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Ferroelectric soft mode properties in ceramics and thin films are reviewed and compared with single crystals. In general, the permittivity in ceramics and thin films is markedly reduced compared to the single crystals mainly because of…

材料科学 · 物理学 2007-05-23 J. Petzelt , S. Kamba , J. Hlinka

The dielectric properties of tantalum doped BaTi0.85Zr0.15O3 were investigated. The conventional solid state reaction method was used to make the ceramic samples. The composition was close to the pinch point of the three structure phase…

材料科学 · 物理学 2007-05-23 Jun Xu , Mitsuru Itoh

CaCu3Ti4O12 (CCTO) ceramics are potential candidates for capacitor applications due to their large dielectric permittivity (e') values of up to 300 000. The underlying mechanism for the high e' is an internal barrier layer capacitor (IBLC)…

材料科学 · 物理学 2014-02-10 Rainer Schmidt , Derek C. Sinclair

Complex electrical permittivity measurements in (1-x)[Pb(Mg1/3 Nb2/3)O3]-xPbTiO3 ceramics for 0.10 x 0.40 were performed in the frequency and temperature range from 1 kHz to 100 kHz and from 15 to 600 K, respectively. Unexpected dielectric…

材料科学 · 物理学 2009-11-10 M. H. Lente , A. L. Zanin , E. R. M. Andreeta , I. A. Santos , D. Garcia , J. A. Eiras

The complex dielectric permittivity of a sintered ceramic tablet consisting of 70.5 % $BiFeO_{3}$ and 27.7% $Bi_{2}Fe_{4}O_{9}$ was analyzed as a function of temperature from -120 {\deg}C to 230 {\deg}C. The results reveal a complicated…

材料科学 · 物理学 2022-11-22 Gilad Orr , Andrey Gorychev , Paul Ben Ishai

Lead-free Ba0.85Ca0.15Ti0.9Zr0.1O3 (BCZT) ceramics had attracted much attention for the fabrication of microelectronic devices by virtue of their excellent dielectric, ferroelectric and piezoelectric properties. To understand the effects of…

We revealed the anomalous temperature behavior of the giant dielectric permittivity and unusual frequency dependences of the pyroelectric response of the fine-grained ceramics prepared by the spark plasma sintering of the ferroelectric…

We reveal the visible influence of the ultra-small concentrations (1 wt.% or less) of the BaTiO3 nanoparticles (average size 24 nm) on the current-voltage characteristics and capacitance of the dielectric liquid crystal (LC) 5CB. The pure…

We explore the effect of charge carrier doping on ferroelectricity using density functional calculations and phenomenological modeling. By considering a prototypical ferroelectric material, BaTiO3, we demonstrate that ferroelectric…

材料科学 · 物理学 2013-01-25 Yong Wang , Xiaohui Liu , J. D. Burton , Sitaram S. Jaswal , Evgeny Y. Tsymbal

Three types of BaTiO3 core - amorphous nano-shell composite ceramics were processed from the same core-shell powder by standard sintering, spark-plasma sintering and two-step sintering techniques and characterized by XRD, HRSEM and…

Some of the Multiferroics [1] form a rare class of materials that exhibit magnetoelectric coupling arising from the coexistence of ferromagnetism and ferroelectricity, with potential for many technological applications.[2,3] Over the last…

材料科学 · 物理学 2009-11-13 R. V. K. Mangalam , Nirat Ray , Umesh V. Waghmare , A. Sundaresan , C. N. R. Rao

Based upon a widely-accepted internal-barrier-layer-capacitance (IBLC) model, the dielectric loss in the giant-dielectric-constant CaCu$_{3}$Ti$_{4}$O$_{12}$ (CCTO) material is expected to decrease as the conductivity of the CCTO…

材料科学 · 物理学 2007-05-23 Lixin Feng , Xiaoming Tang , Yueyue Yan , Xuezhi Chen , Zhengkuan Jiao , Guanghan Cao

Dielectric response as a function of frequency for high-permittivity dielectric and ferroelectric materials is discussed emphasizing the dynamic behaviour in the microwave and infrared range. After introducing the usual modelling of the…

材料科学 · 物理学 2008-12-18 Jan Petzelt , Stanislav Kamba

The bulk photovoltaic effect exhibited by the non-centrosymmetric system gains research interest due to the observed large open-circuit voltage. The ferroelectric systems exhibiting anomalous photovoltaic effect are mostly crystallized with…

For the ferroelectric perovskite compounds BaTiO3 and PbTiO3, we have studied the effects of external electric fields on the structural properties of the (001) surfaces. The field-induced changes in the surface interlayer spacings and…

材料科学 · 物理学 2009-10-31 B. Meyer , David Vanderbilt

Lead-free ba0.85ca0.15zr0.1ti0.9o3 (bczt) ceramic powders were synthesized using the sol-gel method. to achieve high-energy storage and large electrocaloric effect in bulk ceramics the ceramics thickness was reduced. dielectric,…

Fast-cooling after sintering or annealing of BiFeO3-BaTiO3 mixed oxide ceramics yields core-shell structures that give excellent functional properties, but their precise phase assemblage and nanostructure remains an open question. By…

AFe$_{1 / 2}$B$_{1 / 2}$O$_{3}$(A- Ba, Sr, Ca; B-Nb, Ta, Sb) ceramics were synthesized and temperature dependencies of the dielectric permittivity were measured at different frequencies. The experimental data obtained show very high values…

材料科学 · 物理学 2009-11-07 I. P. Raevski , S. A. Prosandeev , A. S. Bogatin , M. A. Malitskaya

The recently discovered ferroelectric nematic liquid crystals have been reported to exhibit very large dielectric permittivity values. Here, we report a systematic investigation of the dielectric behavior of a prototypical ferroelectric…

软凝聚态物质 · 物理学 2024-02-05 Aitor Erkoreka , Josu Martinez-Perdiguero , Richard J. Mandle , Alenka Mertelj , Nerea Sebastián

The structural, dielectric and ferroelectric properties of lead-free (Na0.5-xKxBi0.5-xLax)TiO3 powders synthesized by sol-gel self-combustion method were investigated. Rietveld refinement of Synchrotron x-ray diffraction data confirms pure…

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