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Monte Carlo simulations within the grand canonical ensemble are used to explore the liquid-vapour coexistence curve and critical point properties of the Lennard-Jones fluid. Attention is focused on the joint distribution of density and…

凝聚态物理 · 物理学 2009-10-28 Nigel B. Wilding

The application of an external field often renders empirical criteria for identifying liquid-gas phase transitions ambiguous. Here, we demonstrate that the finite-size scaling of the density profile provides a definitive criterion to…

统计力学 · 物理学 2025-10-28 Chong Zha , Yanshuang Chen , Cheng-Ran Du , Peng Tan , Yuliang Jin

Via a combination of molecular dynamics (MD) simulations and finite-size scaling (FSS) analysis, we study dynamic critical phenomena for the vapor-liquid transition in a three dimensional Lennard-Jones system. The phase behavior of the…

统计力学 · 物理学 2017-08-18 Jiarul Midya , Subir K. Das

Specialized Monte Carlo simulations and the moment free energy (MFE) method are employed to study liquid-gas phase equilibria in size-disperse fluids. The investigation is made subject to the constraint of fixed polydispersity, i.e. the…

软凝聚态物质 · 物理学 2009-11-10 Nigel B. Wilding , Moreno Fasolo , Peter Sollich

We report on the coexistence of liquid-like and gas-like structures in supercritical fluid (SCF). The deltoid coexistence region encloses the Widom line, and may therefore be termed the "Widom delta". Machine learning analysis of simulation…

统计力学 · 物理学 2018-03-26 Min Young Ha , Tae Jun Yoon , Tsvi Tlusty , Yongseok Jho , Won Bo Lee

Critical point of liquid-gas (LG) transition does not conform with the paradigm of spontaneous symmetry breaking because there is no broken symmetry in both phases. This stimulated the ongoing debate about the nature of the universality…

统计力学 · 物理学 2018-06-22 Max Yarmolinsky , Anatoly Kuklov

We analyze the critical gas-liquid phase behavior of arbitrary fluid mixtures in their coexistence region. We focus on the setting relevant for polydisperse colloids, where the overall density and composition of the system are being…

软凝聚态物质 · 物理学 2019-11-22 Pablo de Castro , Peter Sollich

The present work is aimed at investigating the behavior of Morse fluids in the immediate vicinity of the critical point within the framework of a cell model. This region is of both fundamental and practical importance, yet presents…

统计力学 · 物理学 2025-05-20 I. V. Pylyuk , M. P. Kozlovskii , R. V. Romanik

We consider the liquid-gas phase boundary in a binary fluid mixture near its critical end point. Using general scaling arguments we show that the diameter of the liquid-gas coexistence curve exhibits singular behaviour as the critical end…

统计力学 · 物理学 2016-08-31 Nigel B. Wilding

Water's unique anomalies are vital in various applications and biological processes, yet the molecular mechanisms behind these anomalies remain debated, particularly in the metastable liquid phase under supercooling and stretching…

统计力学 · 物理学 2024-05-17 Luis Enrique Coronas , Giancarlo Franzese

By combining accurate liquid-vapor coexistence and heat-capacity data, we have unambiguously separated two non-analytical contributions of liquid-gas asymmetry in fluid criticality and proved the validity of "complete scaling" [Fisher et…

统计力学 · 物理学 2009-11-11 Mikhail A. Anisimov , Jingtao Wang

We report an extensive Monte Carlo study of critical end point behaviour in a symmetrical binary fluid mixture. On the basis of general scaling arguments, singular behaviour is predicted in the diameter of the liquid-gas coexistence curve…

统计力学 · 物理学 2009-10-30 Nigel B. Wilding

In the supercritical fluid (SCF) region, at temperatures and pressures above the critical point, the thermodynamic singularity separating liquids and gases no longer exists. Recent arguments based on thermodynamics and critical scalings…

统计力学 · 物理学 2026-01-23 Sha Jin , Xinyang Li , Xue Fan , Matteo Baggioli , Yuliang Jin

A novel algorithm is presented that yields precise estimates of coexisting liquid and gas densities, $\rho^{\pm}(T)$, from grand canonical Monte Carlo simulations of model fluids near criticality. The algorithm utilizes data for the…

统计力学 · 物理学 2009-11-10 Young C. Kim , Michael E. Fisher

In statistical physics, it is well established that the liquid-gas (LG) phase transition with divergent critical fluctuations belongs to the Ising universality class. Whether non-equilibrium effects can alter this universal behavior remains…

统计力学 · 物理学 2026-04-07 Shang Gao , Hao Shang , Hao Hu , Yu-Qiang Ma , Qun-Li Lei

By confining water in nano-pores of silica glass, we can bypass the crystallization and study the pressure effect on the dynamical behavior in deeply supercooled state using neutron scattering. We observe a clear evidence of a cusp-like…

软凝聚态物质 · 物理学 2009-11-11 Li Liu , Sow-Hsin Chen , Antonio Faraone , Chun-Wan Yen , Chung-Yuan Mou

Finite-size scaling (FSS) is applied to net-baryon cumulant ratios $C_2/C_1$, $C_3/C_2$, $C_4/C_2$, $C_3/C_1$, and $C_4/C_1$ measured in Au+Au collisions over the Beam Energy Scan Phase~I range $\sqrt{s_{NN}}=7.7$--$200$~GeV to constrain…

核实验 · 物理学 2026-03-31 Roy A. Lacey

The behavior of fluids in the vicinity of the liquid-gas critical point is studied within the cell fluid model framework. The analytic method for deriving the equation of state of a cell fluid model in the low-temperature region (T<Tc) is…

统计力学 · 物理学 2020-02-27 I. V. Pylyuk

The properties of critical parameters and phase diagram structure of liquid-gas phase transition are investigated in thermal symmetric and asymmetric nuclear matter with the covariant density functional (CDF) theory. Although uncertainty…

核理论 · 物理学 2019-11-20 Shen Yang , Bo Nan Zhang , Bao Yuan Sun

The study of liquid-liquid phase transition has attracted considerable attention. One interesting example of such phenomenon is phosphorus for which the existence a first-order phase transition between a low density insulating molecular…

软凝聚态物质 · 物理学 2021-08-25 Manyi Yang , Tarak Karmakar , Michele Parrinello
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