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We demonstrate a simple and effective technique for dispersing pristine (unfunctionalized) graphene at high concentrations in a wide range of organic solvents by use of a stabilizing polymer (polyvinylpyrrolidone, PVP). These…

Liquid phase exfoliation (LPE) is the most promising method for the low-cost, scalable production of two-dimensional nanosheets from their bulk counterparts. Extensive exfoliation occurs in most solvents due to the huge amount of energy…

材料科学 · 物理学 2023-10-27 Urvesh Patil , Nuala M. Caffrey

We demonstrate a novel in situ polymerization technique to develop localized polymer coatings on the surface of dispersed pristine graphene sheets. Graphene sheets show great promise as strong, conductive fillers in polymer nanocomposites;…

软凝聚态物质 · 物理学 2011-04-29 Sriya Das , Ahmed S. Wajid , John L. Shelburne , Yen-Chi Liao , Micah J. Green

In the present work, the use of a commercial ionic liquid as a convenient solvent medium for graphite exfoliation in mild and easy conditions without any chemical modification is presented. To confirm the presence of few layer graphene, its…

We have demonstrated a method to disperse and exfoliate graphite to give graphene suspended in water-surfactant solutions. Optical characterisation of these suspensions allowed the partial optimisation of the dispersion process.…

材料科学 · 物理学 2008-09-17 Y Hernandez , M Lotya , V Nicolosi , FM Blighe , S De , G Duesberg , JN Coleman

We investigated the effect of surfactants and their concentration (Csur) on the final graphene concentration (CG) via the liquid-phase exfoliation method. Six typical surfactants including ionic and non-ionic ones were explored and the…

材料科学 · 物理学 2016-06-14 Shuai Wang , Min Yi , Shuaishuai Liang , Zhigang Shen , Xiaojing Zhang , Shulin Ma

Among the large number of promising two-dimensional (2D) atomic layer crystals, true metallic layers are rare. Through combined theoretical and experimental approaches, we report on the stability and successful exfoliation of atomically…

We use molecular dynamics simulation to study the exfoliation of graphene and fluorographene in molecular and ionic liquids, by performing computer experiments in which one layer of the 2D nanomaterial is peeled from a stack, in vacuum and…

介观与纳米尺度物理 · 物理学 2018-02-07 Emilie Bordes , Joanna Szala-Bilnik , Agílio A. H. Pádua

Ion and metal diffusion in metal halide perovskites, charge-transporting layers, and electrodes are detrimental to the performance and stability of perovskite-based photovoltaic devices. As a result, there is an intense research interest in…

Heterostructures prepared from graphene and fluorographene (FG) using the technology of 2D printing on solid and flexible substrates were fabricated and studied. Excellent stability of printed graphene layers and, to a lesser degree,…

We report on the preparation of polycarbonate-based graphene (PC/G) composites, by using a simple and scalable solution blending method to disperse single (SLG) and few layer (FLG) graphene flakes, prepared by liquid phase exfoliation…

Graphene has attracted much attention due to its interesting properties and potential applications. Chemical exfoliation methods have been developed to make graphene recently, aimed at large-scale assembly and applications such as…

材料科学 · 物理学 2009-08-03 Hailiang Wang , Joshua Tucker Robinson , Xiaolin Li , Hongjie Dai

Graphene stands as a promising material with vast potential across energy storage, electronics, etc. Here, we present a novel mechanical approach utilizing ultrasonic high-energy intercalation exfoliation to extract monolayer graphene from…

材料科学 · 物理学 2025-01-15 Kaitong Sun , Si Wu , Junchao Xia , Yinghao Zhu , Guanping Xu , Hai-Feng Li

The production of large area interfaces and the use of scalable methods to build-up designed nanostructures generating advanced functional properties are of high interest for many materials science applications. Nevertheless, large area…

Results of a study on the electrochemical properties of exfoliated single and multilayer graphene flakes are presented. Graphene flakes were deposited on silicon/silicon oxide wafers to enable fast and accurate characterization by optical…

介观与纳米尺度物理 · 物理学 2011-10-11 Anna T. Valota , Ian A. Kinloch , Kostya S. Novoselov , Cinzia Casiraghi , Axel Eckmann , Ernie W. Hill , Robert A. W. Dryfe

Quasi all water soluble composites use graphene oxide (GO) or reduced graphene oxide (rGO) as graphene based additives despite the long and harsh conditions required for their preparation. Herein, polyvinyl alcohol (PVA) films containing…

The non-covalent functionalisation of graphene is an attractive strategy to alter the surface chemistry of graphene without damaging its superior electrical and mechanical properties. Using the facile method of aqueous-phase…

Pyrene-functional PMMAs were prepared via ATRP-controlled polymerization and click reaction, as efficient dispersing agents for the exfoliation of few-layered graphene sheets (GS) in easily processable low boiling point chloroform. In…

Water dispersed graphene oxide sheets were used to prepare graphene-polyethylenglycol diacrylate resin composites by photopolymerization. It was found that graphene sheets undergo excellent morphological distribution within the resin…

材料科学 · 物理学 2013-02-07 M. Sangermano , S. Marchi , L. Valentini , S. Bittolo Bon , P. Fabbri

We demonstrate how self-assembled monolayers of aromatic molecules on copper substrates can be converted into high-quality single-layer graphene using low-energy electron irradiation and subsequent annealing. We characterize this…

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