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We report on spectroscopic studies of hot and ultracold RbSr molecules, and combine the results in an analysis that allows us to fit a potential energy curve (PEC) for the X(1)$^2\Sigma^+$ ground state bridging the short-to-long-range…

High resolution Fourier transform spectroscopy and Laser induced fluorescence has been performed on LiCa in the infrared spectral range. We analyze rovibrational transitions of the $(2)^2\Sigma^+$--$X(1)^2\Sigma^+$ system of LiCa and find…

化学物理 · 物理学 2022-09-19 J. Gerschmann , E. Schwanke , S. Ospelkaus , E. Tiemann

Molecular ions formed in cold hybrid ion-atom experiments may find interesting applications ranging from precision measurements to controlled chemical reactions. Here, we investigate electronic structure of the Sr$_2^+$ molecular ion, which…

原子物理 · 物理学 2020-06-17 Michał Śmiałkowski , Tatiana Korona , Michał Tomza

High-resolution spectroscopy on the $A^2\Pi$ - $X^2\Sigma^+$ electronic system of $^{138}$Ba$^{19}$F is performed using a cold molecular beam produced by a buffer gas source. The hyperfine structure in both $X^2\Sigma^+$ ground and $A^2\Pi$…

We investigate the emergence of ferromagnetism in the two-dimensional metal-halide CoBr$_2$, with a special focus on the role of electronic correlations. The calculated phonon spectrum shows that the system is thermodynamically stable…

强关联电子 · 物理学 2021-05-13 Hrishit Banerjee , Markus Aichhorn

Despite its apparently simple nature with four valence electrons, the strontium dimer constitutes a challenge for modern electronic structure theory. Here we focus on excited electronic states of Sr$_2$, which we investigate theoretically…

Rotationally resolved spectra of the C$^2\Sigma^+$-X$^2\Pi$ electronic system of the CH radical were measured using cavity ring-down spectroscopy in supersonically expanding, planar hydrocarbon plasma. The experimental conditions allowed…

化学物理 · 物理学 2019-05-03 Chris Medcraft , Harold Linnartz , Wim Ubachs

Precision measurements with ultracold molecules require development of robust and sensitive techniques to produce and interrogate the molecules. With this goal, we theoretically analyze factors that affect frequency measurements between…

量子物理 · 物理学 2009-11-13 S. Kotochigova , T. Zelevinsky , Jun Ye

An experimental study of the long range behavior of the ground state X^1\Sigma^+_g of Sr_2 is performed by high resolution spectroscopy of asymptotic vibrational levels and the use of available photoassociation data. Ground state levels as…

化学物理 · 物理学 2010-04-19 A. Stein , H. Knöckel , E. Tiemann

Electronic structure calculations using the augmented spherical wave method have been performed for CuRhO2. For this semiconductor crystallizing in the delafossite structure, it is found that the valence band maximum is mainly due to the 4d…

The electronic, laser-induced fluorescence spectrum of the $B^2\Sigma^+\leftarrow X^2\Sigma^+$ transition in $^{28}$Si$^{16}$O$^+$ and $^{29}$Si$^{16}$O$^+$ has been recorded in a cryogenic buffer gas cell at $\approx$ 100 K. Molecular…

化学物理 · 物理学 2022-09-27 Guo-Zhu Zhu , Guanming Lao , Clayton Ho , Wesley C. Campbell , Eric R. Hudson

In this study, we investigate the structure of the polar alkali-Strontium diatomic molecules as possible candidates for the realization of samples of new species of ultracold polar molecules. Using a quantum chemistry approach based on…

原子与分子团簇 · 物理学 2015-05-19 Romain Guérout , Mireille Aymar , Olivier Dulieu

The relative intensity distribution in the rotationally resolved laser-induced fluorescence spectra belonging to the $E(4)^1\Sigma^+\to (a^3\Sigma^+_1,X^1\Sigma^+)$ band systems of the KCs molecule was analyzed. The experimental intensities…

原子物理 · 物理学 2022-09-14 I. Klincare , M. Tamanis , R. Ferber , E. A. Pazyuk , A. V. Stolyarov , I. Havalyova , A. Pashov

The spectra (rotational, rotation-vibrational or electronic) of diatomic molecules due to transitions involving only closed-shell ($^1\Sigma$) electronic states follow very regular, simple patterns and their theoretical analysis is usually…

化学物理 · 物理学 2016-05-10 Jonathan Tennyson , Lorenzo Lodi , Laura K. McKemmish , Sergei N Yurchenko

The transfer of weakly bound KRb molecules from levels just below the dissociation threshold into the vibrational ground state with shaped laser pulses is studied. Optimal control theory is employed to calculate the pulses. The complexity…

原子物理 · 物理学 2011-04-15 Mamadou Ndong , Christiane P. Koch

In the first section we present the atomic part where a C2+ atomic target was prepared and used to generate theoretical data to investigate recombination lines arising from electron-ion collisions in thin plasma. R-matrix method was used to…

原子物理 · 物理学 2012-11-07 Taha Sochi

We report on the theoretical photoluminescence spectrum of the interacting two-dimensional electron gas at filling factor one (\nu=1). We considered a model similar to the one adopted to study the X-ray spectra of metals and solved it…

介观与纳米尺度物理 · 物理学 2007-05-23 R. L. Doretto , A. O. Caldeira

Heteronuclear alkali-metal dimers represent the class of molecules of choice for creating samples of ultracold molecules exhibiting an intrinsic large permanent electric dipole moment. Among them, the KCs molecule, with a permanent dipole…

原子物理 · 物理学 2015-04-08 D. Borsalino , R. Vexiau , M. Aymar , E. Luc-Koenig , O. Dulieu , N. Bouloufa-Maafa

We report a systematic study of the C(2)$^1\Pi_u$ electronic state in rubidium dimer, observed in polarization labelling spectroscopy experiment through the C $\leftarrow$ X$^{1}\Sigma^{+}_{g}$ transitions recorded under rotational…

化学物理 · 物理学 2022-07-27 Asen Pashov , Pawel Kowalczyk , Jacek Szczepkowski , Wlodzimierz Jastrzebski

We study an electronic structure of CeRhSb$_{1-x}$Sn$_x$ system, which displays quantum critical transition from a Kondo insulator to a non-Fermi liquid at $x=0.13$. We provide ultraviolet photoelectron spectra of valence band obtained at…

强关联电子 · 物理学 2020-03-13 R. Kurleto , J. Goraus , M. Rosmus , A. Ślebarski , P. Starowicz
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