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Nearly two-dimensional diamond, or diamane, is coveted as ultrathin $sp^3$-carbon film with unique mechanics and electro-optics. The very thinness ($~h$) makes it possible for the surface chemistry, e.g. adsorbed atoms, to shift the bulk…

材料科学 · 物理学 2020-10-27 Sergey V. Erohin , Qiyuan Ruan , Pavel B. Sorokin , Boris I. Yakobson

The study of the nanomechanics of graphene $-$ and other 2D materials $-$ has led to the discovery of exciting new properties in 2D crystals, such as their remarkable in-plane stiffness and out of plane flexibility, as well as their unique…

材料科学 · 物理学 2019-02-14 Filippo Cellini , Francesco Lavini , Claire Berger , Walt de Heer , Elisa Riedo

We show by means of molecular dynamics simulations that graphene is an excellent coating for diamond. The transformation of diamond to amorphous carbon while sliding under pressure can be prevented by having at least two graphene layers…

介观与纳米尺度物理 · 物理学 2015-11-05 M. M. van Wijk , A. Fasolino

We unveil the diamondization mechanism of few-layer graphene compressed in the presence of water, providing robust evidence for the pressure-induced formation of 2D diamond. High-pressure Raman spectroscopy provides evidence of a phase…

Graphene - a monolayer of carbon atoms densely packed into a hexagonal lattice - has one of the strongest possible atomic bonds and can be viewed as a robust atomic-scale scaffold, to which other chemical species can be attached without…

We consider a new C2H nanostructure based on bilayer graphene transformed under the covalent bond of hydrogen atoms adsorbed on its external surface, as well as compounds of carbon atoms located opposite each other in neighboring layers.…

介观与纳米尺度物理 · 物理学 2010-02-04 Leonid A. Chernozatonskii , Pavel B. Sorokin , Alexander G. Kvashnin , Dmitry G. Kvashnin

Atomically thin graphite, known as graphene, has been a marvel in material science because of its exceptional properties, novel physics and promising applications. Atomically thin diamond, called diamane, has also attracted considerable…

In our previously published work, we have reported colossal magnetoresistance, Andreev oscillations, ferromagnetism, and granular superconductivity in oxygen-implanted carbon fibers, graphite foils, and highly oriented pyrolytic graphite.…

Graphene demonstrated potential for practical applications owing to its excellent electronic and thermal properties. Typical graphene field-effect transistors and interconnects built on conventional SiO2/Si substrates reveal the breakdown…

材料科学 · 物理学 2015-06-04 Jie Yu , Guanxiong Liu , Anirudha V. Sumant , Vivek Goyal , Alexander A. Balandin

Low-energy ion beam modification was proposed to create graphene on the top of the insulated diamond-like carbon films. In such low-temperature fabrication process the surface of the amorphous carbon could crystallize to graphene as a…

材料科学 · 物理学 2015-05-27 Savcho Tinchev

Chemical oxidation of multilayer graphene grown on silicon carbide yields films exhibiting reproducible characteristics, lateral uniformity, smoothness over large areas, and manageable chemical complexity, thereby opening opportunities to…

材料科学 · 物理学 2014-03-20 S. Zhou , S. Kim , E. Di Gennaro , Y. Hu , C. Gong , X. Lu , C. Berger , W. de Heer , E. Riedo , Y. J. Chabal , C. Aruta , A. Bongiorno

The conversion of multilayer graphenes into sp^3-bonded carbon films on metal surfaces (through hydrogenation or fluorination of the outer surface of the top graphene layer) is indicated through first-principles computations. The main…

材料科学 · 物理学 2013-09-13 Dorj Odkhuu , Dongbin Shin , Rodney S. Ruoff , Noejung Park

Due to the absence of matching carbon atoms at honeycomb centers with carbon atoms in adjacent graphene sheets, theorists predicted that a sliding process is needed to form AA, AB, or ABC stacking when directly converting graphite into sp3…

Hot-filament process was recently employed to convert, totally or partially, few-layer graphene (FLG) with Bernal stacking into crystalline sp$^3$-C sheets at low pressure. Those materials constitute new synthetic carbon nanoforms. The…

材料科学 · 物理学 2019-07-23 Fabrice Piazza , Marc Monthioux , Pascal Puech , Iann C. Gerber

Two-dimensional (2D) diamond has aroused tremendous interest in nanoelectronics and optoelectronics, owing to its superior properties and flexible characteristics compared to bulk diamond. Despite significant efforts, great challenges lie…

The power of polymorphism in carbon is vividly manifested by the numerous applications of carbon-based nano-materials. Ranging from environmental issues to biomedical applications, it has the potential to address many of today's dire…

We study the stability of various kinds of graphene samples under soft X-ray irradiation. Our results show that in single layer exfoliated graphene (a closer analogue to two dimensional material), the in-plane carbon-carbon bonds are…

材料科学 · 物理学 2015-05-14 S. Y. Zhou , C. O. Girit , A. Scholl , C. J. Jozwiak , D. A. Siegel , P. Yu , J. T. Robinson , F. Wang , A. Zettl , A. Lanzara

Graphene is a truly two-dimensional atomic crystal with exceptional electronic and mechanical properties. Whereas conventional bulk and thin-film materials have been studied extensively, the key mechanical properties of graphene, such as…

材料科学 · 物理学 2010-05-25 Dipanjan Sen , Kostya S. Novoselov , Pedro M. Reis , Markus J. Buehler

The morphology of graphene on SiC {0001} surfaces formed in various environments including ultra-high vacuum, 1 atm of argon, and 10^-6 to 10^-4 Torr of disilane is studied by atomic force microscopy, low-energy electron microscopy, and…

材料科学 · 物理学 2015-05-30 N. Srivastava , Guowei He , Luxmi , P. C. Mende , R. M. Feenstra , Yugang Sun

Recent transport measurements on thin graphite films grown on SiC show large coherence lengths and anomalous integer quantum Hall effects expected for isolated graphene sheets. This is the case eventhough the layer-substrate epitaxy of…

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