相关论文: Li doping kagome spin liquid compounds

Tailoring transport properties of strongly correlated electron systems in a controlled fashion counts among the dreams of materials scientists. In copper oxides, varying the carrier concentration is a tool to obtain high-temperature…

Doping carriers into a correlated quantum ground state offers a promising route to generate new quantum states. The recent advent of moir\'{e} superlattices provided a versatile platform with great tunability to explore doping physics in…

Strongly correlated Fermi systems are among the most intriguing and fundamental systems in physics, whose realization in some compounds is still to be discovered. We show that herbertsmithite ZnCu_3(OH)_6Cl_2 can be viewed as a strongly…

Recent theoretical and experimental evaluations demonstrated that KLi6TaO6 is a good Li-ion conductor. In this study, the energetics and detailed mechanism of Li-ion migration, relevant to the point defects of KLi6TaO6, were analyzed by…

We studied structural and magnetic properties of a series of insulating double perovskite compounds, La$_{2-x}$Sr$_{x}$CuRuO$_{6}$ (0 $\le$ x $\le$ 1), representing doping via \textit{A}-site substitution. The end members…

Recent experimental work has realized a new insulating state of samarium nickelate (SmNiO$_3$), accessible in a reversible manner via high-density electron doping. To elucidate this behavior, we use the first-principles density functional…

Herbertsmithite (ZnCu3(OH)6Cl2) is often discussed as the best realization of the highly frustrated antiferromagnetic kagome lattice known so far. We employ density functional theory calculations to determine eight exchange coupling…

In this article, we review some recent theoretical developments on potential high-temperature superconductors and unconventional metallic states that can arise from doping a spin-one Mott insulator in the $d^{8}$ valence. These studies are…

Low energy inelastic neutron scattering on single crystals of the kagome spin liquid compound ZnCu3(OD)6Cl2 (Herbertsmithite) reveals antiferromagnetic correlations between impurity spins for energy transfers E < 0.8 meV (~J/20). The…

Strongly correlated Fermi systems are among the most intriguing and fundamental systems in physics. We show that the herbertsmithite ZnCu3(OH)6Cl2 can be viewed as a new type of strongly correlated electrical insulator that possesses…

Exotic quantum spin liquid (QSL) is formed with such hypothetic particles as fermionic spinons carrying spin 1/2 and no charge. Here we calculate its thermodynamic and relaxation properties. Our calculations unveil the fundamental…

Recently, the bilayer perovskite nickelate La$_3$Ni$_2$O$_7$ has been reported to exhibit high-temperature superconductivity near $80$ K under a moderate pressure of about $14$GPa. To investigate the underlying pairing mechanism and…

We present a microscopic study of a doped quantum spin liquid candidate, the hyperkagome Na$_3$Ir$_3$O$_8$ compound by using $^{23}$Na NMR. We determine the intrinsic behavior of the uniform \textbf{q} $ = 0$ susceptibility via shift…

We have investigated experimentally and theoretically the series (Na$_{1-x}$Li$_{x}$)$_{2}$IrO$_{3}$. Contrary to what has been believed so far, only for $x\leq0.25$ the system forms uniform solid solutions. For larger Li content, as…

Electronic structure calculations indicate that the Sr2FeSbO6 double perovskite has a flat-band set just above the Fermi level that includes contributions from ordinary sub-bands with weak kinetic electron hopping plus a flat sub-band that…

The doped quantum spin liquid on the kagome lattice provides a fascinating platform to explore exotic quantum states, such as the reported holon Wigner crystal at low doping. By extending the doping range to $\delta = 0.027$ - $0.36$, we…

We present a Raman spectroscopic investigation of the Herbertsmithite ZnCu3(OH)6Cl2, the first realization of a Heisenberg s=1/2 antiferromagnet on a perfect kagome lattice. The magnetic excitation spectrum of this compound is dominated by…

Based on experimental data and our theoretical analysis, we provide a strategy for unambiguous establishing of gapless quantum spin liquid state (QSL) in herbertsmithite and other materials. To clarify the nature of QSL, we recommend…

We have studied the magnetic properties of clinoatacamite Cu$_2$Cl(OH)$_3$, the parent compound of the quantum spin liquid candidate herbertsmithite and a longstanding puzzle among frustrated quantum magnets. As we reveal using…

The recently discovered lithium-rich antiperovskites (Li$_2$Fe)SeO and (Li$_2$Fe)SO host lithium and iron ions on the same atomic position which octahedrally coordinates to central oxygens. In a cubic antiperovskite these sites form Kagome…