaos Papadatos

Biological electron transfer (ET) relies on quantum mechanical tunnelling through a dynamically folded protein. Yet, the spatiotemporal coupling between structural fluctuations and electron flux remains poorly understood, largely due to…

All living cells transport molecules and ions across membranes, often against concentration gradients. This active transport requires continual energy expenditure and is clearly a nonequilibrium process for which standard equilibrium…

亚细胞过程 · 定量生物学 2007-05-23 Robert W. Finkel

We present a quantum algorithm based on the Tensor-Train Thermo-Field Dynamics (TT-TFD) method to simulate the open quantum system dynamics of intramolecular charge transfer modulated by an optical cavity on noisy intermediate-scale quantum…

化学物理 · 物理学 2024-04-16 Ningyi Lyu , Pouya Khazaei , Eitan Geva , Victor S. Batista

Recently, several works have analysed the efficiency of photosynthetic complexes in a transient scenario and how that efficiency is affected by environmental noise. Here, following a quantum master equation approach, we study the energy and…

生物大分子 · 定量生物学 2013-02-28 Daniel Manzano

An accurate description of electron transport at a molecular level requires a precise treatment of quantum effects. These effects play a crucial role in determining the electron transport properties of single molecules, such as…

量子物理 · 物理学 2020-12-18 Soran Jahangiri , Juan Miguel Arrazola , Alain Delgado

A generic and intuitive model for coherent energy transport in multiple minima systems coupled to a quantum mechanical bath is shown. Using a simple spin-boson system, we illustrate how a generic donor-acceptor system can be brought into…

生物物理 · 物理学 2014-06-24 Tristan Farrow , Vlatko Vedral

In this work we theoretically study properties of electric current driven by a temperature gradient through a quantum dot/molecule coupled to the source and drain charge reservoirs. We analyze the effect of Coulomb interactions between…

介观与纳米尺度物理 · 物理学 2015-12-01 Natalya A. Zimbovskaya

Non-equilibrium transport properties and energy conversion performance of a molecular photo-voltaic cell are analyzed using the Lindblad master equation within the open quantum systems approach. The method allows us to calculate the…

介观与纳米尺度物理 · 物理学 2015-04-09 Shigeru Ajisaka , Bojan Zunkovic , Yonatan Dubi

We showed that quantum mechanical superposition can sustain in the process of ion transfer in protein membrane for a substantial period, in spite of the presence of the interactions with environmental modes of molecular vibration. The…

量子物理 · 物理学 2013-05-03 Samyadeb Bhattacharya , Sisir Roy

In this work, we study the efficiency of charging a quantum battery through optical pumping. The battery consists of a qutrit and it is connected to a natural thermal reservoir and an external coherent drive in the limit where its upper…

量子物理 · 物理学 2022-11-08 Tiago F. F. Santos , Marcelo F. Santos

Simulating large electronic networks with vibrational environments remains a fundamental challenge due to the long lifetimes of electronic-vibrational (vibronic) excitations on the picosecond scale. Quantum computers are a promising…